scholarly journals Fabrication and Characterization of Flexible Medical-Grade TPU Filament for Fused Deposition Modeling 3DP Technology

2018 ◽  
Author(s):  
Agnieszka Haryńska ◽  
Iga Gubańska ◽  
Justyna Kucińska-Lipka ◽  
Helena Janik
Keyword(s):  
Fused Deposition Modeling ◽  
Thermoplastic Polyurethane ◽  
Extrusion Process ◽  
Biological Properties ◽  
Fused Deposition ◽  
3D Printers ◽  
Deposition Modeling ◽  
A Chain ◽  
Medical Grade

The possibility of using additive manufacturing (AM) in the medicine area has created a new opportunities in health care. This has contributed to a sharp increase in demand for 3D printers, their systems and materials that are adapted to strict medical requirements. We described herein a medical-grade thermoplastic polyurethane (S-TPU), which was developed and then formed into a filament for Fused Deposition Modeling (FDM) 3D printers during a melt-extrusion process. S-TPU consisting of aliphatic hexamethylene 1,6-diisocyanate (HDI), amorphous α,ω-dihydroxy(ethylene-butylene adipate) (PEBA) and 1,4 butandiol (BDO) as a chain extender, was synthesized without the use of a catalyst. The filament properties were characterized by rheological, mechanical, physico-chemical and in vitro biological properties. The tests showed biocompatibility of the obtained filament as well as revealed no significant effect of the filament formation process on its properties. This study may contribute to expanding the range of medical-grade flexible filaments for standard low-budget FDM printers.

scholarly journals Fabrication and Characterization of Flexible Medical-Grade TPU Filament for Fused Deposition Modeling 3DP Technology

Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1304 ◽  
Author(s):  
Agnieszka Haryńska ◽  
Iga Gubanska ◽  
Justyna Kucinska-Lipka ◽  
Helena Janik
Keyword(s):  
Fused Deposition Modeling ◽  
Thermoplastic Polyurethane ◽  
Extrusion Process ◽  
Biological Properties ◽  
Fused Deposition ◽  
3D Printers ◽  
Deposition Modeling ◽  
A Chain ◽  
Medical Grade

The possibility of using additive manufacturing (AM) in the medicine area has created new opportunities in health care. This has contributed to a sharp increase in demand for 3D printers, their systems and materials that are adapted to strict medical requirements. We described herein a medical-grade thermoplastic polyurethane (S-TPU) which was developed and then formed into a filament for Fused Deposition Modeling (FDM) 3D printers during a melt-extrusion process. S-TPU consisting of aliphatic hexamethylene 1,6-diisocyanate (HDI), amorphous α,ω-dihydroxy(ethylene-butylene adipate) (PEBA) and 1,4 butandiol (BDO) as a chain extender, was synthesized without the use of a catalyst. The filament (F-TPU) properties were characterized by rheological, mechanical, physico-chemical and in vitro biological properties. The tests showed biocompatibility of the obtained filament as well as revealed no significant effect of the filament formation process on its properties. This study may contribute to expanding the range of medical-grade flexible filaments for standard low-budget FDM printers.

scholarly journals Medical-Grade PCL Based Polyurethane System for FDM 3D Printing—Characterization and Fabrication

Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 887 ◽  
Author(s):  
Agnieszka Haryńska ◽  
Justyna Kucinska-Lipka ◽  
Agnieszka Sulowska ◽  
Iga Gubanska ◽  
Marcin Kostrzewa ◽  
...  
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Extrusion Process ◽  
C2c12 Cells ◽  
Hexamethylene Diisocyanate ◽  
Scanning Calorimetry ◽  
Thermoplastic Polyurethanes ◽  
Fused Deposition ◽  
Medical Grade

The widespread use of three-dimensional (3D) printing technologies in medicine has contributed to the increased demand for 3D printing materials. In addition, new printing materials that are appearing in the industry do not provide a detailed material characterization. In this paper, we present the synthesis and characterization of polycaprolactone (PCL) based medical-grade thermoplastic polyurethanes, which are suitable for forming in a filament that is dedicated to Fused Deposition Modeling 3D (FDM 3D)printers. For this purpose, we synthesized polyurethane that is based on PCL and 1,6-hexamethylene diisocyanate (HDI) with a different isocyanate index NCO:OH (0.9:1, 1.1:1). Particular characteristics of synthesized materials included, structural properties (FTIR, Raman), thermal (differential scanning calorimetry (DSC), thermogravimetric analysis (TGA)), mechanical and surfaces (contact angle) properties. Moreover, pre-biological tests in vitro and degradation studies were also performed. On the basis of the conducted tests, a material with more desirable properties S-TPU(PCL)0.9 was selected and the optimization of filament forming via melt-extrusion process was described. The initial biological test showed the biocompatibility of synthesized S-TPU(PCL)0.9 with respect to C2C12 cells. It was noticed that the process of thermoplastic polyurethanes (TPU) filaments forming by extrusion was significantly influenced by the appropriate ratio between the temperature profile, rotation speed, and dosage ratio.

scholarly journals Polyurethanes as a Potential Medical-Grade Filament for Use in Fused Deposition Modeling 3D Printers – a Brief Review

2018 ◽  
Vol 26 (6(132)) ◽  
pp. 120-125 ◽  
Author(s):  
Agnieszka Przybytek ◽  
Iga Gubańska ◽  
Justyna Kucińska-Lipka ◽  
Helena Janik
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Thermoplastic Elastomer ◽  
Medical Field ◽  
Fused Deposition ◽  
Basic Operating ◽  
3D Printers ◽  
Deposition Modeling ◽  
Medical Materials ◽  
Medical Grade

The possibility of using 3D printing technology (3DP) in medical field is a kind of revolution in health care. This has contributed to a rapid growth in demand for 3D printers, whose systems and materials are adapted to strict medical requirements. In this paper, we report a brief review of polyurethanes as a potential medical-grade filament for use in Fused Deposition Modeling (FDM) 3D printer technology. The advantages of polyurethanes as medical materials and the basic operating principles of FDM printers are presented. The review of present solutions in the market and literature data confirms the large interest in 3D printing technologies for the production of advanced medical devices. In addition, it is shown that thermoplastic-elastomer polyurethanes may be an effective widespread class of material in the market as thermoplastic filament for FDM 3D printers.

scholarly journals Influence of the Halloysite Nanotube (HNT) Addition on Selected Mechanical and Biological Properties of Thermoplastic Polyurethane

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3625
Author(s):  
Maciej Mrówka ◽  
Małgorzata Szymiczek ◽  
Tomasz Machoczek ◽  
Mirosława Pawlyta
Keyword(s):  
Fused Deposition Modeling ◽  
Thermoplastic Polyurethane ◽  
Tensile Modulus ◽  
Biological Properties ◽  
Mechanical Tests ◽  
Halloysite Nanotube ◽  
Fused Deposition ◽  
Transmission Electron ◽  
Scanning Transmission ◽  
Deposition Modeling

Halloysite nanotube (HNT) additions to the thermoplastic polyurethane (TPU) system were thoroughly evaluated in this study. The resultant composites have been designed for future personalized intervertebral disc implant applications, which requires additional technology to obtain the appropriate geometry unique to each patient. These requirements can be fulfilled using 3D printing. In this work, a technology was developed to produce filaments for fused deposition modeling (FDM). Nanocomposites were prepared using variable HNT content (1, 2, and 3 wt.%). The nanostructure of the resultant composites was confirmed using scanning transmission electron microscopy (STEM). Mechanical tests were used to measure the tensile modulus, stress, and elongation the composites and TPU matrix. Nanocomposites with 2% HNT content were able to withstand 26% increased stress and 50% increased elongation compared to pure TPU before fracturing in addition to a 13% reduction in the friction coefficient. A MTT cytotoxicity assay confirmed the cytotoxicity of all tested materials against human epidermal keratinocyte cells (HaCaT).

Simulation of the viscoplastic extrusion process using the radial point interpolation meshless method

2021 ◽  
pp. 146442072098858
Author(s):  
ROSS Costa ◽  
J Belinha ◽  
RM Natal Jorge ◽  
DES Rodrigues
Keyword(s):  
Meshless Method ◽  
Fused Deposition Modeling ◽  
Interpolation Method ◽  
Extrusion Process ◽  
Fused Deposition ◽  
Radial Point Interpolation ◽  
Large Growth ◽  
Point Interpolation Method ◽  
Point Interpolation ◽  
Deposition Modeling

Additive manufacturing is an emergent technology, which witnessed a large growth demanded by the consumer market. Despite this growth, the technology needs scientific regulation and guidelines to be reliable and consistent to the point that is feasible to be used as a source of manufactured end-products. One of the processes that has seen the most significant development is the fused deposition modeling, more commonly known as 3D printing. The motivation to better understand this process makes the study of extrusion of materials important. In this work, the radial point interpolation method, a meshless method, is applied to the study of extrusion of viscoplastic materials, using the formulation originally intended for the finite element method, the flow formulation. This formulation is based on the reasoning that solid materials under those conditions behave like non-Newtonian fluids. The time stepped analysis follows the Lagrangian approach taking advantage of the easy remeshing inherent to meshless methods. To validate the newly developed numerical tool, tests are conducted with numerical examples obtained from the literature for the extrusion of aluminum, which is a more common problem. Thus, after the performed validation, the algorithm can easily be adapted to simulate the extrusion of polymers in fused deposition modeling processes.

scholarly journals EFFECT OF EXTRUSION PROCESS PARAMETERS ON MECHANICAL PROPERTIES OF 3D PRINTED PLA PRODUCT

2021 ◽  
Vol 6 (2) ◽  
pp. 119
Author(s):  
Nanang Ali Sutisna ◽  
Rakha Amrillah Fattah
Keyword(s):  
Mechanical Properties ◽  
Additive Manufacturing ◽  
Fused Deposition Modeling ◽  
Extrusion Process ◽  
Experimental Procedure ◽  
Fused Deposition ◽  
Novel Approach ◽  
Deposition Modeling ◽  
3D Printed ◽  
3D Digital Models

The method of producing items through synchronously depositing material level by level, based on 3D digital models, is named Additive Manufacturing (AM) or 3D-printing. Amongs many AM methods, the Fused Deposition Modeling (FDM) technique along with PLA (Polylactic acid) material is commonly used in additive manufacturing. Until now, the mechanical properties of the AM components could not be calculated or estimated until they've been assembled and checked. In this work, a novel approach is suggested as to how the extrusion process affects the mechanical properties of the printed component to obtain how the parts can be manufactured or printed to achieve improved mechanical properties. This methodology is based on an experimental procedure in which the combination of parameters to achieve an optimal from a manufacturing experiment and its value can be determined, the results obtained show the effect of the extrusion process affects the mechanical properties.

scholarly journals 3D-Printed Soft Structure of Polyurethane and Magnetorheological Fluid: A Proof-of-Concept Investigation of its Stiffness Tunability

Micromachines ◽  
2019 ◽  
Vol 10 (10) ◽  
pp. 655 ◽  
Author(s):  
Seong-Woo Hong ◽  
Ji-Young Yoon ◽  
Seong-Hwan Kim ◽  
Sun-Kon Lee ◽  
Yong-Rae Kim ◽  
...  
Keyword(s):  
Fused Deposition Modeling ◽  
Permanent Magnets ◽  
Thermoplastic Polyurethane ◽  
Three Dimensional ◽  
Magnetorheological Fluid ◽  
Three Dimensional Printing ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
3D Printed ◽  
Dimensional Printing

In this study, a soft structure with its stiffness tunable by an external field is proposed. The proposed soft beam structure consists of a skin structure with channels filled with a magnetorheological fluid (MRF). Two specimens of the soft structure are fabricated by three-dimensional printing and fused deposition modeling. In the fabrication, a nozzle is used to obtain channels in the skin of the thermoplastic polyurethane, while another nozzle is used to fill MRF in the channels. The specimens are tested by using a universal tensile machine to evaluate the relationships between the load and deflection under two different conditions, without and with permanent magnets. It is empirically shown that the stiffness of the proposed soft structure can be altered by activating the magnetic field.

3D Printed PLA/PCL/TiO2 Composite for Bone Replacement and Grafting

MRS Advances ◽  
2018 ◽  
Vol 3 (40) ◽  
pp. 2373-2378 ◽  
Author(s):  
Sandra E. Nájera ◽  
Monica Michel ◽  
Nam-Soo Kim
Keyword(s):  
Biomedical Applications ◽  
Fused Deposition Modeling ◽  
Fracture Strain ◽  
Fused Deposition ◽  
In Vitro Biocompatibility ◽  
Bone Replacement ◽  
Deposition Modeling ◽  
3D Printed ◽  
The Stability

ABSTRACTPolymer composites of Polylactic acid (PLA) and poly-ε-caprolactone (PCL), containing small amounts of titanium oxide (TiO2) were developed for biomedical applications. These composite materials were prepared, and then printed using Fused Deposition Modeling (FDM). 3D printed structures were characterized to determine their mechanical properties and biocompatibility. DSC analysis yielded useful information regarding the immiscibility of the different polymers, and it was observed that the particles of TiO2 improved the stability of the polymers. The ultimate tensile strength and the fracture strain increased by adding TiO2 as a filler, resulting in values of approximately 45 MPa and 5.5 % elongation. The printed composites show excellent in vitro biocompatibility including cell proliferation and adhesion, and are therefore promising candidates to be used in the biomedical field for bone replacement procedures, due to their properties similar to those of cancellous bone.

scholarly journals In-vitro evaluation of Polylactic acid (PLA) manufactured by fused deposition modeling

2017 ◽  
Vol 11 (1) ◽  
Author(s):  
Matthias C. Wurm ◽  
Tobias Möst ◽  
Bastian Bergauer ◽  
Dominik Rietzel ◽  
Friedrich Wilhelm Neukam ◽  
...  
Keyword(s):  
Polylactic Acid ◽  
Fused Deposition Modeling ◽  
In Vitro Evaluation ◽  
Fused Deposition ◽  
Deposition Modeling
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