scholarly journals Three Spirostanol Glycosides from the Seeds of Hyoscyamus Niger L.

2006 ◽  
Vol 1 (1) ◽  
pp. 100-103
Author(s):  
Irina Lunga ◽  
Pavel Kintia ◽  
Stepan Shvets ◽  
Carla Bassarelo ◽  
Cosimo Pizza ◽  
...  
Keyword(s):  
Spectroscopic Methods ◽  
Two Dimensional ◽  
Hyoscyamus Niger ◽  
One Dimensional ◽  
Steroidal Glycosides ◽  
Ms Analysis ◽  
The Given ◽  
First Time ◽  
Chemical Evidence

Three steroidal glycosides of spirostane series have been isolated from the seeds of Hyoscyamus niger L.(Solanaceae). Their structures were determined on the basis of chemical evidence and extensive spectroscopic methods including one-dimensional, two-dimensional NMR and MS analysis. In the genus Hyoscyamus the given compounds have been found out for the first time.

scholarly journals Steroidal Glycosides from Veronica chamaedrys L. Part I. The Structures of Chamaedrosides C, C1, C2, E, E1 and E2

2012 ◽  
Vol 7 (5) ◽  
pp. 1934578X1200700 ◽  
Author(s):  
Alexandra Marchenko ◽  
Pavel Kintya ◽  
Bozena Wyrzykiewicz ◽  
Elena Gorincioi
Keyword(s):  
2D Nmr ◽  
Spectroscopic Methods ◽  
Steroidal Glycosides ◽  
Ms Analysis ◽  
The Given ◽  
First Time ◽  
Chemical Evidence

Two new spirostane glycosides, chamaedrosides C (1) and C1 (2), two new furostane glycosides, chamaedrosides E (4) and E1 (5), and two new furospirostane glycosides, chamaedrosides C2 (3) and E2 (6), have been isolated from Veronica chamaedrys L. plants. Their structures were determined on the basis of chemical evidence and extensive spectroscopic methods, including 1D- and 2D-NMR experiments, as well as MS analysis. The given compounds have been found for the first time.

scholarly journals Steroidal Glycosides from the Seeds of Hyoscyamus Niger L. and their Antifungal Activity

2007 ◽  
Vol 2 (1) ◽  
pp. 108-113
Author(s):  
Irina Lunga ◽  
Pavel Chintea ◽  
Stepan Shvets ◽  
Anna Favelb ◽  
Cosimo Pizza
Keyword(s):  
Nmr Spectroscopy ◽  
Antifungal Activity ◽  
Pathogenic Fungi ◽  
Phytochemical Analysis ◽  
Two Dimensional ◽  
Hyoscyamus Niger ◽  
Steroidal Glycosides ◽  
Spirostanol Saponins ◽  
First Time

Phytochemical analysis of the seeds of Hyocyamus niger L. (Solonaceae) resulted in the isolation of six steroidal glycosides, two furostanol (1, 2) and four spirostanol saponins (3, 4, 5, 6), which were found in this plant for the first time. The structures of these compounds were determined by detailed analysis of their spectral data, including two-dimensional NMR spectroscopy and MS spectroscopy. The antifungal activity of a crude steroidal glycoside extract, fractions of spirostanoles and individual glicosides was investigated in vitro against a panel of human pathogenic fungi, yeasts as well as dermatophytes and filamentous species.

scholarly journals Steroidal Glycosides from the Seeds of Hyoscyamus niger L

2008 ◽  
Vol 3 (5) ◽  
pp. 1934578X0800300
Author(s):  
Irina Lunga ◽  
Carla Bassarello ◽  
Pavel Kintia ◽  
Stepan Shvets ◽  
Sonia Piacente ◽  
...  
Keyword(s):  
Hyoscyamus Niger ◽  
Spectroscopic Evidence ◽  
Steroidal Glycosides ◽  
The Given ◽  
First Time

The investigation of the steroidal glycosides of the seeds of Hyoscyamus niger L. led to the isolation of two new spirostane saponins (2, 6) together with seven known glycosides with either furostane or spirostane aglycones. On the basis of chemical and spectroscopic evidence, the structures of 2 and 6 were elucidated as (25 R)-5α-spirostan-3β-ol 3- O-β-D-glucopyranosyl-(1→3)-β-D-galactopyranoside (2) and (25 R)-5α-spirostan-3β-ol 3- O-β-D-glucopyranosyl-(1→3)-[β-D-glucopyranosyl-(1→2)]-β-D-galactopyranoside (6). The given compounds have been found for the first time in the genus Hyoscyamus.

Proteome profile of zebrafish caudal fin based on one-dimensional gel electrophoresis LCMS/MS and two-dimensional gel electrophoresis MALDI MS/MS analysis

2010 ◽  
Vol 34 (2) ◽  
pp. 225-232 ◽  
Author(s):  
Sachin K. Singh ◽  
Mula G. Meena Lakshmi ◽  
Sandeep Saxena ◽  
Cherukuvada V. Brahmendra Swamy ◽  
Mohammed M. Idris
Keyword(s):  
Gel Electrophoresis ◽  
Maldi Ms ◽  
Two Dimensional ◽  
Two Dimensional Gel Electrophoresis ◽  
Caudal Fin ◽  
One Dimensional ◽  
Ms Analysis ◽  
Proteome Profile

scholarly journals BLOCK CIPHERS ON THE BASIS OF REVERSIBLE CELLULAR AUTOMATA

2020 ◽  
Vol 10 (1) ◽  
pp. 8-11
Author(s):  
Yuliya Tanasyuk ◽  
Petro Burdeinyi
Keyword(s):  
Cellular Automata ◽  
Block Cipher ◽  
Key Generation ◽  
One Dimensional ◽  
C Programming Language ◽  
C Programming ◽  
Shared Secret ◽  
Reversible Cellular Automata ◽  
The Given ◽  
First Time

The given paper is devoted to the software development of block cipher based on reversible one-dimensional cellular automata and the study of its statistical properties. The software implementation of the proposed encryption algorithm is performed in C# programming language in Visual Studio 2017. The paper presents specially designed approach for key generation. To ensure desired cryptographic stability, the shared secret parameters can be adjusted to contain information needed for creating substitution tables, defining reversible rules, and hiding final data. For the first time, it is suggested to create substitution tables based on iterations of a cellular automaton that is initialized by the key data.

Isoflavones from Camphorosma lessingii Inhibit the Organic Anion Transporters OAT1 and OAT3

Planta Medica ◽  
2018 ◽  
Vol 85 (03) ◽  
pp. 225-230 ◽  
Author(s):  
Xinhui Wang ◽  
Dujuan Wang ◽  
Xue Wang ◽  
Manana Khutsishvili ◽  
Kamilla Tamanyan ◽  
...  
Keyword(s):  
Organic Anion ◽  
Inhibitory Effect ◽  
Spectroscopic Methods ◽  
Organic Anion Transporters ◽  
One Dimensional ◽  
Anion Transporters ◽  
Significant Inhibitory Effect ◽  
Phytochemical Investigation ◽  
The Family ◽  
First Time

AbstractPhytochemical investigation of Camphorosma lessingii has resulted in the isolation of four previously unreported isoflavones (1–4) and eight known compounds (5–12). Nine of these compounds (1–6, 8–10) are reported for the first time from members of the family Amaranthaceae. The structures of all isolated compounds were determined by spectroscopic methods, primarily one-dimensional and two-dimensional nuclear magnetic resonance and mass spectrometry. The absolute configuration of 6 was confirmed by circular dichroism. Inhibition of the organic anion transporters, OAT1 and OAT3, by the isolated compounds was evaluated. Among them, 7, 2′-dihydroxy- 6,8-dimethoxyisoflavone (1), 2′-hydroxy-6,7,8-trimethoxyisoflavone (2), 6,2′-dihydroxy-7,8-dimethoxyisoflavone (3), and 7-methoxyflavone (5) showed a significant inhibitory effect on 6-carboxyfluorescein uptake mediated by OAT1 and OAT3.

scholarly journals Preparative Separation of Diterpene Lactones and Flavones from Andrographis paniculate Using Off-Line Two-Dimensional High-Speed Counter-Current Chromatography

Molecules ◽  
2019 ◽  
Vol 24 (3) ◽  
pp. 620 ◽  
Author(s):  
Xiaowei Sun ◽  
Huijiao Yan ◽  
Yujie Zhang ◽  
Xiao Wang ◽  
Dawei Qin ◽  
...  
Keyword(s):  
Ethyl Acetate ◽  
Petroleum Ether ◽  
High Speed ◽  
Spectroscopic Methods ◽  
Two Dimensional ◽  
Preparative Separation ◽  
Counter Current ◽  
First Time

Seven diterpene lactones, andrographolide (1), isoandrographolide (2), neo-andrographolide (3), 14-deoxy-11,12-didehydroandrographolide (4), 14-deoxyandrographiside (5), 14-deoxy-11,12-didehydroandrographiside (6), 3,14-dideoxyandrographolide (10), and three flavones, andrographidine C (7), andrographidine A (8), 5-hydroxy-7,8-dimethoxyflavanone (9) have been successfully and efficiently isolated from A. paniculata using an off-line two dimensional (2D) high-speed counter-current chromatography (HSCCC) method for the first time. For the first dimension HSCCC separation, petroleum ether-ethyl acetate-methanol-water 3:7:5:5 (v/v) was employed to isolate 14.4 mg of compound 1, 3.1 mg of compound 2, 7.8 mg of compound 3, and 18.0 mg of compound 4 from 200 mg of the A. paniculata extract. For the second dimension HSCCC separation, petroleum ether-ethyl acetate-methanol-water 2:8:1:9 (v/v) and 5:5:6:4 (v/v) were employed to isolate the collected fractions ranged from 55 to 79 min and the flow out fraction, respectively, which led to 5.1 mg of compound 5, 4.4 mg of compound 6, 2.4 mg of compound 7, 3.3 mg of compound 8, 4.0 mg of compound 9, 7.0 mg of compound 10. The structures of these diterpene lactones and flavones were elucidated by extensive spectroscopic methods.

scholarly journals Novel Pyran Derivative Ornamented with free Amino and Nitrile Functionalities: Synthesis and Spectroscopic Characterization

2019 ◽  
Vol 9 (1S3) ◽  
pp. 278-282
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Free Amino ◽  
Spectroscopic Characterization ◽  
Spectroscopic Methods ◽  
Two Dimensional ◽  
Spectral Techniques ◽  
One Dimensional ◽  
One Step ◽  
Pyran Derivative

A novel 4H-pyran derivative tethered with free amino and nitrile groups (1) was synthesized from commercially available meta-bromobenzaldehyde, malononitrile and 2-(methacryloyloxy)ethyl 3-oxobutanoate by adopting a one-step three components reaction strategy. The structure of the synthesized 1 has been established based on physical and spectroscopic methods such as infrared, one dimensional proton and carbon nuclear magnetic resonance as well as two-dimensional HSQC and HMBC spectral techniques.

scholarly journals Steroidal Saponins from the Seeds of Hyoscyamus Niger L.

2008 ◽  
Vol 3 (1) ◽  
pp. 89-93
Author(s):  
Irina Lunga ◽  
Pavel Kintia ◽  
Stepan Shvets ◽  
Carla Bassarello ◽  
Sonia Piacente ◽  
...  
Keyword(s):  
13C Nmr ◽  
Chemical Shifts ◽  
Two Dimensional ◽  
Hyoscyamus Niger ◽  
Steroidal Saponins ◽  
1H And 13C Nmr ◽  
13C Nmr Chemical Shifts ◽  
Nmr Techniques ◽  
Pregnane Glycoside ◽  
First Time

Ten steroidal saponins have been isolated form the seeds of Hyoscyamus niger L. for the first time and their structures have been elucidated. Seven saponins belong to spirostane series, two are furostane-type and one is pregnane glycoside. Hyoscyamosides B, C and C2 are new steroidal saponins, which have never been reported before in literature. Complete assignments of the 1H and 13C NMR chemical shifts for all these glycosides were achieved by means of one- and two-dimensional NMR techniques, including 1H–1H COSY, HSQC, HMBC and ROESY spectra.

Two-Dimensional Study of Heat Transfer and Fluid Flow in a Natural Convection Loop

1982 ◽  
Vol 104 (3) ◽  
pp. 508-514 ◽  
Author(s):  
A. Mertol ◽  
R. Greif ◽  
Y. Zvirin
Keyword(s):  
Heat Transfer ◽  
Fluid Flow ◽  
Natural Convection ◽  
A Priori ◽  
Two Dimensional ◽  
Transfer Coefficients ◽  
One Dimensional ◽  
Heat Transfer Coefficients ◽  
First Time ◽  
Good Agreement

A study has been made of the heat transfer and fluid flow in a natural convection loop. Previous studies of these systems have utilized a one-dimensional approach which requires a priori specifications of the friction and the heat-transfer coefficients. The present work carries out a two-dimensional analysis for the first time. The results yield the friction and the heat-transfer coefficients and give their variation along the loop with the Graetz number as a parameter. Comparison is also made with experimental data for the heat flux and good agreement is obtained.

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