Determination of Adsorption-Retention Constants and Inaccessible Pore Volume for High-Molecular Polymers

2021 ◽  
Author(s):  
Konstantin Mikhailovich Fedorov ◽  
Tatyana Anatolyevna Pospelova ◽  
Aleksandr Vyacheslavovich Kobyashev ◽  
Aleksandr Yanovich Gilmanov ◽  
Tatyana Nikolaevna Kovalchuk ◽  
...  

Abstract The application of chemical enhanced oil recovery methods is based mainly on data from experiments. Determining the adsorption constants without destroying the sample remains a relevant problem. It is necessary for accurate data. The determination of filtration parameters of high-molecular polymers in a porous medium using special model is considered in this paper. The aim of the investigation is the solution of inverse problem of polymer transport with adsorption. The key data for this are the characteristic times of the polymer front propagation, water and rock densities, porosity, and initial polymer concentration. The solutions of the direct problem and the inverse problem from the characteristic form of equations are obtained. The algorithm of interpretation of adsorption-retention parameters and inaccessible pore volume form non-destructive experimental studies is developed. Comparison of the calculated values of the inaccessible pore volume with the results of laboratory studies leads to an error within 10%. The practical application of the algorithm was carried out using the data obtained in previously conducted experiments.

1975 ◽  
Vol 15 (04) ◽  
pp. 323-337 ◽  
Author(s):  
M.T. Szabo

Abstract Numerous single-phase flow and oil-recovery tests were carried out in unconsolidated sands and Berea sandstone cores using C14-tagged, hydrolyzed polyacrylamide solutions. The polymer-retention polyacrylamide solutions. The polymer-retention data from these flow tests are compared with data obtained from static adsorption tests. Polymer concentrations in produced water in Polymer-flooding tests were studied using various Polymer-flooding tests were studied using various polymer concentrations, slug sizes, salt polymer concentrations, slug sizes, salt concentrations, and different permeability sands. Results show that polymer retention by mechanical entrapment had a dominant role in determining the total polymer retention in short sand packs. However, the role of mechanical entrapment was less in the large-surface-area Berea cores. In oil-recovery tests, high polymer concentrations were noted at water breakthrough in sand-pack experiments, an indication that the irreducible water was not displaced effectively ahead of the polymer slug. However, in similar tests with Berea cores, a denuded zone developed at the leading edge of the polymer slug. polymer slug. The existence of inaccessible pore volume to polymer flow is shown both in sand packs and in polymer flow is shown both in sand packs and in sandstone cores. Absolute polymer-retention values show an almost linear dependency on polymer concentration. The effect of polymer slug size on absolute polymer retention is also discussed. Distribution of retained polymer in sand packs showed an exponential decline with distance. The "dynamic polymer-retention" values in short sand packs showed much higher vales than the ‘static packs showed much higher vales than the’ static polymer-adsorption" values caused by mechanical polymer-adsorption" values caused by mechanical entrapment. The mechanism of polymer retention in silica sands and sandstones is described, based on the observed phenomenon. Introduction It is widely recognized that, as polymer solution flows in a porous medium, a portion of the polymer is retained. It is evident that both physical adsorption and mechanical entrapment contribute to polymer retention. The question of the relative importance of these retention mechanisms has not been studied adequately. The effect of residual oil saturation on polymer retention and the polymer retention during the displacement of oil from porous media has also been studied inadequately. Mungen et al. have reported a few data on polymer concentration in produced water in oil-recovery tests. However, no produced water in oil-recovery tests. However, no comparison was made between polymer retention at 100-percent water saturation and at partial oil saturation. It has been shown that the actual size of the flowing polymer molecules, with the associated water, can approach the dimensions of certain smaller pores found in porous media. Therefore, an inaccessible pore volume exists in which no polymer flow occurs. In this study, the existence polymer flow occurs. In this study, the existence of inaccessible pore volume is shown clearly, both in sand and sandstone. Although polymer-retention values have been reported for various conditions, correlation is difficult because of the differing conditions of measurements. The effect of slug size, polymer concentration, salinity, and type of porous media on polymer retention has not been systematically studied. The purpose of this study was to develop answers to these questions, rather than to provide adsorption data for actual field core samples. For this reason, unconsolidated silica sands were used in most of the experiments reported. This permitted identical, uniform single-layer and multilayer porous media to be constructed for repeated experiments under varying test conditions. Some experiments were also carried out in Berea sandstone cores to determine whether sand-pack results can be extrapolated to consolidated sandstones. Using a C 14-tagged polymer provided a very rapid, simple, and accurate polymer-concentration determination technique. SPEJ P. 323


2016 ◽  
pp. 120-125
Author(s):  
M. Ya. Habibullin ◽  
R. R. Shangareyev

The article deals with the issues related to the hydrocarbon reservoirs oil recovery enhancement. It describes the bench laboratory experimental studies. The results obtained during determination of fluid leakage through the rock samples and the amount of absorption of pressure fluctuations at various regime parameters are presented. Using the experimental data the regression analysis was performed on the basis of which the qualitative correlations between factorial and resultant features were identified. Using the regression equations the graphic relations were constructed. It was found that with increasing the oscillation frequency of the fluid the amount of fluid passing through the sample of porous medium increased, with the highest value of q reached at the frequency range of 600 ... 1000 Hz. With increase in the oscillations penetration depth the absorption of the amplitude of the pressure fluctuations corresponds to the linear decrease, and with the overburden pressure increase the linear variation of absorption is distorted.


2014 ◽  
Vol 17 (03) ◽  
pp. 314-325 ◽  
Author(s):  
R.N.. N. Manichand ◽  
R.S.. S. Seright

Summary During a polymer flood, polymer retention can have a major impact on the rate of polymer propagation through a reservoir, and consequently on oil recovery. A review of the polymer-retention literature revealed that iron and high-surface-area minerals (e.g., clays) dominate polymer-retention measurements in permeable rock and sand (>100 md). A review of the literature on inaccessible pore volume (IAPV) revealed inconsistent and unexplained behavior. A conservative approach to design of a polymer flood in high-permeability (>1 darcy) sands would assume that IAPV is zero. Laboratory measurements using fluids and sands associated with the Sarah Maria polymer flood in Suriname suggested polymer retention and IAPV values near zero [0±20 μg/g for retention and 0±10% pore volume (PV) for IAPV]. A procedure was developed using salinity-tracer and polymer concentrations from production wells to estimate polymer retention during the Sarah Maria polymer flood in the Tambaredjo reservoir. Field calculations indicated much higher polymer-retention values than those from laboratory tests, typically ranging from approximately 50 to 250 μg/g. Field cores necessarily represent an extremely small fraction of the reservoir. Because of the importance of polymer retention, there is considerable value in deriving polymer retention from field results, so that information can be used in the design of project expansions.


2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Agnieszka Dudzińska

In this paper the results of the experimental studies on a relationship between pore volume of hard coals and their tendency to spontaneous combustion are presented. Pore volumes were determined by the gas adsorption method and spontaneous combustion tendencies of coals were evaluated by determination of the spontaneous combustion indexesSzaandSza′on the basis of the current Polish standards. An increase in the spontaneous combustion susceptibility of coal occurs in the case of the rise both in micropore volumes and in macropore surfaces. Porosity of coal strongly affects the possibility of oxygen diffusion into the micropores of coal located inside its porous structure. The volume of coal micropores determined on the basis of the carbon dioxide adsorption isotherms can serve as an indicator of a susceptibility of coal to spontaneous combustion.


1978 ◽  
Vol 18 (01) ◽  
pp. 5-12 ◽  
Author(s):  
S.P. Gupta

Abstract This study shows the factors that affect the polymer mobility buffer bank, that is, slug size and polymer mobility buffer bank, that is, slug size and concentration. The slug size is a function of polymer/chase-water mixing, polymer inaccessible polymer/chase-water mixing, polymer inaccessible pore volume (IPV), and polymer retention. The pore volume (IPV), and polymer retention. The designed polymer concentration depends on polymer apparent viscosity and, to varying degrees, on shear degradation. The polymer/chase-water mixing-zone volume at a given mobility ratio is the same for glycerine (classical miscible fluid), biopolymer, and polyacrylamide. However, the propagation rate of the polyacrylamide. However, the propagation rate of the mining zone is much higher for polymer than for glycerine because of IPV. Therefore, a larger polymer bank is required to protect the micellar polymer bank is required to protect the micellar slug than would be indicated by mixing-zone volume alone. IPV increased as polymer concentration decreased over the investigated range. A micellar fluid ahead of the polymer bank increased IPV. When polyacrylamides are used in the mobility buffer bank, their concentration should be increased to compensate for the effect of shear degradation. For each field application, shear-degradation tests should be conducted in field cores using field brine and at anticipated sand-face velocities. The loss of polyacrylamide effectiveness because of shear degradation should be determined from apparent viscosity measurement of the sheared polymer, not from polymer concentration, Brookfield viscosity, or screen factor. Introduction In a micellar flood, water-soluble polymers are used as a mobility buffer to protect the micellar slug from invasion by high-mobility chase water. In addition, polymer may be added to the micellar fluid to adjust viscosity, to improve sweep in a waterflood, as a preflush in micellar flood to improve the sweep, to control water production in producers, and for selective partial plugging of high-permeability thief zones. Biopolymers (Xanthan gum) and polyacrylamides are two classes of polymers most commonly used in oil recovery processes. processes. When designing a polymer slug for field application, proper sizing and chemical concentration are critical variables. In a micellar flood, the polymer-mobility buffer-bank size depends on polymer inaccessible pore volume (IPV), mixing, polymer inaccessible pore volume (IPV), mixing, and polymer retention. Because the primary purpose of the polymer bank is to provide adequate mobility control, a sufficient polymer concentration must be selected. However, the concentration for polyacrylamides often must be increased to account polyacrylamides often must be increased to account for losses resulting from shear degradation. This study was undertakento determine the magnitude of and variables affecting polymer inaccessible pore volume (IPV),to characterize the effect of IPV on polymer/chase-water mixing behavior, andto examine polyacrylamide shear degradation. In these IPV and mixing studies, the biopolymer is Kelzan MF TM (Xanflood); and the polyacrylamide is Dow Pusher 500. In shear polyacrylamide is Dow Pusher 500. In shear degradation studies, the polyacrylamides are Dow Pusher 500, Pusher 700, and Amoco Chemicals Pusher 500, Pusher 700, and Amoco Chemicals Sweepaid 105 (an experimental polymer). POLYMER INACCESSIBLE PORE VOLUME POLYMER INACCESSIBLE PORE VOLUME Polymers propagate through porous media more rapidly than through their carrier water. The pore space volume available for polymer flow is pore space volume available for polymer flow is less than the volume available to water. The volume in which polymer cannot flow commonly is called polymer inaccessible pore volume (IPV). The polymer inaccessible pore volume (IPV). The exact mechanism of IPV is not clear. However, it has been estimated that the polymer molecule size is of the same order as pore sizes in rock. In many cases, the smaller rock pores are not capable of transporting polymer molecules, but can transport water. Another phenomenon possibly contributing to IPV is the inability of the polymer molecule center to get near the pore wall. As a result, the average velocity of the polymer molecules is greater than that of water molecules. SPEJ p. 5


2020 ◽  
Author(s):  
Boni Swadesi ◽  
Erdico Prasidya Saktika ◽  
Mahruri Sanmurjana ◽  
Septoratno Siregar ◽  
Dyah Rini

2021 ◽  
Vol 14 (04) ◽  
pp. 239-258
Author(s):  
M. F. Zampieri ◽  
C. C. Quispe ◽  
R. B. Z. L. Moreno

Polymer flooding has been widely used for enhancing oil recovery, due to the growing number of successful applications around the world. The process aims to increase water viscosity and, thus, decrease the water/oil mobility ratio, thereby improving sweep efficiency. The understanding of the physical mechanisms involved in this enhanced oil recovery process allows us to forecast the application potential of polymer flooding. This work aims to assess physical phenomena associated with heavy oil recovery through polymer flooding using 1D small-scale simulation models. We evaluate the influence of different levels of adsorption, accessible pore volume, residual resistance factor, and polymer concentration on the results and compare their magnitude effect on the results. The models used in this study were built using data from previous lab work and literature. For each one of the mentioned parameters, this work compares the histories of water cut, cumulative water-oil ratio, average pressure, and oil recovery factor. Additionally, water saturation, water viscosity, and water mobility profile were determined for specific periods of the flooding process. The sensitivity analyses showed that high levels of adsorption influence the polymer loss of the advance front, delaying oil recovery. Low values of accessible pore volume lead to a slightly faster polymer breakthrough and oil recovery anticipation. A high residual resistance factor increases the average pressure and improves oil recovery. Higher polymer concentration enhances the displacement efficiency and enhances the recovery factor.


Problems when calculating reinforced concrete structures based on the concrete deformation under compression diagram, which is presented both in Russian and foreign regulatory documents on the design of concrete and reinforced concrete structures are considered. The correctness of their compliance for all classes of concrete remains very approximate, especially a significant difference occurs when using Euronorm due to the different shape and sizes of the samples. At present, there are no methodical recommendations for determining the ultimate relative deformations of concrete under axial compression and the construction of curvilinear deformation diagrams, which leads to limited experimental data and, as a result, does not make it possible to enter more detailed ultimate strain values into domestic standards. The results of experimental studies to determine the ultimate relative deformations of concrete under compression for different classes of concrete, which allowed to make analytical dependences for the evaluation of the ultimate relative deformations and description of curvilinear deformation diagrams, are presented. The article discusses various options for using the deformation model to assess the stress-strain state of the structure, it is concluded that it is necessary to use not only the finite values of the ultimate deformations, but also their intermediate values. This requires reliable diagrams "s–e” for all classes of concrete. The difficulties of measuring deformations in concrete subjected to peak load, corresponding to the prismatic strength, as well as main cracks that appeared under conditions of long-term step loading are highlighted. Variants of more accurate measurements are proposed. Development and implementation of the new standard GOST "Concretes. Methods for determination of complete diagrams" on the basis of the developed method for obtaining complete diagrams of concrete deformation under compression for the evaluation of ultimate deformability of concrete under compression are necessary.


1983 ◽  
Vol 27 ◽  
Author(s):  
L. Salamanca-Riba ◽  
B.S. Elman ◽  
M.S. Dresselhaus ◽  
T. Venkatesan

ABSTRACTRutherford backscattering spectrometry (RBS) is used to characterize the stoichiometry of graphite intercalation compounds (GIC). Specific application is made to several stages of different donor and acceptor compounds and to commensurate and incommensurate intercalants. A deviation from the theoretical stoichiometry is measured for most of the compounds using this non-destructive method. Within experimental error, the RBS results agree with those obtained from analysis of the (00ℓ) x-ray diffractograms and weight uptake measurements on the same samples.


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