scholarly journals Persistent and mobile organic chemicals in water resources: occurrence and removal options for water utilities

Author(s):  
Marco Scheurer ◽  
Anna Sandholzer ◽  
Tobias Schnabel ◽  
Stephanie Schneider-Werres ◽  
Mario Schaffer ◽  
...  

Abstract Persistent and mobile organic micropollutants (PMOC) are being recognized as serious threats to water resources and drinking water suppliers have to use advanced treatment if raw waters are contaminated with PM substances. In this study, analytical methods for 25 micropollutants for which insufficient or no data on their occurrence in surface waters and on their behavior during drinking water treatment were available, were developed. More than 120 surface water samples were analyzed and laboratory tests were performed to evaluate the compoundś behavior during aerobic bank filtration (BF), activated carbon treatment, and ozonation. Ensulizole, 1,3-diphenylguanidine and 2-acrylamido-2-methylpropane sulfonic acid had revealed the highest detection frequencies in the Rhine river. Concentration level and detection frequency correlated positively with the wastewater fraction. However, street run-off is likely an additional discharge pathway for 1,3-diphenylguanidine. In simulated BF, 7 (6) substances could be classified as persistent (very persistent). By applying powdered activated carbon, 42% of the substances were well removed as it was the case for 50% of the compounds when applying 0.2 mg/L O3. In total, eight of the substances detected in surface waters were weakly removed by at least one of the investigated removal processes and may cause problems for drinking water suppliers.

Membranes ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 72
Author(s):  
Rui M. C. Viegas ◽  
Margarida Campinas ◽  
Rosário Coelho ◽  
Helena Lucas ◽  
Maria João Rosa

Two pilot trials of powdered activated carbon (PAC)/(coagulation)/ceramic microfiltration were conducted to compare continuous 10–12 mg/L PAC inline dosing with 8–10 mg/L dosing to a 2 h-contact tank. Two low turbidity/low natural organic matter (NOM, total organic carbon <2 mg C/L) surface waters spiked with 7.2–10.3 µg/L total-pesticides were tested and the dosing options were compared towards operational performance, average removal of pesticides and NOM and costs. Removal differences between the two PAC dosing options depended on pesticides’ amenability to adsorption and NOM characteristics (254 nm absorbance, A254). Waters containing low A254-absorbing NOM and only pesticides amenable to adsorption showed very high removals (all pesticides ≥93%) and no significant differences between the two PAC dosing options. Waters containing higher A254-absorbing NOM and high loads of pesticides less amenable to adsorption (dimethoate, bentazone) required higher inline PAC dose. Those or more severe conditions may require PAC doses higher than tested to comply with the Drinking Water Directive limits for pesticides. Cost analysis showed PAC inline dosing is more cost-effective than PAC dosing to the contact tank when identical PAC dose is sufficient or when the doses are low, even if 50% higher for inline dosing, and the plant is small.


Author(s):  
O.J.I. Kramer ◽  
C. van Schaik ◽  
P.D.R. Dacomba-Torres ◽  
P.J. de Moel ◽  
E.S. Boek ◽  
...  

Author(s):  
Nguyet Thi-Minh Dao ◽  
The-Anh Nguyen ◽  
Viet-Anh Nguyen ◽  
Mitsuharu Terashima ◽  
Hidenari Yasui

The occurrence of pesticides even at low concentrations in drinking water sources might induce potential risks to public health. This study aimed to investigate the removal mechanisms of eight pesticides by the nitrifying expanded-bed filter using biological activated carbon media at the pretreatment of a drinking water plant. The field analysis demonstrated that four pesticides Flutolanil, Buprofezin, Chlorpyrifos, and Fenobucard, were removed at 82%, 55%, 54%, and 52% respectively, while others were not significantly removed. Under controlled laboratory conditions with continuous and batch experiments, the adsorption onto the biological activated carbon media was demonstrated to be the main removal pathway of the pesticides. The contribution of microorganisms to the pesticide removals was rather limited. The pesticide removals observed in the field reactor was speculated to be the adsorption on the suspended solids presented in the influent water. The obtained results highlighted the need to apply a more efficient and cost-effective technology to remove the pesticide in the drinking water treatment process. Keywords: biological activated carbon; drinking water treatment; nitrifying expanded-bed filter; pesticide removal.


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