Characterization and variations of dissolved organic matter in the Lake Taihu area of China

2012 ◽  
Vol 12 (4) ◽  
pp. 439-450
Author(s):  
Yong Qiu ◽  
Hanchang Shi ◽  
He Jing ◽  
Rui Liu ◽  
Qiang Cai ◽  
...  
Keyword(s):  
Water Quality ◽  
Organic Matter ◽  
Surface Water ◽  
Dissolved Organic Matter ◽  
Lake Taihu ◽  
Surface Water Quality ◽  
Spatial Variations ◽  
Nutrient Concentrations ◽  
Wet Season ◽  
Seasonal And Spatial Variations

Lake Taihu in China is a eutrophicated lake surrounded by industrial and urbanized zones, thus its water quality often suffers from organic and nutrient contaminants. In this paper, a 1 year water quality survey was conducted around the lake and statistical analysis tools were used to characterize the variations of organic pollutants. Analysis of variance (ANOVA), cluster analysis and principal component analysis (PCA) confirm the seasonal and spatial variations of surface water quality in Lake Taihu. Surface water quality is better during the wet season and worse downstream during the dry season. The dissolved organic matter was further analyzed using a parallel factor analysis (PARAFAC) model with three-dimensional excitation-emission fluorescence matrices. Four components were extracted from the fluorescence data, namely, two autochthonous biodegradation products (C1: amino acids, C4: protein-like materials) and two humic-like substances (C2: from microbial processing, C3: terrestrial). C1 and C4 were dominant in the chromophoric dissolved organic matter (CDOM) fluorophores; this result is similar to those of other inland water bodies in China. The CDOM fluorophores showed similar seasonal and spatial variations with common water quality indices, with the exception of the seasonal responses of C2 in winter. Bivariance correlations between the organic and nutrient concentrations and the fluorescence intensities of the CDOM fluorophores imply possible common sources of the different contaminants. This paper exemplifies advanced statistical methods as a useful tool in understanding the behavior of contaminants in inland fresh water systems.

Effects of Fe addition on sediment P dynamics in a eutrophic lake

2021 ◽  
Author(s):  
Melanie Münch ◽  
Rianne van Kaam ◽  
Karel As ◽  
Stefan Peiffer ◽  
Gerard ter Heerdt ◽  
...  
Keyword(s):  
Water Quality ◽  
Organic Matter ◽  
Surface Water ◽  
Water Column ◽  
Sediment Cores ◽  
Surface Water Quality ◽  
Water Interface ◽  
Eutrophic Lakes ◽  
Fe Addition

<p>The decline of surface water quality due to excess phosphorus (P) input is a global problem of increasing urgency. Finding sustainable measures to restore the surface water quality of eutrophic lakes with respect to P, other than by decreasing P inputs, remains a challenge. The addition of iron (Fe) salts has been shown to be effective in removing dissolved phosphate from the water column of eutrophic lakes. However, the resulting changes in biogeochemical processes in sediments as well as the long-term effects of Fe additions on P dynamics in both sediments and the water column are not well understood.</p><p>In this study, we assess the impact of past Fe additions on the sediment P biogeochemistry of Lake Terra Nova, a well-mixed shallow peat lake in the Netherlands. The Fe-treatment in 2010 efficiently reduced P release from the sediments to the surface waters for 6 years. Since then, the internal sediment P source in the lake has been increasing again with a growing trend over the years.</p><p>In 2020, we sampled sediments at three locations in Terra Nova, of which one received two times more Fe during treatment than the other two. Sediment cores from all sites were sectioned under oxygen-free conditions. Both the porewaters and sediments were analysed for their chemical composition, with sequential extractions providing insight into the sediment forms of P and Fe. Additional sediment cores were incubated under oxic and anoxic conditions and the respective fluxes of P and Fe across the sediment water interface were measured.</p><p>The results suggest that Fe and P dynamics in the lake sediments are strongly coupled. We also find that the P dynamics are sensitive to the amount of Fe supplied, even though enhanced burial of P in the sediment was not detected. The results of the sequential extraction procedure for P, which distinguishes P associated with humic acids and Fe oxides, as well as reduced flux of Fe(II) across the sediment water interface in the anoxic incubations, suggest a major role of organic matter in the interaction of Fe and P in these sediments.</p><p>Further research will include investigations of the role of organic matter and sulphur in determining the success of Fe-treatment in sequestering P in lake sediments. Based on these data in combination with reactive transport modelling we aim to constrain conditions for successful lake restoration through Fe addition.</p>

Enhanced Prairie Wetland Effects on Surface Water Quality in Crowfoot Creek, Alberta

2003 ◽  
Vol 38 (2) ◽  
pp. 335-359 ◽  
Author(s):  
Gerald R. Ontkean ◽  
David S. Chanasyk ◽  
Sandi Riemersma ◽  
D. Rodney Bennett ◽  
Jerry M. Brunen
Keyword(s):  
Water Quality ◽  
Surface Water ◽  
Surface Water Quality ◽  
Nutrient Status ◽  
Nutrient Concentrations ◽  
Prairie Wetland ◽  
Spring Runoff ◽  
Creek Watershed ◽  
Decomposition Of Organic Matter ◽  
Waterfowl Habitat

Abstract A three-year study was conducted to examine the effects of a prairie wetland enhanced for waterfowl habitat on surface water quality in the Crowfoot Creek watershed in southern Alberta, Canada. Monitoring was carried out at the Hilton wetland from mid-March to the end of October in 1997 to 1999 at two inflow sites and one outflow site. Data were collected on flow, total phosphorus (TP), total nitrogen (TN), total suspended solids (TSS), and fecal coliform (FC) bacteria. Nutrient concentrations were highest in the spring, and decreased during the remainder of the monitoring period each year. Nutrient concentrations did not change significantly within the wetland due to the form of nutrient, reduced retention times for nutrient uptake, and the addition of nutrients to the water through sediment release and decomposition of organic matter. The wetland acted as both a source and a sink for nutrients, depending on flow volumes. TSS concentrations decreased significantly from inflow to outflow, indicating sedimentation occurred in the wetland. FC bacteria levels were lowest in the spring and increased during the post-spring runoff (PSRO) period. FC bacteria counts decreased significantly within the wetland throughout the entire year. The Hilton wetland was effective in reducing the amounts of TSS and FC bacteria exported from the wetland; however, there was no significant change in nutrient status.

Seasonal and spatial variations in characteristics of Lake Biwa dissolved organic matter: sorption of pyrene and its derivatives and fluorescence properties

2008 ◽  
Vol 58 (8) ◽  
pp. 1609-1614
Author(s):  
T. Kusakabe ◽  
K. Ikeda ◽  
Y. Shimizu ◽  
S. Higashi ◽  
Y. Kawabata ◽  
...  
Keyword(s):  
Organic Matter ◽  
Dissolved Organic Matter ◽  
Lake Biwa ◽  
Vertical Mixing ◽  
Three Dimensional ◽  
Spatial Variations ◽  
Fluorescence Properties ◽  
Sorption Coefficient ◽  
Suwannee River Fulvic Acid ◽  
Seasonal And Spatial Variations

The objectives of this research were to investigate seasonal and spatial variations in (1) sorption of pyrene and its derivatives onto dissolved organic matter (DOM) and (2) fluorescence properties of DOM in Lake Biwa, Japan. In the case of pyrene, sorption coefficient (Kdoc) of Lake Biwa DOM seasonally changed from 1,200 to 3,800 L/kgC. Vertical distribution of Kdoc was affected by thermocline formation in summer, while it was uniformly distributed as a result of vertical mixing in winter. Functional groups affected sorption of pyrene onto Lake Biwa DOM in different manner from that onto Suwannee River fulvic acid. Three-dimensional excitation emission matrices (3D-EEMs) fluorescence spectroscopy was applied to characterize Lake Biwa DOMs and indicated the existence of at least two fluorophores. The two major peaks at Ex230/Em300 and Ex230/Em425 originated from protein-like and fulvic/humic-like substances, respectively. The peak at Ex230/Em300 showed the maximum fluorescence intensity at a depth of 5 m and could be affected by stratification of the water column in summer. On the other hand, the peak at Ex230/Em425 showed similar profiles both in summer and in winter. These results demonstrably showed that sorption of micropollutants and fluorescence properties of Lake Biwa DOMs were seasonally and spatially varied.

scholarly journals An assessment of the Effects of Housing Development on Water quality in Enugu Urban

2021 ◽  
pp. 33-37
Author(s):  
Eke B.L. ◽  
Essaghah A.E. ◽  
Okechukwu C.N.
Keyword(s):  
Water Quality ◽  
Organic Matter ◽  
Surface Water ◽  
Water Sample ◽  
Environmental Quality ◽  
Surface Water Quality ◽  
Housing Development ◽  
Environmental Standards ◽  
Rivers And Streams ◽  
Enugu State

This study examined the effect of housing development on surface water quality in Enugu urban. The research design used for this study was experimental. A total of 11 samples of water were collected from the various selected site locations within the study area, in the three local government areas of Enugu urban. The water sample was collected with acid-washed and open dried polyethylene bottles, the samples were labeled according to their various rivers and streams, the polyethylene bottles were corked and were kept in ice-filled boxes, transported to PRODA for analysis. The major findings of the study showed that housing development in Enugu urban has a negative significant impact on water quality because Okwuosa river has an Organic matter level of 4.19 while WHO Limit is 2,9, therefore this aspect should be monitored for Okwuosa river in Enugu South. Other findings were Compared with the WHO standard and it showed that water quality deteriorates as housing development progresses. It is therefore the recommendation of the study that the housing authorities in Enugu state should institute measures to ensure that housing development does not compromise environmental quality and house owners and indeed all residents should be properly sensitized through environmental education on the dangers of abusing environmental standards.

scholarly journals Groundwater impacts on surface water quality and nutrient loads in lowland polder catchments: monitoring the greater Amsterdam area

2018 ◽  
Vol 22 (1) ◽  
pp. 487-508 ◽  
Author(s):  
Liang Yu ◽  
Joachim Rozemeijer ◽  
Boris M. van Breukelen ◽  
Maarten Ouboter ◽  
Corné van der Vlugt ◽  
...  
Keyword(s):  
Water Quality ◽  
Surface Water ◽  
Surface Water Quality ◽  
Anthropogenic Sources ◽  
Nutrient Concentrations ◽  
Nutrient Loads ◽  
Surface Water Chemistry ◽  
Seepage Rate ◽  
Groundwater Seepage ◽  
Nutrient Levels

Abstract. The Amsterdam area, a highly manipulated delta area formed by polders and reclaimed lakes, struggles with high nutrient levels in its surface water system. The polders receive spatially and temporally variable amounts of water and nutrients via surface runoff, groundwater seepage, sewer leakage, and via water inlets from upstream polders. Diffuse anthropogenic sources, such as manure and fertiliser use and atmospheric deposition, add to the water quality problems in the polders. The major nutrient sources and pathways have not yet been clarified due to the complex hydrological system in lowland catchments with both urban and agricultural areas. In this study, the spatial variability of the groundwater seepage impact was identified by exploiting the dense groundwater and surface water monitoring networks in Amsterdam and its surrounding polders. A total of 25 variables (concentrations of total nitrogen (TN), total phosphorus (TP), NH4, NO3, HCO3, SO4, Ca, and Cl in surface water and groundwater, N and P agricultural inputs, seepage rate, elevation, land-use, and soil type) for 144 polders were analysed statistically and interpreted in relation to sources, transport mechanisms, and pathways. The results imply that groundwater is a large source of nutrients in the greater Amsterdam mixed urban–agricultural catchments. The groundwater nutrient concentrations exceeded the surface water environmental quality standards (EQSs) in 93 % of the polders for TP and in 91 % for TN. Groundwater outflow into the polders thus adds to nutrient levels in the surface water. High correlations (R2 up to 0.88) between solutes in groundwater and surface water, together with the close similarities in their spatial patterns, confirmed the large impact of groundwater on surface water chemistry, especially in the polders that have high seepage rates. Our analysis indicates that the elevated nutrient and bicarbonate concentrations in the groundwater seepage originate from the decomposition of organic matter in subsurface sediments coupled to sulfate reduction and possibly methanogenesis. The large loads of nutrient-rich groundwater seepage into the deepest polders indirectly affect surface water quality in the surrounding area, because excess water from the deep polders is pumped out and used to supply water to the surrounding infiltrating polders in dry periods. The study shows the importance of the connection between groundwater and surface water nutrient chemistry in the greater Amsterdam area. We expect that taking account of groundwater–surface water interaction is also important in other subsiding and urbanising deltas around the world, where water is managed intensively in order to enable agricultural productivity and achieve water-sustainable cities.

Past trophic status and hypolimnetic anoxia during eutrophicaton and remediation of Gravenhurst Bay, Ontario: comparison of diatoms, chironomids, and historical records

2000 ◽  
Vol 57 (2) ◽  
pp. 333-341 ◽  
Author(s):  
Joanne L Little ◽  
Roland I Hall ◽  
Roberto Quinlan ◽  
John P Smol
Keyword(s):  
Water Quality ◽  
Surface Water ◽  
Total Phosphorus ◽  
Sewage Treatment ◽  
Surface Water Quality ◽  
Nutrient Concentrations ◽  
Historical Records ◽  
European Settlement ◽  
Chironomid Assemblages ◽  
Sewage Treatment Water

Quantitative paleolimnological inferences of diatom-inferred total phosphorus and chironomid-inferred hypolimnetic oxygen levels (measured as the anoxic factor) were compared along with historical records for Gravenhurst Bay, Ontario, prior to and following sewage treatment. Water quality declined dramatically following European settlement in the mid-1800s and reached its highest inferred nutrient concentrations during the first half of the twentieth century. After treatment of sewage began in 1972, surface water total phosphorus rapidly returned to near oligotrophic conditions. Diatom assemblages reflected the period of nutrient enrichment, as well as the subsequent recovery. Chironomid assemblages exhibited trends consistent with decreased availability of dissolved oxygen to deepwater habitats since ca. 1886, with profundal taxa being largely absent since ca. 1958 when deepwater anoxia became more severe. Despite remediation efforts, Gravenhurst Bay still experiences long periods of anoxia, and chironomid assemblages have shown no sign of recovery to the improved surface water quality. We suggest that chironomid assemblages responded more strongly to changes in deepwater oxygen availability than to epilimnetic nutrient concentrations, especially during periods of pronounced hypoxia. This study demonstrates the advantages of using both chironomids and diatoms in paleolimnological assessments of eutrophication, as the indicators track changes in different lake strata.

scholarly journals Temporal Aspects of Surface Water Quality Variation Using Robust Statistical Tools

2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
Adamu Mustapha ◽  
Ahmad Zaharin Aris ◽  
Mohammad Firuz Ramli ◽  
Hafizan Juahir
Keyword(s):  
Water Quality ◽  
Surface Water ◽  
Oxygen Demand ◽  
Surface Water Quality ◽  
Repeated Measure ◽  
Wet Season ◽  
Statistical Tools ◽  
Linear Effect ◽  
Water Quality Variation ◽  
Quality Variation

Robust statistical tools were applied on the water quality datasets with the aim of determining the most significance parameters and their contribution towards temporal water quality variation. Surface water samples were collected from four different sampling points during dry and wet seasons and analyzed for their physicochemical constituents. Discriminant analysis (DA) provided better results with great discriminatory ability by using five parameters with (P<0.05) for dry season affording more than 96% correct assignation and used five and six parameters for forward and backward stepwise in wet season data withP-value (P<0.05) affording 68.20% and 82%, respectively. Partial correlation results revealed that there are strong (rp=0.829) and moderate (rp=0.614) relationships between five-day biochemical oxygen demand (BOD5) and chemical oxygen demand (COD), total solids (TS) and dissolved solids (DS) controlling for the linear effect of nitrogen in the form of ammonia (NH3) and conductivity for dry and wet seasons, respectively. Multiple linear regression identified the contribution of each variable with significant valuesr= 0.988,R2= 0.976 andr= 0.970,R2= 0.942 (P<0.05) for dry and wet seasons, respectively. Repeated measuret-test confirmed that the surface water quality varies significantly between the seasons with significant valueP<0.05.

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