Reactions of Sechura Phosphate Rock and Single Superphosphate in Soil

1986 ◽  
Vol 50 (2) ◽  
pp. 480-485 ◽  
Author(s):  
J. K. Syers ◽  
A. D. Mackay
Author(s):  
A.G. Sinclair ◽  
C.B. Dyson ◽  
P.W. Shannon

Sechura reactive phosphate rock (SPR) and triple superphosphate (TSP) have been compared as phosphate fertihsers for pastures in a series of 19 field trials dispersed throughout New Zealand, each continuing for 3-6 years. Both fertilisers were applied annuaIly at 4 rates. In the first 2 years SPR was much less effective at increasing dry matter yields than TSP, but its performance improved markedly with time. In year 6 SPR outyielded TSP at alI application rates for all sites combined. The relative performance of SPR and TSP differed markedly at different sites. Very high soil phosphate retention and a combination of low moisture and high pH appeared to be unfavourable for SPR performance. In most sites SPR was equal or superior to TSP by year 6. SPR substantially raised molybdenum concentration in clovers, and this may have contributed to its superior performance at some sites. As TSP and single superphosphate were equally effective, the good performauce of SPR and the relative cheapness of reactive phosphate rocks suggest an important role for the latter on New Zealand pastures. Keywords Sechura phosphate rock, reactive phosphate rock, RPR, superphosphates, phosphate fertilisers


Author(s):  
P.W. Shannon

Increasing material, processing, and distribution costs have raised superphosphate prices to a point where many farms cannot support the costs of meeting maintenance phosphate requires men& Alternatives to superphosphate, particularly those that have lower processing costs and contain more P, may offer a solution to the problem provided they are agronomically as effective. Phosphate rock may indeed be such an alternative. Preliminary results from a series of five trials in Northland show that on soils of moderate P fertility, with low phosphate retention (PR) and high pH (5.9.6.0), initial pasture growth responses to rock phosphates are smaller than those from single or triple superphosphate. On one soil of higher PR and lower pH, the differences in yield between the rock-phosphates and the super. phosphates were smaller. Of the rock phosphates tested, Sechura and North Carolina (unground and ungranulated) tended to be more effective than ground and granulated Chatham Rise phosphorite. The effect on production of applying fertilisers once every three years, as opposed to annual applications is being investigated using triple superphosphate and Sechura phosphate rock. After two years, production levels appear largely unaffected by differences in application frequency. A comparison of locally-produced superphosphate with a reference standard showed that both performed similarly, indicating that the local product was of satisfactory quality.


HortScience ◽  
2009 ◽  
Vol 44 (2) ◽  
pp. 426-430 ◽  
Author(s):  
Ricardo González-Ponce ◽  
Esther G. López-de-Sá ◽  
César Plaza

Struvite (MgNH4PO4·6H2O) production is widely studied as a way to remove phosphorus (P) from wastewater and generate a potentially marketable P fertilizer, but its effects on crops have yet to be researched more thoroughly. This study was conducted to evaluate struvite recovered by the Spanish Research Council (CSIC) pilot process (STR) as a source of P for lettuce (Lactuca sativa L.) by comparing its effectiveness with that of single superphosphate (SUP), a common P fertilizer derived from phosphate rock. In a greenhouse pot experiment, a P-deficient loamy sand soil was amended with either SUP or STR at P rates of 0, 4, 8, 12, 16, and 20 mg·kg−1. Nitrogen and potassium were uniformly supplied to all treatments. The response of lettuce head fresh weight and P uptake to P rate exhibited statistically significant quadratic relationships for both SUP and STR. With respect to SUP, STR was significantly more effective in increasing lettuce yield and P uptake, probably because of the larger amount of magnesium (Mg) incorporated with this material and a synergistic effect on P uptake. This work supports previous findings based on other test crops in suggesting that STR can be a P source attractive to the fertilizer market with additional agronomic and environmental benefits such as providing available Mg and nitrogen, helping attenuate consumption of phosphate rock, and reducing release of P by discharge of treated wastewaters to surface and groundwater systems.


Soil Research ◽  
1996 ◽  
Vol 34 (6) ◽  
pp. 985 ◽  
Author(s):  
V Manoharan ◽  
P Loganathan ◽  
RL Parfitt ◽  
RW Tillman

This study describes some of the effects of 8 years of annual application of 6 types of phosphatic fertilisers on the chemical composition and aluminium (Al) speciation in soil solution extracted from a soil under pasture. Soil samples at 2 depths, 0-30 and 30-75 mm, were collected at the end of 8 years. Soil solutions were extracted by centrifuging at 12 000 RCF and analysed for Al, Na, K, Ca, Mg, F, NO3, Cl, and SO4, as well as pH and ionic strength. Soil and soil solution pH were significantly increased at both depths by application of North Carolina phosphate rock (NCPR) compared with the control. In contrast, diammonium phosphate (DAP) significantly decreased the soil and solution pH. Single superphosphate (SSP) did not have any significant effect on soil or solution pH compared with the untreated control. The surface soil (0-30 mm) solution pH was on average 0.6 of a unit higher than the subsurface soil (30-75 mm) solution pH. Total monomeric Al concentration [Al], measured by the pyrocatecol violet (PCV; 4 min) method, ranged from 1.5 to 4.8 �M in the surface soil and 2.5 to 12.2 �M in the subsurface soil. The DAP and higher rates of SSP application resulted in a large increase in total and inorganic monomeric [Al] in the soil solution extracted from the subsurface soil. Total soluble [F] ranged from 2.7 to 23.5 �M and 3.2 to 25.6 �M in the surface and subsurface soils, respectively, and was significantly increased by the application of NCPR and by higher rates of SSP. The predominant forms of inorganic monomeric Al present in the soil solution were estimated to be the non-phytotoxic Al-F complexes, AlF2+, and AlF2+. There was a marked decrease in toxic Al species (Al3+, Al(OH)2+, Al(OH)2+) in soil solution following NCPR and SSP application. This was due primarily to complexation of Al with F derived from these fertilisers forming non-toxic AI-F complexes. The results suggest that the long-term application of reactive phosphate rock such as NCPR may contribute to amelioration of soil acidity and Al toxicity under legume-based pastures. In contrast ammonium-containing phosphate fertilisers such as DAP probably decrease soil pH and increase the formation of toxic Al species in the soil solution.


1995 ◽  
Vol 35 (4) ◽  
pp. 489 ◽  
Author(s):  
HJ Di ◽  
R Harrison ◽  
AS Campbell

This paper describes the use of an isotope injection technique for assessing the agronomic effectiveness of phosphate sources in undisturbed soils in field and glasshouse experiments. A special injection apparatus consisting of 20 syringe needles linked to a common reservoir was used to label soil cores 150 mm in diameter and 150 mm in height, without significantly disturbing the soil structure and established perennial ryegrass (Lolium perenne) root patterns. Variations in the amount of phosphorus (P) taken up by plants from single superphosphate (applied at 30, 60, and 100 kg P/ha), from 30% acidulated North Carolina phosphate rock (60 g P/ha), and from 'as received' North Carolina phosphate rock (60 kg P/ha) were indicated by the specific activity of the plant P. Percentages of plant P derived from the fertilisers were calculated on the basis of the specific activity of the fertilised treatments and the controls. The technique provides a simple method of comparing the agronomic effectiveness of phosphate sources in undisturbed soils and, unlike total dry matter yield and P uptake, is relatively unaffected by environmental factors.


Author(s):  
K.W. Perrott ◽  
B.E. Kerr ◽  
J.H. Watkinson ◽  
J.E. Waller

The dissolution rate of Sechura phosphate rock (particle size 75-150 pm) was determined at 95 New Zealand sites with a range of soil and environmental properties. Rates ranged from 0 to 70% of the phosphate rock dissolved per year with an average dissolution rate of 3 1 %/year. An initial model based on stepwise linear regression analysis indicated that the rate of dissolution was negatively associated with soil pH and positively associated with rainfall and exchangeable soil magnesium. There was also an effect of soil type and drainage. The amount of residual RPR accumulated from previous fertiliser application can be determined by a new soil test. This, together with the dissolution rate estimated from the nature of the RF'R and the soil and site factors, can be used to indicate likely soil P status. Keywords: dissolution, fertiliser, phosphorus, reactive phosphate rock, soil test


1987 ◽  
Vol 14 (2) ◽  
pp. 173-180
Author(s):  
Muhammad Ishaque ◽  
Ishtiaq Ahmad

1992 ◽  
Vol 32 (1) ◽  
pp. 91-99 ◽  
Author(s):  
J. S. Robinson ◽  
J. K. Syers ◽  
N. S. Bolan

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