Application and Control of Periodic Crazing for Polymer Materials

2014 ◽  
Vol 70 (7) ◽  
pp. P-223-P-228 ◽  
Author(s):  
KEISHI NAITO
2018 ◽  
Vol 6 (46) ◽  
pp. 23197-23219 ◽  
Author(s):  
Yuya Oaki ◽  
Kosuke Sato

Recent advances in morphology design and control of organic polymer materials from nanoscopic to macroscopic scales, larger than the molecular scale, are summarized as crystal-controlled polymerization from a new perspective.


Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 713
Author(s):  
Józef Flizikowski ◽  
Weronika Kruszelnicka ◽  
Marek Macko

Recently, a dynamic increase in the number of polymer elements ending their life cycle has been observed. There are three main ways of dealing with polymer waste: reuse in an unchanged form, recycling (both material and energy), and disposal (mainly in the form of landfilling or incineration). The legislation of European countries promotes in particular two forms of waste management: reuse and recycling. Recycling processes are used to recover materials and energy especially from contaminated waste, which are structurally changed by other materials, friction, temperature, machine, process, etc. The recycling of polymers, especially of multi-plastic structural elements, requires the use of special technological installations and a series of preparatory operations, including crushing and separating. Due to the universality and necessity of materials processing in recycling engineering, in particular size reduction, the aim of this study is to organize and systematize knowledge about shredding in the recycling process of end-of-life polymeric materials. This could help properly design these processes in the context of sustainable development and circular economy. Firstly, an overview of the possibilities of end-of-life plastics management was made, and the meaning of shredding in the end-of-life pathways was described. Then, the development of comminution in recycling processes was presented, with special emphasis given to quasi-cutting as the dominant mode of comminution of polymeric materials. The phenomenon of quasi-cutting, as well as factors related to the material, the operation of the shredding machine, and the technological process affecting it were described. Research conducted on quasi-cutting as a phenomenon when cutting single material samples and quasi-cutting as a machine process was characterized. Then, issues regarding recycling potentials in the context of shredding were systematized. Considerations included the areas of material, technical, energy, human, and control potentials. Presented bases and models can be used to support the innovation of creative activities, i.e., environmentally friendly actions, that produce specific positive environmental results in the mechanical processing of recycled and reused materials. The literature survey indicates the need to explore the environmental aspect of the shredding process in recycling and connect the shredding process variables with environmental consequences. This will help to design and control the processes to get the lowest possible environmental burdens.


Mechanik ◽  
2018 ◽  
Vol 91 (4) ◽  
pp. 274-277
Author(s):  
Maciej Heneczkowski

In the manuscript current trends in the area of modification of polymer materials, including composites, new processing techniques and manufacturing managing and control systems have been described.


Author(s):  
R. R. Dils ◽  
P. S. Follansbee

Electric fields have been applied across oxides growing on a high temperature alloy and control of the oxidation of the material has been demonstrated. At present, three-fold increases in the oxidation rate have been measured in accelerating fields and the oxidation process has been completely stopped in a retarding field.The experiments have been conducted with an iron-base alloy, Pe 25Cr 5A1 0.1Y, although, in principle, any alloy capable of forming an adherent aluminum oxide layer during oxidation can be used. A specimen is polished and oxidized to produce a thin, uniform insulating layer on one surface. Three platinum electrodes are sputtered on the oxide surface and the specimen is reoxidized.


Author(s):  
D. M. DePace

The majority of blood vessels in the superior cervical ganglion possess a continuous endothelium with tight junctions. These same features have been associated with the blood brain barrier of the central nervous system and peripheral nerves. These vessels may perform a barrier function between the capillary circulation and the superior cervical ganglion. The permeability of the blood vessels in the superior cervical ganglion of the rat was tested by intravenous injection of horseradish peroxidase (HRP). Three experimental groups of four animals each were given intravenous HRP (Sigma Type II) in a dosage of.08 to.15 mg/gm body weight in.5 ml of.85% saline. The animals were sacrificed at five, ten or 15 minutes following administration of the tracer. Superior cervical ganglia were quickly removed and fixed by immersion in 2.5% glutaraldehyde in Sorenson's.1M phosphate buffer, pH 7.4. Three control animals received,5ml of saline without HRP. These were sacrificed on the same time schedule. Tissues from experimental and control animals were reacted for peroxidase activity and then processed for routine transmission electron microscopy.


Author(s):  
G. Mazzocchi ◽  
P. Rebuffat ◽  
C. Robba ◽  
P. Vassanelli ◽  
G. G. Nussdorfer

It is well known that the rat adrenal zona glomerulosa steroidogenic activity is controlled by the renin-angiotensin system. The ultrastructural changes in the rat zona glomerulosa cells induced by renovascular hypertension were described previously, but as far as we are aware no correlated biochemical and morphometric investigations were performed.Twenty adult male albino rats were divided into 2 experimental groups. One group was subjected to restriction of blood flow to the left kidney by the application of a silver clip about the left renal artery. The other group was sham-operated and served as a control. Renovascular hypertension developed in about 10 days: sistolic blood pressure averaged 165 ± 6. 4 mmHg, whereas it was about 110 ± 3. 8 mmHg in the control animals. The hypertensive and control rats were sacrificed 20 days after the operation. The blood was collected and plasma renin activity was determined by radioimmunological methods. The aldosterone concentration was radioimmunologically assayed both in the plasma and in the homogenate of the left capsular adrenal gland.


Author(s):  
Henry I. Smith ◽  
D.C. Flanders

Scanning electron beam lithography has been used for a number of years to write submicrometer linewidth patterns in radiation sensitive films (resist films) on substrates. On semi-infinite substrates, electron backscattering severely limits the exposure latitude and control of cross-sectional profile for patterns having fundamental spatial frequencies below about 4000 Å(l),Recently, STEM'S have been used to write patterns with linewidths below 100 Å. To avoid the detrimental effects of electron backscattering however, the substrates had to be carbon foils about 100 Å thick (2,3). X-ray lithography using the very soft radiation in the range 10 - 50 Å avoids the problem of backscattering and thus permits one to replicate on semi-infinite substrates patterns with linewidths of the order of 1000 Å and less, and in addition provides means for controlling cross-sectional profiles. X-radiation in the range 4-10 Å on the other hand is appropriate for replicating patterns in the linewidth range above about 3000 Å, and thus is most appropriate for microelectronic applications (4 - 6).


Author(s):  
Amankwah K.S. ◽  
A.D. Weberg ◽  
R.C. Kaufmann

Previous research has revealed that passive (involuntary inhalation) tobacco smoking during gestation can have adverse effects upon the developing fetus. These prior investigations did not concentrate on changes in fetal morphology. This study was undertaken to delineate fetal neural abnormalities at the ultrastructural level in mice pups exposed in utero to passive maternal smoking.Pregnant study animals, housed in a special chamber, were subjected to cigarette smoke daily from conception until delivery. Blood tests for determination of carbon monoxide levels were run at 15-18 days gestation. Sciatic nerve tissue from experimental and control animals were obtained following spontaneous delivery and fixed in 2.5% gluteraldehyde in 0.1M cacodylate buffer pH 7.3. The samples were post-fixed in osmium ferrocyanide (1:1 mixture of 1.5% aqueous OSO4 and 2.5% K4 Fe(CN)6). Following dehydration, the tissues were infiltrated with and embedded in Spurr. Sections were stained with uranyl acetate and lead citrate.


Author(s):  
R. E. Worsham ◽  
J. E. Mann ◽  
E. G. Richardson

This superconducting microscope, Figure 1, was first operated in May, 1970. The column, which started life as a Siemens Elmiskop I, was modified by removing the objective and intermediate lenses, the specimen chamber, and the complete vacuum system. The large cryostat contains the objective lens and stage. They are attached to the bottom of the 7-liter helium vessel and are surrounded by two vapor-cooled radiation shields.In the initial operational period 5-mm and 2-mm focal length objective lens pole pieces were used giving magnification up to 45000X. Without a stigmator and precision ground pole pieces, a resolution of about 50-100Å was achieved. The boil-off rate of the liquid helium was reduced to 0.2-0.3ℓ/hour after elimination of thermal oscillations in the cryostat. The calculated boil-off was 0.2ℓ/hour. No effect caused by mechanical or electrical instability was found. Both 4.2°K and 1.7-1.9°K operation were routine. Flux pump excitation and control of the lens were quite smooth, simple, and, apparently highly stable. Alignment of the objective lens proved quite awkward, however, with the long-thin epoxy glass posts used for supporting the lens.


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