Structural Analysis of Sol-Gel Derived TiO2 Nanoparticles: A Critical Impact of TiO2 Nanoparticles on Thermo-Mechanical Mechanism of Glass Fiber Polymer Composites

2021 ◽  
Author(s):  
Avinash Kumar ◽  
Abir Saha ◽  
Santosh Kumar
Keyword(s):  
Mechanical Properties ◽  
Structural Analysis ◽  
Glass Fiber ◽  
Tio2 Nanoparticles ◽  
Epoxy Matrix ◽  
Composite Laminates ◽  
Sol Gel ◽  
Epoxy Composites ◽  
Gravimetric Analysis ◽  
Dispersion Of Nanoparticles

Abstract The incorporated of inorganic nanoparticles with thermosetting epoxy polymer are an emerging field of research over past few years. It is well analyzed that epoxy matrix are brittle in nature that shows poor crack initiation and propagation and results poor thermo-mechanical properties. Therefore, researchers are showing their interest towards nanoparticles embedded epoxy composites to improve their fracture resistance (brittleness and toughness). In this investigation, the dispersion of TiO2 nanoparticles at different weight fraction (0-2%) with glass fiber reinforced epoxy composites is performed to enhance structural and thermo-mechanical properties. The TiO2 nanoparticles are prepared by sol-gel method and structural analysis of TiO2 nanoparticles shows greater interfacial bond with epoxy matrix and glass fibers due to fine dispersion of nanoparticles. From obtained results, a significant enhancement in their tensile strength (38.56%), flexural strength (30.52%), inter-laminar shear stress (25.22%), impact strength (327.10%), micro-hardness (48.53%) and fracture energy (40.19%) with minimum detrimental effect on toughness was revealed for GFRP-T1.0 compare to GFRP-T0.0 composite laminates. The stiffness and rigidity also improved up to 52.72% and 34.13% respectively for GFRP-T1.5 compare to GFRP-T0.0 composite laminates. The effects of nanoparticles contents and clustering size on thermal stability and glass transition temperature of developed composites are observed by thermo-gravimetric analysis. The surface morphology of TiO2 nanoparticles are characterized by transmission electron microscope (TEM) while dispersion of nanoparticles and failure of developed composites were analyzed by scanning electron microscopy (SEM).

Carbon Fiber Powder Reinforced Epoxy Composites used for Rapid Tooling

2011 ◽  
Vol 287-290 ◽  
pp. 197-200
Author(s):  
Hai Qing Hu ◽  
Li Zhao ◽  
Jia Qiang Liu ◽  
Shi Bao Wen ◽  
Yong Jiang Gu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Fiber ◽  
Glass Fiber ◽  
Epoxy Resin ◽  
Epoxy Matrix ◽  
Rapid Tooling ◽  
Epoxy Composites ◽  
Waste Materials ◽  
Ultrasonic Time ◽  
Good For

Carbon fiber powder (CFP) instead of the traditional glass fiber (cloth) was used to reinforce epoxy resin for rapid tooling. There are two obvious advantages: one is to utilize the waste materials, which is good for the protection of the environment; another is to simplify the producing process by cast molding. The filling amount and dispersing process of CFP was studied in this paper. The results show that when the amount of CFP was 10 wt%, and the ultrasonic time is more than 15 min, the CFP can be dispersed in the epoxy matrix uniformly, and the mechanical properties can meet the requirement of epoxy molding.

Surface Modified Clay Reinforced Silicon Incorporated Epoxy Hybrid Nanocomposites: Thermal, Mechanical, and Morphological Properties

2018 ◽  
Vol 9 (1) ◽  
pp. 1-22
Author(s):  
C. Karikal Chozhan ◽  
A. Chandramohan ◽  
M. Alagar
Keyword(s):  
Mechanical Properties ◽  
Epoxy Resin ◽  
Epoxy Matrix ◽  
Thermo Gravimetric Analysis ◽  
Epoxy Composites ◽  
Neat Epoxy ◽  
Gravimetric Analysis ◽  
Modified Clay ◽  
Mmt Clay ◽  
Surface Modified

The silicon-containing epoxy/clay nanocomposites were developed by incorporating the surface-modified MMT clay upto 7wt% into Si-epoxy resin. The surface of the montmorillonite (MMT) clay was modified with two surface modifiers namely cetyltrimethylammonium bromide (CTAB) and 3-aminopropyltriethoxysilane (γ-APS). The surface modified clay reinforced Si-epoxy composites were developed in the form of castings, and were characterized for their thermal and mechanical properties. Thermal behaviour of the composites was characterized by differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Mechanical properties were studied as per ASTM standards. Data result from the different studies, it is inferred that the surface modified clay reinforced Si-epoxy composites exhibit lower Tg than that of neat epoxy matrix (127°C <165°C). The decomposition temperature for 60% weight loss of clay reinforced Si-epoxy composites is 674–823°C which is higher when compared to that of neat epoxy matrix. For 5wt% clay reinforced Si-epoxy composites, the values of tensile, flexural and impact strength are increased to 26%, 21% and 29% respectively. The storage modulus (E’) is increased from 5932 to 6308 MPa for clay reinforced Si-epoxy resin. XRD analysis confirmed the well-dispersed exfoliated nanocomposites structure.

scholarly journals High modulus polyimide particle-reinforcement of epoxy composites

2021 ◽  
Author(s):  
Johannes Essmeister ◽  
M. Josef Taublaender ◽  
Thomas Koch ◽  
D. Alonso Cerrón-Infantes ◽  
Miriam M. Unterlass ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Composite Materials ◽  
Epoxy Matrix ◽  
Epoxy Composites ◽  
High Modulus ◽  
Particle Reinforcement

A novel class of fully organic composite materials with well-balanced mechanical properties and improved thermal stability was developed by incorporating highly crystalline, hydrothermally synthesized polyimide microparticles into an epoxy matrix.

Research on Properties of CNF/Glass Fiber/Epoxy Composites

2014 ◽  
Vol 513-517 ◽  
pp. 161-164
Author(s):  
Xing Kai Chen
Keyword(s):  
Infrared Spectrum ◽  
Glass Fiber ◽  
Functional Groups ◽  
Carbon Nanofibers ◽  
Epoxy Matrix ◽  
Tensile Modulus ◽  
Epoxy Composites ◽  
Reinforcement Efficiency

In the present investigation, carbon nanofibers (CNF) were dispersed in epoxy matrix to form CNF/glass fiber/epoxy composites. Before blending, CNF was oxidated to get more functional groups on CNF and improve the interface combination between resin and CNF, the infrared spectrum was used to test the efficiency. After that, tensile modulus tests were carried on for CNF/glass fiber/epoxy composites with different CNF fractions, the results indicated that there were slight improvements of tensile modulus when adding CNF. At 3.0 wt% of CNF, composites have the high improvement of tensile modulus, but the reinforcement of CNF decreased at 5.0 wt% of CNF. And the CNF reinforcement efficiency was analyzed using modified Coxs model and rule of mixture.

scholarly journals Influence of layering pattern of modified kenaf fiber on thermomechanical properties of epoxy composites

2019 ◽  
Vol 36 (1) ◽  
pp. 47-62
Author(s):  
AR Mohammed ◽  
MS Nurul Atiqah ◽  
Deepu A Gopakumar ◽  
MR Fazita ◽  
Samsul Rizal ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Chemical Modification ◽  
Epoxy Matrix ◽  
Epoxy Composites ◽  
Woven Composites ◽  
Fiber Reinforced ◽  
Kenaf Fiber ◽  
Kenaf Fibers ◽  
The Impact ◽  
Woven Kenaf

Natural fiber-reinforced composites gained considerable interest in the scientific community due to their eco-friendly nature, cost-effective, and excellent mechanical properties. Here, we reported a chemical modification of kenaf fiber using propionic anhydride to enhance the compatibility with the epoxy matrix. The incorporation of the modified woven and nonwoven kenaf fibers into the epoxy matrix resulted in the improvement of the thermal and mechanical properties of the composite. The thermal stability of the epoxy composites was enhanced from 403°C to 677°C by incorporating modified woven kenaf fibers into the epoxy matrix. The modified and unmodified woven kenaf fiber-reinforced epoxy composites had a tensile strength of 64.11 and 58.82 MPa, respectively. The modified woven composites had highest flexural strength, which was 89.4 MPa, whereas, for unmodified composites, it was 86.8 MPa. The modified woven fiber-reinforced epoxy composites showed the highest value of flexural modulus, which was 6.0 GPa compared to unmodified woven composites (5.51 GPa). The impact strength of the epoxy composites was enhanced to 9.43 kJ m−2 by the incarnation of modified woven kenaf fibers into epoxy matrix. This study will be an effective platform to design the chemical modification strategy on natural fibers for enhancing the compatibility toward the hydrophobic polymer matrices.

Tensile Properties of Epoxy Composites Reinforced with Continuous Sisal Fibers

2014 ◽  
Vol 775-776 ◽  
pp. 284-289 ◽  
Author(s):  
Sergio Neves Monteiro ◽  
Frederico Muylaert Margem ◽  
Wellington Pereira Inácio ◽  
Artur Camposo Pereira ◽  
Michel Picanço Oliveira
Keyword(s):  
Mechanical Properties ◽  
Tensile Properties ◽  
Epoxy Matrix ◽  
Room Temperature ◽  
Fracture Analysis ◽  
Epoxy Composites ◽  
Matrix Composites ◽  
Matrix Interface ◽  
Fiber Matrix Interface ◽  
Sisal Fibers

The tensile properties of DGEBA/TETA epoxy matrix composites reinforced with different amounts of sisal fibers were evaluated. Composites reinforce with up to 30% in volume of long, continuous and aligned sisal fibers were room temperature tested in an Instron machine. The fracture was analyzed by SEM. The results showed significant changes in the mechanical properties with the amount of sisal fibers. These mechanical properties were compared with other bend-tested composites results. The fracture analysis revealed a weak fiber/matrix interface, which could be responsible for the performance of some properties.

scholarly journals Studies on Water Sorption Behaviour of Laminated Bamboo Polymer Composite

2019 ◽  
Vol 130 ◽  
pp. 01040 ◽  
Author(s):  
Yuniar Ratna Pratiwi ◽  
Indah Widiastuti ◽  
Budi Harjanto
Keyword(s):  
Mechanical Properties ◽  
Water Absorption ◽  
Tensile Properties ◽  
Water Immersion ◽  
Bamboo Fiber ◽  
Epoxy Composites ◽  
Gravimetric Analysis ◽  
Sorption Behaviour ◽  
Laminated Bamboo ◽  
The Matrix

The aim of this article is to evaluate water absorption in bamboo fiber composites. Bamboo is hydrophilic, means that it easily absorbs water. In this study the bamboo fiber-based composites were developed using hand lay up method, with epoxy resin as the matrix constituent. Water absorption characteristics of specimens of bamboo composite and epoxy were determined from water immersion tests at several temperatures. Gravimetric analysis was performed to determine the moisure absorbed as a function of time at two different temperatures: 25 ºC and 50 C. The diffusivity of water in an epoxy bamboo composite was determined after reaching saturation point. During room temperature soaking, epoxy specimen showed the characteristic of Fickian behavior. Similar immersion tests on bamboo-epoxy composites followed nonfickian behavior. Changes in the mechanical properties of material due to water absorption were evaluated from tensile testing on materials with varied water content. It was found that the waterabsorption in all samples reduced the tensile properties. The degradation of tensile properties was greater with an increasing temperature of immersion. The results of this study emphasize the importance ofconsidering deterioration of mechanical properties in the bamboo epoxy composites during their application in water and possibly in humid environment.

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