A Novel Shaped Charge Engineered from Nano-metallic Glass Composite / High Entropy Alloy Liner for Debris Free Perforation Tunnel with Improved Reservoir Conductivity Leading to Enhanced Production

2021 ◽  
Author(s):  
Ting C. Roy ◽  
Kamel Bennaceur ◽  
Daniel Markel ◽  
Leonard Harp ◽  
Casey Harrison ◽  
...  

Abstract There is an unmet need for a clean perforating tunnel, for deep-water natural completions that reduces fluid friction, providing better reservoir connectivity and thus enhanced production. As a disruptive innovator in the technology space, particularly in the energy sector, we have now bridged this technology gap through the synthesis of a novel alloy, which when cold isostatic pressed into a conical shaped charge liner enables a unique response. During the detonation event, the jet created from our novel degradable liner punctures the casing and progresses to penetrate the formation until an eventual collapse. Our novel material is designed such that, during detonation, reaction products, bulk metallic glasses (BMG) and/or high entropy alloys (HEA), are formed which disintegrate into a fine powdery debris in contact with water. These degradable BMG/HEA or complexions are preferentially segregated at interfaces with high free energy. They tend to decorate the grain boundaries and domain interfaces of the impermeable skin lining the crushed zone of the perforation tunnel as amorphous intergranular films (AIFs) and plug at end of the pathway. Interacting with flowback fluids the complexions promote grain dropping, disintegrating the liner and carrot leaving behind a clean perforation tunnel. As a result, it is projected that fracture conductivity is significantly improved, resulting in enhanced productivity. In addition, a clear perf-tunnel has zero skin value. As such, when compared to a coated tunnel with gun and charge debris, it needs little or no acid to clean-up. In addition, it is anticipated that this will reduce the formation breakdown and opening pressures offering improved economics for the client. Last but not least, this leads to cost reduction of authorized field expenditure (AFE) to support optimized performance of completion designs allowing for increased production. The additional novelty of our liner designed through powder metallurgy (PM) techniques is a sub-sonic deflagration of the jet, during its collapse, resulting in sputtering of complexions and BMG/HEA residue along the perforation tunnel. These sputter-deposited jet complexions react with fluids during flowback, selectively being etched, barely needing water for the clean-up. The disintegration of this skin and slug, if any, in the perf-tunnel into fine particulates, subsequently being removed, leaves behind a clear, clean tunnel. CLEAR shaped charges have now been qualified to customer specifications in field conditions and are ready to be commercialized. Our journey of innovation does not end here. In fact, this is not even the beginning of the end, but it is, perhaps, the end of the beginning. To offset our carbon footprint and having embraced environmental and natural resources stewardship as one of our core values we are committed to contributing, as individuals and as an organization, to a flourishing human-ecological system. Through technology synthesis we have developed the concept of engineering seedpods for sustainable reforestation and Agri-tech. This had led to an endeavor for rapid tree planting through areal drones and UAVs’ to offset the effects of deforestation caused by human activities and natural disasters. In our paper we will additionally highlight this innovative technology cross-pollination and our efforts in low carbon and ESG endeavors.

2019 ◽  
Vol 813 ◽  
pp. 159-164
Author(s):  
Carlos Alberto Souto ◽  
Gustavo Faria Melo da Silva ◽  
Laura Angelica Ardila Rodriguez ◽  
Aline C. de Oliveira ◽  
Kátia Regina Cardoso

Coatings with high entropy alloys of the AlCoCrFeNiV system were obtained by selective laser melting on low carbon steel substrates. The effect of the variation of the Fe and V contents as well as the laser processing parameters in the development of the coating were evaluated. The coatings were obtained from the simple powder mixtures of the high purity elemental components in a planetary ball mill. The coatings were obtained by using CO2 laser with a power of 100 W, diameter of 0.16 mm, and scan speed varying from 3 to 12 mm/s. Phase constituents, microstructure and hardness were investigated by XRD, SEM, and microhardness tester, respectively. Wear resistance measurements were carried out by the micro-abrasion method using ball-cratering tests. The coatings presented good adhesion to the substrate and high hardness, of the order of 480 to 650 HV. Most homogeneous coating with nominal composition was obtained by using the higher scan speed, 12 mm/s. Vanadium addition increased hardness and gave rise to a high entropy alloy coating composed by BCC solid solutions. Ball cratering tests conducted on HEA layer showing improvement of material wear resistance, when compared to base substrate, decreasing up to 88% its wear rate, from 1.91x10-6 mm3/Nmm to 0.23x10-6 mm3/Nmm.


2016 ◽  
Vol 23 (11) ◽  
pp. 1195-1199 ◽  
Author(s):  
Xiao-tao Liu ◽  
Wen-bin Lei ◽  
Qun-jiao Wang ◽  
Wei-ping Tong ◽  
Chang-sheng Liu ◽  
...  

2021 ◽  
Author(s):  
Ting Chen Roy ◽  
Kamel Bennaceur ◽  
Daniel Markel ◽  
Leonard Harp ◽  
Casey Harrison ◽  
...  

Abstract A shaped charge for wellbore perforation includes a solid metal or powder liner pressed onto a case, sandwiching high explosives which may have varying thermal stability, dictated by the expected time of exposure and bottom hole temperature (BHT). It is common knowledge that post detonation, the liner-jet punctures the gun body and casing, continuing forward to perforate the formation until its eventual collapse. The jet debris is deposited on the crushed zone forming an impermeable skin and a slug at the end of the perforation-tunnel. This reduces fracture conductivity, and thus, production. Here we present a game changing innovation, the development of a shaped charge with a novel responsive liner. The jet created from our novel degradable liner, post detonation punctures the casing and progress to penetrate the formation until an eventual collapse. However, this system is designed so that, during detonation, a water disintegrable reaction product, bulk metallic glasses (BMG) and/or high entropy alloys (HEA), are formed. These degradable BMG/HEA or complexions decorate the grain boundaries and domain interfaces of the impermeable skin lining the crushed zone of the perforation tunnel as amorphous intergranular films (AIFs) and plug at end of the pathway. Interacting with flowback fluids the BMG/HEA promotes grain dropping, disintegrating the liner and carrot leaving behind a clean perforation tunnel, improving fracture conductivity thus enhanced productivity. In addition, a clear perf tunnel has zero skin value. As such, compared to a coated tunnel with gun and charge debris, it needs little or no acid to clean-up. This results in a demarked reduction of formation breakdown pressures with improved economics for the client. Last but not least this leads to cost reduction of authorized field expenditure (AFE) to support optimized performance of completion design allowing for increased production. CLEAR shaped charges have been qualified to customer specifications in field conditions and are ready to be commercialized. An extension of this technology is being applied to design charges for "Big-Hole" perforations, for the Plug and Abandonment (P&A) market where an effective cement squeeze, anchoring a plug effectively seals the wellbore, preventing the leakage of residual hydrocarbon and associated contamination and emissions.


2021 ◽  
Author(s):  
Ting C. Roy ◽  
Daniel Markel ◽  
Casey Harrison ◽  
James Shelton ◽  
Leonard Harp ◽  
...  

Abstract Strengthening materials through grain refinement often results in reduced ductility necessitating means to augment their elongation to failure for engineering applications. Grain boundary engineering (GBE), encompassing novel thermo-mechanical processing has shown promise of simultaneously enhancing both strength and ductility of materials and fracture behavior, especially with low stacking fault energy materials. The ultrahigh strength and reasonable ductility originate from dislocations being effectively blocked at the nano-twinned boundaries resulting in dislocation accumulation and entanglement. This necessitates the careful design of alloys and nano-composites, an effective harnessing of these unique sub-micron features to the benefit of engineering downhole tools for strategic applications. Enabled by these novel material developments, here we present two such articles for the unconventionals. First, a frangible barrier to abet placement of casings and liners through trapping an air column below the barrier while supporting a fluid column in the casing above, providing an up-thrust, a buoyant force that significantly reduces drag and lateral casing weight during placement. This is a viable concept because "shales don't kick". Second is the unmet need for a clean perforating tunnel allowing reduced fluid friction thus better reservoir connectivity. This has been achieved through the development of a novel shape charge with a reactive liner which during the detonation event, additionally generates reactive metallic glassy phase(s) and high entropy alloy complex(s) and their segregation in the deposited jet debris that lines the perf-tunnel. During flowback, reaction with aqueous fluids selectively etch these phases and stimulates the disintegration of the impervious skin on the perf-tunnel into fine particulates subsequently removing them, leaving behind a clear, clean tunnel.


2021 ◽  
pp. 130020
Author(s):  
W.F. Wu ◽  
N. Gao ◽  
X.W. Liu ◽  
W. Guo ◽  
L. Yang ◽  
...  

2019 ◽  
Author(s):  
Nirmal Kumar ◽  
Subramanian Nellaiappan ◽  
Ritesh Kumar ◽  
Kirtiman Deo Malviya ◽  
K. G. Pradeep ◽  
...  

<div>Renewable harvesting clean and hydrogen energy using the benefits of novel multicatalytic materials of high entropy alloy (HEA equimolar Cu-Ag-Au-Pt-Pd) from formic acid with minimum energy input has been achieved in the present investigation. The synthesis effect of pristine elements in the HEA drives the electro-oxidation reaction towards non-carbonaceous pathway . The atomistic simulation based on DFT rationalize the distinct lowering of the d-band center for the individual atoms in the HEA as compared to the pristine counterparts. This catalytic activity of the HEA has also been extended to methanol electro-oxidation to show the unique capability of the novel catalyst. The nanostructured HEA, properties using a combination of casting and cry omilling techniques can further be utilized as fuel cell anode in direct formic acid/methanol fuel cells (DFFE).<br></div>


Author(s):  
Janez Dolinšek ◽  
Stanislav Vrtnik ◽  
J. Lužnik ◽  
P. Koželj ◽  
M. Feuerbacher

2006 ◽  
Vol 31 (6) ◽  
pp. 723-736 ◽  
Author(s):  
Keng-Hao Cheng ◽  
Chia-Han Lai ◽  
Su-Jien Lin ◽  
Jien-Wei Yeh

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