Geochemical Characteristics of the Campano-Maastrictian Sediments of the Anambra Basin, Southeastern Nigeria - Implication For Provenance, Paleodepositional Environment, Maturity and Tectonic Setting

2021 ◽  
Author(s):  
Michael Edirin Okiotor ◽  
EDeh Desiree Ogueh
Keyword(s):  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Passive Margin ◽  
Source Rocks ◽  
Sediment Provenance ◽  
Southeastern Nigeria ◽  
Inductively Coupled ◽  
Anambra Basin ◽  
Plasma Mass Spectrometry ◽  
Chemical Index Of Alteration

Abstract The present study investigates the Anambra Basin shales to determine the provenance and maturity of the sediments using standard geochemical techniques. Twelve (12) representative samples recovered from shale sequences of The Mamu Formation and Nkporo Group of The Anambra Basin were studied to determine the sediment provenance, paleoenvironment, diagenetic conditions, maturity as well as the tectonic setting. To consider in detail and establish the inherent constituents of the Major minerals, Trace and Rare Earth elements, Inductively Coupled Plasma Mass Spectrometry (ICP-MS) analyses techniques was employed. The detrital minerals determined are Al2O3 (18.27% and 21.16%), TiO2 (1.73% and 1.63%) and Fe2O3 (2.78% \ and 2.85%), for Nkporo Group and Mamu Formation respectively. The enrichment of SiO2, Al2O3 and TiO2 (1.14, 1.94, 3.67 respectively) supported by Chemical Index of Alteration (CIA) of 93.54 & 39.55 and Rb/Sr ratio of 0.57 & 0.40, indicate that the Anambra Basin sediments are matured. TiO2/AL2O3 binary plots, Th/Co Vs La/Sc crossplots, Th-Sc-Zr triplots and Cr, Ni concentration suggest mixed provenance of felsic to mafic source rocks for these sediments. From the log (K2O/Na2O) Vs SiO2 crossplots, a passive margin tectonic setting was determined for these sediments.

scholarly journals Geochemistry of Fluvial Sediments from Geregu, Southwest Nigeria

2017 ◽  
Vol 64 (1) ◽  
pp. 35-52 ◽  
Author(s):  
Emmanuel E. Adiotomre ◽  
Innocent O. Ejeh ◽  
Edwin O. Adaikpoh
Keyword(s):  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Passive Margin ◽  
Fluvial Sediments ◽  
Geochemical Analysis ◽  
Sediment Samples ◽  
Inductively Coupled ◽  
Southwest Nigeria ◽  
Plasma Mass Spectrometry ◽  
Quartz Grains

Abstract Geochemical analysis of fluvial sediments on the banks of River Ero using inductively coupled plasma mass spectrometry illustrates their maturity, provenance and tectonic setting. The analysed sediment samples show low SiO2/Al2O3 ratios of 2.92-2.99 (units FL_A, FL_B and FL_E) and high SiO2/Al2O3 ratios of 4.064-4.852 (units FL_C, FL_D, FL_F and FL_G). Sediments were geochemically classified as shales (units FL_A, FL_B and FL_E) and greywackes (units FL_C, FL_D, FL_F and FL_G). Variability in sediment maturity (FL_F > FL_G >FL_C >FL_D >FL_A > FL_B > FL_E) parallels a decreasing order in the ratios of SiO2/Al2O3 and K2O/Al2O3, as well as the proportion of quartz grains and matrix components. Evidence from Al2O3/TiO2, K2O, Rb, La/Co, Th/Co, Cr/ Th, Th/Cr, La/Th-Hf, Th-Hf-Co and rare earth element contents of sediment samples suggest felsic protoliths of upper continental crust in a passive margin tectonic setting. An insignificant contribution of mafic components from the source is, however, inferred based on the Ni and Cr contents of the sediment samples. Combined Eu anomalies <0.85 and (Gd/Yb)n ratios <2.0 (1.53- 1.82, average 1.65) suggest post-Archean protoliths.

Discussion of the reply by R.L. Romer and U. Kroner on “Geochemical signature of Ordovician Mn-rich sedimentary rocks on the Avalonian shelf” 1Appears in Canadian Journal of Earth Sciences, 49(6): 775–780, 10.1139/e2012-006.

2012 ◽  
Vol 49 (11) ◽  
pp. 1372-1377
Author(s):  
David I. Schofield ◽  
John W.F. Waldron ◽  
Chris E. White ◽  
Sandra M. Barr
Keyword(s):  
Inductively Coupled Plasma ◽  
Sedimentary Rocks ◽  
Sediment Provenance ◽  
Inductively Coupled ◽  
Geochemical Signature ◽  
North Wales ◽  
Plasma Mass Spectrometry ◽  
History Of ◽  
Spectrometry Technique ◽  
Depositional Age

In their article ‘Reply to the discussion by J.W.F. Waldron and C.E. White on “Geochemical signature of Ordovician Mn-rich sedimentary rocks on the Avalonian shelf”’, R.L. Romer and U. Kroner reinterpret geochronological data presented by J.W.F. Waldron, D.I. Schofield, C.E. White, and S.M. Barr to imply an Ordovician, not a Cambrian, depositional age for the succession of the Harlech Dome, North Wales, and Meguma Supergroup, Nova Scotia. However, an extensive history of biostratigraphic and geological survey data refutes this interpretation and shows that the rocks are unequivocally Cambrian. Waldron et al. used the U–Pb zircon laser-ablation – multicollector – inductively coupled plasma – mass spectrometry technique primarily to provide information on sediment provenance and not depositional age. Investigation of anomalously young 206Pb/238U ages showed evidence of Pb loss. These data provide little constraint on depositional age and cannot be used to infer that the Harlech Grits Group is Ordovician.

Detrital zircon populations in quartzites of the Krkonoše–Jizera Massif: implications for pre-collisional history of the Saxothuringian Domain in the Bohemian Massif

2011 ◽  
Vol 149 (3) ◽  
pp. 443-458 ◽  
Author(s):  
ELIŠKA ŽÁČKOVÁ ◽  
JIŘÍ KONOPÁSEK ◽  
JAN KOŠLER ◽  
PETR JEŘÁBEK
Keyword(s):  
Detrital Zircon ◽  
Inductively Coupled Plasma ◽  
Detrital Zircons ◽  
Passive Margin ◽  
Inductively Coupled ◽  
Northwestern Margin ◽  
Plasma Mass Spectrometry ◽  
History Of ◽  
Early Palaeozoic ◽  
Ordovician Granitoids

AbstractAge spectra of detrital zircons from metamorphosed quartzites of the Krkonoše–Jizera Massif in the northeastern part of the Saxothuringian Domain were obtained by U–Pb laser ablation inductively coupled plasma mass spectrometry dating. The zircon ages cluster in the intervals of 450–530 Ma and 550–670 Ma, and show individual data between 1.6 and 3.1 Ga. Zircons in the analysed samples are predominantly of Cambrian–Ordovician and Neoproterozoic age, and the marked peak at c. 525–500 Ma suggests a late Cambrian maximum age for the sedimentary protolith. Detritus of the quartzites probably originated from the erosion of Cambrian–Ordovician granitoids and their Neoproterozoic (meta)sedimentary or magmatic country rocks. The lack of Neoproterozoic (meta)sedimentary rocks in the central and eastern part of the Krkonoše–Jizera Massif suggests that the country rocks to voluminous Cambrian–Ordovician magmatic bodies were largely eroded during the formation of early Palaeozoic rift basins along the southeast passive margin of the Saxothuringian Domain. The detrital zircon age spectra confirm the previous interpretation that the exposed basement, dominated by Neoproterozoic to Cambrian–Ordovician granitoids, was overthrust during Devonian–Carboniferous subduction–collision processes by nappes composed of metamorphosed equivalents of the uppermost Cambrian–Devonian passive margin sedimentary formations. Only a negligible number of Mesoproterozoic ages, typically from the Grenvillian event, supports the interpretation that the Saxothuringian Neoproterozoic basement has an affinity to the West African Craton of the northwestern margin of Gondwana.

Further detrital zircon evidence for peri-Gondwanan blocks in the central Appalachian Piedmont Province, USA

2019 ◽  
Vol 56 (10) ◽  
pp. 1061-1076
Author(s):  
Aaron J. Martin ◽  
Howell Bosbyshell
Keyword(s):  
Detrital Zircon ◽  
Inductively Coupled Plasma ◽  
Mass Spectrometry Data ◽  
Sediment Provenance ◽  
Inductively Coupled ◽  
Depleted Mantle ◽  
Plasma Mass Spectrometry ◽  
Appalachian Piedmont ◽  
Detrital Zircon Ages ◽  
Piedmont Province

Evidence for exotic terranes in the central Appalachian Piedmont Province is fragmented between central Virginia, northern Maryland, and southeastern Pennsylvania. Here we present laser ablation-inductively coupled plasma mass spectrometry data from detrital zircon that support the presence of an exotic terrane in this region. U–Pb dating of detrital zircon from new samples of the Storck quartzite (central Virginia) and the Hoods Mill rocks (northern Maryland) confirms the presence of a major peak at ca. 630–610 Ma in these units. These ages are consistent with derivation from Gondwana, but not Ediacaran Laurentia. Further, modern εHf values of five of the ca. 670–580 Ma grains in these samples are inconsistent with derivation from the few plutons of this age in Ediacaran Laurentia. The Loch Raven Schist and a metasedimentary xenolith in the Wilmington Complex contain a smaller proportion of ca. 670–580 Ma grains than the Storck quartzite and the Hoods Mill rocks, but more such grains than in sediment derived from Ediacaran Laurentia, so we tentatively conclude that these two units also received sediment from Gondwana. Detrital zircon ages from the Piney Run Formation, Pleasant Grove Schist, Prettyboy Schist, and Wissahickon Formation allow sediment provenance solely in Ediacaran Laurentia. We also present new zircon spot U–Pb and Lu–Hf isotopic data from western Newfoundland plutons for comparison with these types of data from the detrital zircon. Intrusion ages of the Steel Mountain Anorthosite, Disappointment Hill Tonalite, and Round Pond Granite are 608 ± 12, 600 ± 8, and 590 ± 9 Ma, respectively. None of these units was derived entirely from the depleted mantle.

Genesis and implications of the Late Jurassic Hailesitai granites in the northern Greater Khingan Range: evidence from zircon U–Pb dating and Hf isotope

2016 ◽  
Vol 154 (5) ◽  
pp. 963-982 ◽  
Author(s):  
PINGPING ZHU ◽  
QIUMING CHENG ◽  
ZHENJIE ZHANG ◽  
ZIYE WANG
Keyword(s):  
Inductively Coupled Plasma ◽  
Late Jurassic ◽  
Tectonic Setting ◽  
Hf Isotope ◽  
Source Rocks ◽  
High Potassium ◽  
Inductively Coupled ◽  
Depleted Mantle ◽  
Two Stages ◽  
Extensional Collapse

AbstractThe tectonic setting and geodynamic model of the Greater Khingan Range (GKR) is highly controversial due to the lack of reliable geological, isotopic and geochronological evidence. In the current study, the Hailesitai pluton, located at the west of the suture between the northern and southern GKR in the east of the Central Asian Orogenic Belt, is selected to address this issue. These granites of the high potassium calc-alkaline series belong to the A1-type granites with typical geochemical characteristics including high contents of Al2O3, extremely low contents of Ti, P, enriched LREE, LILE, depleted HFSE, and a medium Eu negative anomaly. Laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) zircon U−Pb dating indicates that the granites can be divided into two stages: c. 152 and c. 161 Ma. The intrusion of A1-type granites at ~161 Ma implies that intra-plate orogenesis of the northern GKR started at c. 161 Ma at latest. The Hailesitai pluton has relatively homogeneous Hf isotope compositions with a εHf (t) value (+6.0 − +9.0), and two-stage depleted mantle model ages of 579−738 Ma show that the original magma is a mixture of juvenile and crustal source rocks. Extensional collapse of the Mongol−Okhotsk belt between the Siberia block and the northern GKR resulted in the formation of late Jurassic A1-type granites in the northern GKR. The Hailesitai pluton formed in response to post-orogenic extensional collapse of the Mongol–Okhotsk belt, coupled with back-arc extension related to Palaeo-Pacific plate subduction.

Field relationships, petrology, age, and tectonic setting of the Late Cambrian–Ordovician West Barneys River Plutonic Suite, southern Antigonish Highlands, Nova Scotia, Canada

2013 ◽  
Vol 50 (7) ◽  
pp. 727-745 ◽  
Author(s):  
D.B. Archibald ◽  
S.M. Barr ◽  
J.B. Murphy ◽  
C.E. White ◽  
T.G. MacHattie ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Inductively Coupled Plasma ◽  
Magma Mixing ◽  
Tectonic Setting ◽  
Alkali Feldspar ◽  
Chemical Compositions ◽  
Ionization Mass ◽  
The West ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry

The West Barneys River Plutonic Suite consists of gabbro, syenite-monzonite, alkali-feldspar syenite to quartz alkali-feldspar syenite, and alkali-feldspar granite outcropping in an area of ∼100 km2 in the southern Antigonish Highlands. Magma mixing and mingling textures indicate a comagmatic relationship between some of the mafic and intermediate–felsic lithologies. However, nine U–Pb (zircon) ages, three by thermal ionization mass spectrometry (TIMS) and six by laser-ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS), from the West Barneys River suite and the lithologically similar Cape Porcupine Complex located 60 km to the east range from ca. 495 to 460 Ma, indicating that emplacement occurred over a significant span of time. Intermediate to felsic rocks consist mainly of perthitic K-feldspar and variable amounts of quartz; interstitial granophyre is present in some samples, consistent with shallow emplacement. Mafic phases are Fe-rich amphibole and clinopyroxene, and in some units, fayalite. Intermediate and felsic samples have chemical characteristics of within-plate ferroan A-type granitoid rocks. Gabbroic rocks consist of plagioclase (oligoclase–labradorite) and augite/diopside with less abundant orthopyroxene, olivine, biotite, and ilmenite/magnetite. Their chemical compositions are transitional from tholeiitic to alkalic and characteristic of continental within-plate mafic rocks. The εNd values are similar in gabbroic, syenitic, and granitic samples, ranging between 0.9 and 4.9, consistent with a co-genetic origin for the mafic and intermediate/felsic components of the suite, and derivation from Avalonian subcontinental lithospheric mantle in an extensional environment.

scholarly journals Two stages of Late Carboniferous to Triassic magmatism in the Strandja Zone of Bulgaria and Turkey

2021 ◽  
pp. 1-14
Author(s):  
Anna Sałacińska ◽  
Ianko Gerdjikov ◽  
Ashley Gumsley ◽  
Krzysztof Szopa ◽  
David Chew ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Age Groups ◽  
Late Carboniferous ◽  
The Balkans ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Tethys Ocean ◽  
Two Stages

Abstract Although Variscan terranes have been documented from the Balkans to the Caucasus, the southeastern portion of the Variscan Belt is not well understood. The Strandja Zone along the border between Bulgaria and Turkey encompasses one such terrane linking the Balkanides and the Pontides. However, the evolution of this terrane, and the Late Carboniferous to Triassic granitoids within it, is poorly resolved. Here we present laser ablation – inductively coupled plasma – mass spectrometry (LA-ICP-MS) U–Pb zircon ages, coupled with petrography and geochemistry from the Izvorovo Pluton within the Sakar Unit (Strandja Zone). This pluton is composed of variably metamorphosed and deformed granites which yield crystallization ages of c. 251–256 Ma. These ages are older than the previously assumed age of the Izvorovo Pluton based on a postulated genetic relationship between the Izvorovo Pluton and Late Jurassic to Early Cretaceous metamorphism. A better understanding of units across the Strandja Zone can now be achieved, revealing two age groups of plutons within it. An extensive magmatic episode occurred c. 312–295 Ma, and a longer-lived episode between c. 275 and 230 Ma. Intrusions associated with both magmatic events were emplaced into pre-Late Carboniferous basement, and were overprinted by Early Alpine metamorphism and deformation. These two stages of magmatism can likely be attributed to changes in tectonic setting in the Strandja Zone. Such a change in tectonic setting is likely related to the collision between Gondwana-derived terranes and Laurussia, followed by either subduction of the Palaeo-Tethys Ocean beneath Laurussia or rifting in the southern margin of Laurussia, with granitoids forming in different tectonic environments.

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