Evaluation of Treatment Efficiency of Processes for Petroleum Refinery Wastewater

1994 ◽  
Vol 29 (8) ◽  
pp. 47-50 ◽  
Author(s):  
Kee Kean Chin

Processes used in the treatment of a petroleum refinery wastewater included initial API oil separator to be followed by dissolved air flotation and an extended aeration system. The API oil separator removed most of the settleable solids and oil. The residual oil varied from around 680 mg/l to 104 mg/l and was further treated with chemical coagulation, flocculation and dissolved air flotation which remove more than 80 % of the oil and grease. Mean COD after dissolved air flotation was around 970 mg/l and it was lowered to around 378 mg/l using the extended aeration biological system at 15-day HRT. The final effluent COD/BOD ratio was high indicating the presence of a high percentage of refractory organic compounds.

JUMINTEN ◽  
2020 ◽  
Vol 1 (2) ◽  
pp. 93-104
Author(s):  
Amanullah Fathurrahman ◽  
Iriani Iriani ◽  
Dwi Sukma Donoriyanto

CV. ABC merupakan pabrik yang bergerak dalam bidang olahan kayu seperti speaker aktif dan mebel-mebel. Dimana perusahaan tersebut memiliki sebuah komitmen internal dalam proses produksinya, agar dapat mengurangi dampak lingkungan dan memelihara ekosistem disekitarnya. Namun dalam kenyataannya, dalam proses produksinya baku mutu air perusahaan melebihi dari standar PERGUBJATIM No. 72 Tahun 2013, COD (Chemical Oxygen Demand) yang diatas batas standar sebesar 61,40 mg/l dan Oil and Grease sebesar 12 mg/l. Dimana akan berdampak pada lingkungan sekitar yang dapat mengganggu kesehatan lingkungan sekitar, selain itu dapat berdampak menurunnya produktivitas dan kinerja lingkungan perusahaan. Dengan adanya permasalahan tersebut pendekatan yang tepat untuk membantu perusahaan agar dapat mampu meningkatkan produktivitas serta kinerja lingkungan tersebut adalah dengan menerapkan metode Green Productivity (GP). Penelitian ini bertujuan untuk dapat mengevaluasi pengelolaan limbah berbasis Green Productivity, serta dapat memberikan usulan perbaikan dalam pengelolaan limbah. Hasil yang didapat diketahui bahwa terdapat 2 alternatif yang dapat menurunkan tingkat BOD (Biological Oxygen Demand), COD (Chemical Oxygen Demand), TSS (Total Suspeded Solid), Oil and Grease. Akan tetapi solusi yang dapat dijadikan usulan perbaikan adalah alternatif 2, yitu pemasangan alat DAF (Dissolved Air Flotation). Keuntungan yang didapatkan CV. ABC dengan alternatif 2 ini adalah peningkatan Green Productivity Index yang ditunjukan Green Productivity Ratio sebesar 13,06 dan Tingkat Produktivitas meningkat sebesar 0,01 %


Author(s):  
Siyasanga Mbulawa ◽  
Seteno Karabo Obed Ntwampe ◽  
Moses Basitere ◽  
Yolanda Mpentshu ◽  
Cynthia Dlangamandla ◽  
...  

Delipidation is a method of defatting that is generally associated with the removal of residual lipids or lipid groups from matrices in which they are present in minute quantities. The bio-delipidation of protein-rich poultry slaughterhouse wastewater (PSW) pre-treated with a dissolved air flotation (DAF) system was developed using microbial lipases from bacterial strains isolated from the PSW. The efficacy of the bio-delipidation system was quantitatively characterised by comparing the quality parameters i.e., fats, oil and grease (FOGs), turbidity, total suspended solutes (TSS), total chemical oxygen demand (tCOD) and protein concentration of the DAF pre-treated PSW and bio-lipidized samples. As hypothesised, the bio-delipidation system was able to effectively reduce the levels of these quality parameters when crude lipases of Bacillus cereus AB1 (BF3) and Bacillus cereus CC-1 (B30) strains were used. Strain-dependent quality characteristics were also observed in bio-delipidized samples. The study successfully managed to complement physical reduction techniques (DAF) with biological strategies (bio-delipidation) for improved PSW quality, with potential industrial applications.


2013 ◽  
Vol 49 (2) ◽  
pp. 135-143 ◽  
Author(s):  
Jessica M. Younker ◽  
Margaret E. Walsh

Produced water is a major wastewater stream in the oil and gas industry which typically consists of dispersed and dissolved oils, and high levels of salinity. Despite concerns that dissolved aromatics in produced water may be detrimental to marine life, discharge regulations and treatment technologies for produced water largely focus on dispersed oil and grease removal. The purpose of this research project was to investigate coagulation with ferric chloride (FeCl3) and dissolved air flotation (DAF) at bench-scale for the removal of both dispersed and dissolved oils from synthetic and offshore produced water samples, with a specific focus on the impact of salinity on the coagulation process. Coagulation and DAF treatment of the produced water samples achieved high removals of dispersed oil and grease, but had limited impact on dissolved aromatics. The coagulation process in the saline produced water samples reduced dispersed oil and grease concentrations from 100 mg/L to below North American discharge limits (i.e. 30 mg/L in Canada, 29 mg/L in the USA) under all conditions tested, while the effectiveness of coagulation treatment in the fresh water synthetic samples was highly dependent on coagulation pH.


2017 ◽  
Vol 12 (3) ◽  
pp. 534-540 ◽  
Author(s):  
Dayana Melo Torres ◽  
André Luís Calado Araújo ◽  
Rui de Oliveira ◽  
André Câmara de Brito

This work evaluated the performance of a dissolved air flotation (DAF) system for biomass recovery from the effluent of algal ponds used for sewage treatment in Northeast Brazil. Two different coagulants and effluent samples were tested following a random-factor experimental design (34–1–4 factors and 3 levels), in triplicate. Factor analysis showed that coagulant dose was the most important factor, independently of the type of coagulant and sample characteristics. For polyaluminium chloride it is possible to work with the original sample pH at the lower recirculation rate (10%) and flocculation time (10 minutes), being able to recovery an algal masses (dry basis) of around 1,200 kg/day and 550 kg/day from the primary facultative and second maturation pond (final effluent), respectively. DAF was more efficient for ferric chloride, however a pH correction to the value of 5.0 was necessary, leading the process to generate masses of solids (dry basis) of about 1,150 kg/day for the facultative pond and 830 kg/day for the maturation pond. Removals of suspended solids, turbidity, and chlorophyll-a were above 60%, reaching at optimal conditions removals up to 90%.


2018 ◽  
Vol 6 ◽  
pp. 1173-1177
Author(s):  
Emmanuel Kweinor Tetteh ◽  
Sudesh Rathilal

The global demand for petrochemical and petroleum industry products unavoidably generates large volumes of oil refinery wastewater (ORW). The complete treatment, reclamation and disposal of the ORW to an acceptable environmental limit is currently a challenge to most of the petroleum industries. With the current development in conventional treatment methods viz. coagulation, dissolved air flotation (DAF), and biological and membrane separation processes. DAF, which is well-established separation process, effectively employs microbubbles as a carrier phase for separation. Although, DAF is frequently used in combined water and wastewater treatment plants, its fundamental characteristics and operational parameters have not yet been fully investigated for the treatment of ORW. In this study, the correlation and effects of the parameters understudy (coagulant dosage, air saturator pressure, air-water ratio and rising rate) on chemical oxygen demand, soap oil and grease, turbidity and total suspended solids removal from ORW were examined experimentally using a laboratory DAF system. The results showed that increasing the saturator working pressure and the rising rate had less effect on the system, than increasing the air-water ratio. The agglomeration of the oil droplets was found to depend solely on the polyaluminum sulphate (PAS) dosage to destabilize the oil droplets. The DAF treatability performance showed over 80% removal of the contaminants at optimum conditions of pH of 5, PAS dosage of 10 mg/L, rising rate of 15 minutes, air saturator pressure of 300-500 kPa, and air-water ratio of 5-15%. The PAS dosage was found to be the most significant factor. Therefore, a moderate increase of the PAS dosage under these optimum conditions will increase the DAF efficiency in the treatment of ORW.


2013 ◽  
Vol 40 (12) ◽  
pp. 1164-1172 ◽  
Author(s):  
Wayne Chung ◽  
Stephanie Young

Restaurant dishwashers consume a large quantity of fresh water and produce significant amounts of high strength oily wastewater which may cause serious problems when discharged into the sewer. An analysis of restaurant dishwasher effluent (RDE) from a busy upscale restaurant identified high levels of oil and grease, chemical oxygen demand (COD), biochemical oxygen demand (BOD), alkalinity, pH, and chlorine, but low levels of nitrogen and phosphorus. In this study, RDE was treated using an internationally patented chemical dissolved air flotation (chemical DAF) system. The chemical DAF system was designed so that coagulation, flocculation, and flotation processes could be carried out within the same reactor. The treatment system is therefore small and compact and suitable for use in restaurants where space is limited. The treatment performance of the chemical DAF was evaluated by determining optimal process conditions, contaminant removal efficiencies, and residual contaminant concentrations. It was found that removal efficiencies of 98.90%, 93.16%, 98.68%, 90.04%, and 88.20% could be achieved under optimal process conditions for turbidity, oil, TSS, BOD5, and COD, respectively. Total coliform and E. coli were not detected in either the raw dishwasher effluent or the treated dishwasher effluent due to the use of sodium hypochlorite as a dishwashing sanitizer. Water quality of the treated effluent met the criteria put forth in the Canadian Guidelines for Domestic Reclaimed Water for Use in Toilet and Urinal Flushing, with the exception of BOD5. Present findings suggest that chemical DAF is a promising treatment process for the removal of contaminants from restaurant dishwasher effluent.


1989 ◽  
Vol 24 (3) ◽  
pp. 363-390 ◽  
Author(s):  
P.L. Dold

Abstract Current practice and experience in the treatment of petroleum refinery wastewater is reviewed briefly, with emphasis on the fate of toxic contaminants. The sources and composition of the wastewater are described in terms of the parameters adopted for evaluating the performance of individual treatment units. The parameters include oil and grease content and sulphide concentration for evaluating the primary treatment units: sour water stripping, API separation and dissolved air flotation (DAF). COD, BOD, suspended solids and “listed” trace contaminant concentrations are considered in the description of biological activated sludge secondary treatment. Current treatment technology achieves a significant reduction in toxic contaminants and other pollutants generated in the petroleum refining process, with the principle reduction occurring in the activated sludge system. The removal mechanisms considered in activated sludge are biological degradation, nitrification, stripping of VOC’s, biosorption, bioaccumulation of heavy metals and heavy metal precipitation. A number of potential problems associated with activated sludge treatment are identified; amongst others, high effluent COD’s, presence of toxic contaminants (at low concentrations) in the treated effluent, inhibition, poor sludge settleability, and waste sludge disposal.


1989 ◽  
Vol 24 (3) ◽  
pp. 463-477
Author(s):  
Stephen G. Nutt

Abstract Based on discussions in workshop sessions, several recurring themes became evident with respect to the optimization and control of petroleum refinery wastewater treatment systems to achieve effective removal of toxic contaminants. It was apparent that statistical process control (SPC) techniques are finding more widespread use and have been found to be effective. However, the implementation of real-time process control strategies in petroleum refinery wastewater treatment systems is in its infancy. Considerable effort will need to be expended to demonstrate the practicality of on-line sensors, and the utility of automated process control in petroleum refinery wastewater treatment systems. This paper provides a summary of the discussions held at the workshop.


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