Assessing the suitability of chemical ameliorants for reducing bio-availability of heavy metals in bulk fly ash contaminated soil

2021 ◽  
Author(s):  
Joy Kumar Mandal ◽  
Siddhartha Mukherjee ◽  
Niharendu Saha ◽  
Nibedan Halder ◽  
Sanjoy Chakraborty
Keyword(s):  
Fly Ash ◽  
Environmental Sustainability ◽  
Contaminated Soils ◽  
Crop Production ◽  
Power Plants ◽  
Microbial Biomass Carbon ◽  
Thermal Power ◽  
Ammonium Phosphate ◽  
Contamination Factor ◽  
Management Option

Abstract In-situ rehabilitation of fly ash at dumping sites has been rarely addressed for crop production due to growth-related constraints, largely of heavy metal (HM) contamination in soils and crops. Current communication deals with a novel approach to identify a suitable management option for rejuvenating the contaminated soils. In this background, a 60-days incubation experiment was conducted with different fly ash-soil mixtures (50 + 50%, A1; 75 + 25%, A2; 100 + 0%, A3) along with four ameliorants, namely, lime (T1), sodium sulphide (T2), di-ammonium phosphate (T3), and humic acid (T4) at 30 ± 2 0 C to assess the ability of different fly ash-soil-ameliorant mixtures in reducing bio-availability of HMs. DTPA-extractable bio-available HM contents for lead (Pb), cadmium (Cd), nickel (Ni), and chromium (Cr) and their respective ratios to total HM contents under the influence of different treatments were estimated at different stages of incubation. Further, the ecotoxicological impact of different treatments on soil microbial properties was studied. A1T1 significantly recorded the lowest bio-availability of HMs (~ 49–233% lower) followed by A2T1 (~ 35–133%) among the treatments. The principle component analysis also confirmed the superiority of A1T1 and A2T1 in this regard. Further, A1T1 achieved low contamination factor and ecological risk with substantial microbial biomass carbon load and dehydrogenase activity. Thus, liming to fly ash-soil mixture at 50:50 may be considered as the best management option for ameliorating metal toxicity. This technology may guide thermal power plants to provide the necessary package of practices for the stakeholders to revive their contaminated lands for better environmental sustainability.

scholarly journals Assessing the Capability of Chemical Ameliorants to Reduce the Bioavailability of Heavy Metals in Bulk Fly Ash Contaminated Soil

Molecules ◽  
2021 ◽  
Vol 26 (22) ◽  
pp. 7019
Author(s):  
Joy Kumar Mandal ◽  
Siddhartha Mukherjee ◽  
Niharendu Saha ◽  
Nibedan Halder ◽  
Tufleuddin Biswas ◽  
...  
Keyword(s):  
Fly Ash ◽  
Environmental Sustainability ◽  
Contaminated Soils ◽  
Crop Production ◽  
Power Plants ◽  
Microbial Biomass Carbon ◽  
Thermal Power ◽  
Ammonium Phosphate ◽  
Contamination Factor ◽  
Management Option

In-situ rehabilitation of fly ash at dumping sites has rarely been addressed for crop production due to growth-related constraints, largely of heavy metal (HM) contamination in soils and crops. Current communication deals with a novel approach to identify a suitable management option for rejuvenating the contaminated soils. In this background, a 60-days incubation experiment was conducted with different fly ash-soil mixtures (50 + 50%, A1; 75 + 25%, A2; 100 + 0%, A3) along with four ameliorants, namely, lime (T1), sodium sulphide (T2), di-ammonium phosphate (T3), and humic acid (T4) at 30 ± 2 °C to assess the ability of different fly ash-soil-ameliorant mixtures in reducing bio-availability of HMs. Diethylenetriaminepentaacetic acid (DTPA)-extractable bio-available HM contents for lead (Pb), cadmium (Cd), nickel (Ni), and chromium (Cr) and their respective ratios to total HM contents under the influence of different treatments were estimated at 0, 15, 30, 45, and 60 days of incubation. Further, the eco-toxicological impact of different treatments on soil microbial properties was studied after 60 days of experimentation. A1T1 significantly recorded the lowest bio-availability of HMs (~49–233% lower) followed by A2T1 (~35–133%) among the treatments. The principal component analysis also confirmed the superiority of A1T1 and A2T1 in this regard. Further, A1T1 achieved low contamination factor and ecological risk with substantial microbial biomass carbon load and dehydrogenase activity. Thus, liming to fly ash-soil mixture at 50:50 may be considered as the best management option for ameliorating metal toxicity. This technology may guide thermal power plants to provide the necessary package of practices for the stakeholders to revive their contaminated lands for better environmental sustainability.

A Review on Utilization of Fly- Ash and Pond-Ash as a Partial Replacement of Cement in Concrete Mix Design

2018 ◽  
pp. 413-418
Author(s):  
Harshkumar Patel ◽  
Yogesh Patel
Keyword(s):  
Fly Ash ◽  
Electricity Generation ◽  
Power Plants ◽  
Renewable Energy Sources ◽  
Thermal Power ◽  
Strength Test ◽  
Partial Replacement ◽  
Pond Ash ◽  
Research Activities ◽  
Ash Disposal

Now-a-days energy planners are aiming to increase the use of renewable energy sources and nuclear to meet the electricity generation. But till now coal-based power plants are the major source of electricity generation. Disadvantages of coal-based thermal power plants is disposal problem of fly ash and pond ash. It was earlier considered as a total waste and environmental hazard thus its use was limited, but now its useful properties have been known as raw material for various application in construction field. Fly ash from the thermal plants is available in large quantities in fine and coarse form. Fine fly ash is used in construction industry in some amount and coarse fly ash is subsequently disposed over land in slurry forms. In India around 180 MT fly is produced and only around 45% of that is being utilized in different sectors. Balance fly ash is being disposed over land. It needs one acre of land for ash disposal to produce 1MW electricity from coal. Fly ash and pond ash utilization helps to reduce the consumption of natural resources. The fly ash became available in coal based thermal power station in the year 1930 in USA. For its gainful utilization, scientist started research activities and in the year 1937, R.E. Davis and his associates at university of California published research details on use of fly ash in cement concrete. This research had laid foundation for its specification, testing & usages. This study reports the potential use of pond-ash and fly-ash as cement in concrete mixes. In this present study of concrete produced using fly ash, pond ash and OPC 53 grade will be carried. An attempt will be made to investigate characteristics of OPC concrete with combined fly ash and pond ash mixed concrete for Compressive Strength test, Split Tensile Strength test, Flexural Strength test and Durability tests. This paper deals with the review of literature for fly-ash and pond-ash as partial replacement of cement in concrete.

scholarly journals Preparation of Synthetic Zeolites from Coal Fly Ash by Hydrothermal Synthesis

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1267
Author(s):  
David Längauer ◽  
Vladimír Čablík ◽  
Slavomír Hredzák ◽  
Anton Zubrik ◽  
Marek Matik ◽  
...  
Keyword(s):  
Fly Ash ◽  
Coal Combustion ◽  
Power Plants ◽  
Coal Fly Ash ◽  
Thermal Power ◽  
Product Analysis ◽  
Coal Combustion Products ◽  
X Ray ◽  
Wide Range ◽  
Silica Alumina

Large amounts of coal combustion products (as solid products of thermal power plants) with different chemical and physical properties cause serious environmental problems. Even though coal fly ash is a coal combustion product, it has a wide range of applications (e.g., in construction, metallurgy, chemical production, reclamation etc.). One of its potential uses is in zeolitization to obtain a higher added value of the product. The aim of this paper is to produce a material with sufficient textural properties used, for example, for environmental purposes (an adsorbent) and/or storage material. In practice, the coal fly ash (No. 1 and No. 2) from Czech power plants was firstly characterized in detail (X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), particle size measurement, and textural analysis), and then it was hydrothermally treated to synthetize zeolites. Different concentrations of NaOH, LiCl, Al2O3, and aqueous glass; different temperature effects (90–120 °C); and different process lengths (6–48 h) were studied. Furthermore, most of the experiments were supplemented with a crystallization phase that was run for 16 h at 50 °C. After qualitative product analysis (SEM-EDX, XRD, and textural analytics), quantitative XRD evaluation with an internal standard was used for zeolitization process evaluation. Sodalite (SOD), phillipsite (PHI), chabazite (CHA), faujasite-Na (FAU-Na), and faujasite-Ca (FAU-Ca) were obtained as the zeolite phases. The content of these zeolite phases ranged from 2.09 to 43.79%. The best conditions for the zeolite phase formation were as follows: 4 M NaOH, 4 mL 10% LiCl, liquid/solid ratio of 30:1, silica/alumina ratio change from 2:1 to 1:1, temperature of 120 °C, process time of 24 h, and a crystallization phase for 16 h at 50 °C.

scholarly journals Assessment of Characteristics of Acid Mine Drainage Treated with Fly Ash

2021 ◽  
Vol 11 (9) ◽  
pp. 3910
Author(s):  
Saba Shirin ◽  
Aarif Jamal ◽  
Christina Emmanouil ◽  
Akhilesh Kumar Yadav
Keyword(s):  
Fly Ash ◽  
Acid Mine Drainage ◽  
Power Plants ◽  
Mine Drainage ◽  
Thermal Power ◽  
Mineralogical Characterization ◽  
Acid Mine ◽  
Before And After ◽  
Abandoned Coal Mines

Acid mine drainage (AMD) occurs naturally in abandoned coal mines, and it contains hazardous toxic elements in varying concentrations. In the present research, AMD samples collected from an abandoned mine were treated with fly ash samples from four thermal power plants in Singrauli Coalfield in the proximate area, at optimized concentrations. The AMD samples were analyzed for physicochemical parameters and metal content before and after fly ash treatment. Morphological, geochemical and mineralogical characterization of the fly ash was performed using SEM, XRF and XRD. This laboratory-scale investigation indicated that fly ash had appreciable neutralization potential, increasing AMD pH and decreasing elemental and sulfate concentrations. Therefore, fly ash may be effectively used for AMD neutralization, and its suitability for the management of coalfield AMD pits should be assessed further.

scholarly journals Effect of Lignite Fly Ash on the Growth and Reproduction of Earthworm Eisenia fetida

2009 ◽  
Vol 6 (2) ◽  
pp. 511-517 ◽  
Author(s):  
S. Sarojini ◽  
S. Ananthakrishnasamy ◽  
G. Manimegala ◽  
M. Prakash ◽  
G. Gunasekaran
Keyword(s):  
Fly Ash ◽  
Eisenia Fetida ◽  
Power Plants ◽  
Thermal Power ◽  
Biological Properties ◽  
Cow Dung ◽  
Physical Chemical ◽  
Lignite Fly Ash ◽  
Agricultural Use ◽  
Growth And Reproduction

Fly ash is an amorphous ferroalumino silicate, an important solid waste around thermal power plants. It creates problems leading to environmental degradation due to improper utilization or disposal. However, fly ash is a useful ameliorant that may improve the physical, chemical and biological properties of soils and is a source of readily available plant macro and micronutrients when it is used with biosolids. Supply of nutrients from fly ash with biosolids may enhance their agricultural use. The growth and reproduction ofEisenia fetidawas studied during vermicomposting of fly ash with cowdung and pressmud in four different proportions (T1,T2,T3& T4) and one controli.e.,cow dung and pressmud alone. The growth, cocoon and hatchlings production were observed at the interval of 15 days over a period of 60 days. The maximum worm growth and reproduction was observed in bedding material alone. Next to that the T1was observed as the best mixture for vermiculture.

TRACE ELEMENT ANALYSIS OF FLY ASH BY PIXE

1999 ◽  
Vol 09 (03n04) ◽  
pp. 417-422 ◽  
Author(s):  
V. VIJAYAN ◽  
S. N. BEHERA
Keyword(s):  
Fly Ash ◽  
Trace Element ◽  
Power Plants ◽  
Building Materials ◽  
Thermal Power ◽  
Trace Element Analysis ◽  
Chemical Properties ◽  
Solid Material ◽  
Thermal Power Plants ◽  
Element Analysis

Fly ash is a major component of solid material generated by the coal-fired thermal power plants. In India the total amount of fly ash produced per annum is around 100 million tonnes. Fly ash has a great potential for utilization in making industrial products such as cement, bricks as well as building materials, besides being used as a soil conditioner and a provider of micro nutrients in agriculture. However, given the large amount of fly ash that accumulate at thermal power plants, their possible reuse and dispersion and mobilization into the environment of the various elements depend on climate, soils, indigenous vegetation and agriculture practices. Fly ash use in agriculture improved various physico-chemical properties of soil, particularly the water holding capacity, porosity and available plant nutrients. However it is generally apprehended that the application of large quantity of fly ash in fields may affect the plant growth and soil texture. Hence there is a need to characterize trace elements of fly ash. The results of trace element analysis of fly ash and pond ash samples collected from major thermal power plants of India by Particle Induced X-ray Emission (PIXE) have been discussed.

The Latest Research in Mongolia on the Utilization of Coal Combustion By-Products

2021 ◽  
Vol 323 ◽  
pp. 8-13
Author(s):  
Jadambaa Temuujin ◽  
Damdinsuren Munkhtuvshin ◽  
Claus H. Ruescher
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Coal Combustion ◽  
Power Plants ◽  
Thermal Power ◽  
Thermal Power Plants ◽  
Power Stations ◽  
Thermal Power Stations ◽  
Coal Ashes ◽  
By Products

With a geological reserve of over 170 billion tons, coal is the most abundant energy source in Mongolia with six operating thermal power stations. Moreover, in Ulaanbaatar city over 210000 families live in the Ger district and use over 800000 tons of coal as a fuel. The three thermal power plants in Ulaanbaatar burn about 5 million tons of coal, resulting in more than 500000 tons of coal combustion by-products per year. Globally, the ashes produced by thermal power plants, boilers, and single ovens pose serious environmental problems. The utilization of various types of waste is one of the factors determining the sustainability of cities. Therefore, the processing of wastes for re-use or disposal is a critical topic in waste management and materials research. According to research, the Mongolian capital city's air and soil quality has reached a disastrous level. The main reasons for air pollution in Ulaanbaatar are reported as being coal-fired stoves of the Ger residential district, thermal power stations, small and medium-sized low-pressure furnaces, and motor vehicles. Previously, coal ashes have been used to prepare advanced materials such as glass-ceramics with the hardness of 6.35 GPa, geopolymer concrete with compressive strength of over 30 MPa and zeolite A with a Cr (III) removal capacity of 35.8 mg/g. Here we discuss our latest results on the utilization of fly ash for preparation of a cement stabilized base layer for paved roads, mechanically activated fly ash for use in concrete production, and coal ash from the Ger district for preparation of an adsorbent. An addition of 20% fly ash to 5-8% cement made from a mixture of road base gave a compressive strength of ~ 4MPa, which exceeds the standard. Using coal ashes from Ger district prepared a new type of adsorbent material capable of removing various organic pollutants from tannery water was developed. This ash also showed weak leaching characteristics in water and acidic environment, which opens up an excellent opportunity to utilize.

Experimental Study on Various Mineral Admixtures in Fibre Reinforced Concrete

2019 ◽  
pp. 309-317
Author(s):  
Kavitha E ◽  
Karthik S ◽  
Eithya B ◽  
Seenirajan M
Keyword(s):  
Fly Ash ◽  
Rice Husk ◽  
Power Plants ◽  
Rice Husk Ash ◽  
Thermal Power ◽  
Experimental Studies ◽  
Mineral Admixtures ◽  
Hardened Concrete ◽  
Polypropylene Fibres ◽  
Concrete Production

The quantity of fly ash produced from thermal power plants in India is approximately 80 million tons each year, and its percentage utilization is less than 10%. An attempt has been made to utilize these cheaper materials in concrete production. This thesis aims at investigating the characteristics of fresh concrete and various strengths of hardened concrete made with various mineral admixtures such as fly ash. GGBFS, silica fume. Rice husk ash along with polypropylene fibres in various proportions.  M20 grade concrete is considered for experimental studies with 53grade Ordinary Portland Cement blended with varying percentages of mineral admixtures. The maximum size of coarse aggregate used is 20mm.  Various mineral admixtures such as fly ash. GGBFS.Silica fume. Rice Husk Ash were added concrete in various percentages by partially replacing cement and the optimum percentage of the mineral admixtures will be found.  Based on the obtained values, the admixture with maximum mechanical strength is determined and to this polypropylene fibre is added by varying 0 to 0.5 % by weight of cement to the mix.  The test results obtained were compared and discussed with conventional concrete.

RESEARCH OF COMPLEX MODIFICATION OF HEAVY CONCRETE

2021 ◽  
Vol 96 (4) ◽  
pp. 107-112
Author(s):  
YU.S. FILIMONOVA ◽  
◽  
E.G. VELICHKO ◽  
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Power Plants ◽  
High Efficiency ◽  
Thermal Power ◽  
Thermal Power Plants ◽  
Complex Chemical ◽  
Composition And Structure ◽  
Combined Use ◽  
Mineral Additive

Modification of the composition and structure of heavy concrete with the use of a complex chemical-mineral additive consisting of fly ash from thermal power plants, a superplasticizer, a high-valence hardening accelerator AC and a fine-dispersed clinker component is considered. Modified concrete is characterized by an increase in compressive strength at a brand age by 67%, a decrease in the water content of a concrete mixture by 13.6% and an improvement in its workability by 11-12 cm. With the combined use of a superplasticizer and a high-valence hardening accelerator AC a significant synergistic effect is observed in the format of enhancing their plasticizing effect. The high efficiency of the application of the mixed-dispersed clinker component has been established.

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