Regulating Specific Organic Substances and Heavy Metals in Industrial Wastewater Discharged to Municipal Wastewater Treatment Plants

1994 ◽  
Vol 29 (9) ◽  
pp. 55-67
Author(s):  
H. Grüttner ◽  
L. Munk ◽  
F. Pedersen ◽  
J. Tørsløv

Due to the extension of wastewater treatment plants to nutrient removal and the development towards reuse of sludge in agriculture, new guidelines for regulating industrial discharges in Denmark were needed. The paper describes how a concept for regulating the discharge of specific organic substances and heavy metals has been developed during the past two years. The concept is based on guidelines that are made according to considerations of the environment and the treatment plant system, and that encourage the introduction of a cleaner technology and integrated preventive measures. For most organic substances, present knowledge of fate and effects in biological treatment plants is too scarce to underpin the setting of general standards. Therefore, it has been decided to base the developed priority system on the data used in the EEC-system for classification of hazardous chemicals. This includes ready degradability, defined by the OECD-test, bio-sorption and bio-accumulation, defined by the octanol/water distribution coefficient and toxic effects on water organisms. Several potential effects of seven heavy metals have been evaluated, and the most critical effects were found to be the quality criteria for sludge intended for use in agriculture, and the quality criteria for the aquatic environment. Proposals for general guidelines have been calculated using a simple mass balance model combined with water quality criteria and the Danish limit values for use of sludge in agriculture.

1992 ◽  
Vol 25 (4-5) ◽  
pp. 413-419
Author(s):  
A. V. Ghirardini ◽  
F. Avezzù ◽  
P. Cescon

In a previous paper the A.A. used a mathematical model to describe the complex mechanisms affecting heavy metals distribution between liquid and solid phases in order to predict the quality of effluents of an activated sludge biological treatment system. In the present work the mathematical model is employed to depict the behaviour of particulate and soluble zinc in large municipal wastewater treatment plants for which operating data were available in the existing literature. The results obtained by this model, compared with experimental data, describe zinc behaviour in activated sludge systems satisfactorily. The behaviour of some other metals (zinc, nickel, copper, chromium), studied in solid and liquid3 flows of a municipal wastewater treatment plant in the north-east of Italy (5000 m3/day), is satisfactorily simulated.


1992 ◽  
Vol 25 (4-5) ◽  
pp. 429-431 ◽  
Author(s):  
M. Sedláček ◽  
T. Just

Since 1987 operators of municipal wastewater treatment plants, having the population equivalent over 5 000, monitor systematically heavy metals in sludges, based on one or two samplings on the average annually. Generally, Cd, Cr, Cu, Ni, Pb and Zn are monitored: since 1989 Hg is becoming the centre of systematic attention. Occasional data are available on concentrated Ag, Co, As and Mo. These data were collected and ordered by the authors of the paper. On their basis lines of exceedance were plotted and sets were prepared, characterizing both localities with the common level of the sludge contamination, and with the extremely low contamination level reflecting the condition that could be achieved if measures limiting the heavy metal input into public sewerage systems were adopted. The results achieved were compared with heavy metal concentration limits, as determined in the Industrial composts standard, both for raw materials used for the compost production, and for composts of Ist and IInd grades. With a view to the general environmental contamination, and considering the present economic and agricultural use, the input raw materials should meet the demands that are required under the standard for the prepared composts.


1999 ◽  
Vol 40 (7) ◽  
pp. 55-65 ◽  
Author(s):  
Mohamed F. Hamoda ◽  
Ibrahim A. Al-Ghusain ◽  
Ahmed H. Hassan

Proper operation of municipal wastewater treatment plants is important in producing an effluent which meets quality requirements of regulatory agencies and in minimizing detrimental effects on the environment. This paper examined plant dynamics and modeling techniques with emphasis placed on the digital computing technology of Artificial Neural Networks (ANN). A backpropagation model was developed to model the municipal wastewater treatment plant at Ardiya, Kuwait City, Kuwait. Results obtained prove that Neural Networks present a versatile tool in modeling full-scale operational wastewater treatment plants and provide an alternative methodology for predicting the performance of treatment plants. The overall suspended solids (TSS) and organic pollutants (BOD) removal efficiencies achieved at Ardiya plant over a period of 16 months were 94.6 and 97.3 percent, respectively. Plant performance was adequately predicted using the backpropagation ANN model. The correlation coefficients between the predicted and actual effluent data using the best model was 0.72 for TSS compared to 0.74 for BOD. The best ANN structure does not necessarily mean the most number of hidden layers.


2021 ◽  
Vol 6 (4) ◽  
pp. 244-250
Author(s):  
Serhii Protsenko ◽  
◽  
Mykola Kizyeyev ◽  
Olha Novytska ◽  
◽  
...  

The possibility of increasing the efficiency of municipal wastewater treatment plant (WWTP) operation by changing the flow diagram of biological wastewater treatment in aeration tanks at minimum expenses for their reconstruction is shown in the paper on the example of one of the regional centres of Ukraine. The technology of nitri-denitrification of wastewater according to the flow diagram of the two-stage modified Ludzak-Ettinger process is offered for the considered conditions. The distribution of wastewater flows and internal nitrate recycling between the individual stages of this flow diagram has been optimized in order to minimize the residual content of total nitrogen in the treated effluents. Computer dynamic modelling of biochemical processes has proved the high efficiency and reliability of the flow diagram proposed by the authors.


Water ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1248 ◽  
Author(s):  
Yuhua Zhou ◽  
Jing Lei ◽  
Yu Zhang ◽  
Jing Zhu ◽  
Yanna Lu ◽  
...  

Industrial wastewater and sewage are both important sources of heavy metals and metalloids in urban wastewater treatment plants (WWTPs). China has made great efforts to control heavy metal and metalloid pollution by setting discharge limits for WWTPs. There is, however, limited discharge data and no systematic methodology for the derivation of discharge limits. In this study, 14 heavy metals and metalloids (Hg, alkyl mercury, As, Cd, Cr, Cr6+, Pb, Ni, Be, Ag, Cu, Zn, Mn, Se) that are listed in the Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB 18918-2002) were selected for the analysis of discharge characteristics while using the supervised monitoring data from more than 800 WWTPs located in nine provinces in China. Of the 14 heavy metals and metalloids, all but alkyl mercury were detected in the discharge water. There was a high rate of detection of As, Cu, Mn, Se, and there were some samples that exceeded the standard concentrations of Cr, Cr6+, Pb, and Ni. Removal rates of Hg, As, Cd, Cr, Cr6+, Pb, Ni, Cu, Zn, Mn, and Se were higher than 40%, comparable to values from other countries. Hg and As were selected to analyze the influencing factors of effluent and derive discharge limits of WWTPs using a statistical method, because these two metals had more detected data than other metals. The study used supervised monitoring data from Zhejiang WWTPs with 99 for Hg and 112 for As. Based on the delta-lognormal distribution, the results showed that geographic location was significantly closely correlated with Hg (P = 0.027 < 0.05) and As (P ≈ 0 < 0.05) discharge concentrations, while size (for Hg P = 0.695 > 0.05, for As P = 0.088 > 0.05) and influent concentration (R2 < 0.5) were not. Derived Hg and As discharge limits suggest that it is necessary to establish stricter discharge limits for WWTPs, which is more consistent with the real-world situation in China. The study here comprehensively researches the discharge characteristics of heavy metals and metalloids in effluent of WWTPs in China, and developed for the first time in China heavy metals and metalloids discharge limits based on statistical methods. The results may inform special discharge limit settings for WWTPs in China.


2008 ◽  
Vol 57 (10) ◽  
pp. 1487-1493 ◽  
Author(s):  
S. Lindtner ◽  
H. Schaar ◽  
H. Kroiss

During a six-year period the Austrian Benchmarking System was developed. The main objectives of this benchmarking system are the development of process indicators, identification of best performance and determination of cost reduction potentials. Since 2004 this system is operated via an internet platform and automated to a large extent. Every year twenty to thirty treatment plants use the web-based access to this benchmarking platform. The benchmarking procedure comprises data acquisition, data evaluation including reporting and organised exchange of experience for the treatment plant managers. The process benchmarking method links the real costs with four defined main processes and two support processes. For wastewater treatment plants with a design capacity &gt;100,000 PE these processes are further split up into sub-processes. For each (sub-) process the operating costs are attributed to six cost elements. The specific total yearly costs and the yearly operating costs of all (sub-)processes are related to the measured mean yearly pollution load of the plant expressed in population equivalents (PE110: 110 gCOD/d corresponding to 60 g BOD5/d)). The specific capital costs are related to the design capacity (PE). The paper shows the benchmarking results of 6 Austrian plants with a design capacity &gt;100,000 PE representing approximately 30% of the Austrian municipal wastewater treatment plant capacity.


2018 ◽  
Vol 4 (12) ◽  
pp. 1988-1996 ◽  
Author(s):  
Yan He ◽  
Yishuang Zhu ◽  
Jinghan Chen ◽  
Minsheng Huang ◽  
Guohua Wang ◽  
...  

The tense deficiency of available land resources is becoming one of the bottlenecks in dealing with wastewater treatment plant (WWTP) management issues.


Membranes ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 421
Author(s):  
Dimitra C. Banti ◽  
Michail Tsangas ◽  
Petros Samaras ◽  
Antonis Zorpas

Membrane bioreactor (MBR) systems are connected to several advantages compared to the conventional activated sludge (CAS) units. This work aims to the examination of the life cycle environmental impact of an MBR against a CAS unit when treating municipal wastewater with similar influent loading (BOD = 400 mg/L) and giving similar high-quality effluent (BOD < 5 mg/L). The MBR unit contained a denitrification, an aeration and a membrane tank, whereas the CAS unit included an equalization, a denitrification, a nitrification, a sedimentation, a mixing, a flocculation tank and a drum filter. Several impact categories factors were calculated by implementing the Life Cycle Assessment (LCA) methodology, including acidification potential, eutrophication potential, global warming potential (GWP), ozone depletion potential and photochemical ozone creation potential of the plants throughout their life cycle. Real data from two wastewater treatment plants were used. The research focused on two parameters which constitute the main differences between the two treatment plants: The excess sludge removal life cycle contribution—where GWPMBR = 0.50 kg CO2-eq*FU−1 and GWPCAS = 2.67 kg CO2-eq*FU−1 without sludge removal—and the wastewater treatment plant life cycle contribution—where GWPMBR = 0.002 kg CO2-eq*FU−1 and GWPCAS = 0.14 kg CO2-eq*FU−1 without land area contribution. Finally, in all the examined cases the environmental superiority of the MBR process was found.


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