<p>&#160;&#160; <sup>36</sup>Cl and <sup>81</sup>Kr (half-lives of 301 and 229 kyr, respectively) are among a very few age tracers with dating capabilities in the 10<sup>4</sup>&#8211;10<sup>6</sup> yr timescale. Although widely applied since the 1980s in various hydrological studies, the <sup>36</sup>Cl/Cl system has been found complex as an effective dating tool. In contrast, <sup>81</sup>Kr has become a practical tool only recently and is considered to be an ideal dating tool due to the inert properties of the noble gas. In the present study, simultaneous measurements of both radioisotopes were used to assess the <sup>36</sup>Cl/Cl input ratios and the Cl<sup>-</sup> content for paleorecharge into the deep, transboundary Nubian Sandstone Aquifer (NSA) which stretches below the hyperarid deserts of the Sinai Peninsula (Egypt) and the Negev (Israel).</p><p>&#160;&#160; By means of <sup>81</sup>Kr data, reconstructed Cl<sup>-</sup> content of recharge that occurred during the late Pleistocene was found to be 300&#8211;400 mg/L with an initial <sup>36</sup>Cl/Cl ratio of 50 &#215; 10<sup>-15</sup>. This latter value is in agreement with the <sup>36</sup>Cl/Cl ratio in recent local rainwater, indicating constancy over prolonged periods with possible variable climatic conditions. This similarity in values suggests a process that is rather insensitive to atmospheric <sup>36</sup>Cl fallout rates. Erosion and weathering of near-surface materials in the desert environment could dominate the hydrochemistry of rains, floods, and the consequent groundwater recharge. This near-surface Cl<sup>-</sup> reservoir integrates various sources and processes, including marine and terrestrial Cl<sup>-</sup>, cosmogenic <sup>36</sup>Cl fallout, and cosmogenic <sup>36</sup>Cl production in the shallow unsaturated zone, all of which are active over long timescales and accumulate on the land surface and in the epigene zone.&#160; Spatial differences in the reconstructed initial <sup>36</sup>Cl/Cl ratio are attributed to differences in the mineral aerosol sources for specific recharge areas of the NSA. The results of this study highlight the potential of integrating <sup>81</sup>Kr age information in evaluating the initial <sup>36</sup>Cl/Cl and Cl<sup>-</sup> input, which is essential for the calibration of <sup>36</sup>Cl radioisotope as a long-term dating tool for a given basin.</p>