scholarly journals Effect of magnetic iron-zirconium modified zeolite on the different phosphorus forms in river sediment under aerobic and anoxic condition

Author(s):  
Chunlei Wang ◽  
Herong Gui ◽  
Chen Li ◽  
Jiayu Chen ◽  
Chen Chen

Abstract In this study, a magnetic iron-zirconium modified zeolite (FeZrMZ) was synthesized. Through sediment culture experiments, the influence of the addition of modified materials on the migration and transformation of phosphorus in river sediments was investigated. The results show that the modified zeolite can not only effectively reduce the phosphorus concentration in the overlying water, but also significantly reduce the phosphorus concentration in the pore water of sediments. The addition of modified zeolite makes the unstable weakly adsorbed phosphorus (NH4Cl-P) and redox phosphorus (BD-P) transform into the more stable metal oxide bound phosphorus (NaOH-P) and very stable residual phosphorus (Res-P).The four types of bioavailable phosphorus (BAP), including water-soluble phosphorus (WSP), readily desorbable phosphorus (RDP), algae-available phosphorus (AAP), and NaHCO3 extractable phosphorus (Olsen-P). Under anoxic conditions, they were reduced by 53.5%, 14.1%, 23.8%, and 49.9% respectively. Under aerobic conditions, they were reduced by 23.2%, 16.6%, 32.1%, and 50.0%. Obviously, the addition of magnetic iron-zirconium modified zeolite can reduce the release potential of phosphorus in sediment, and it can be recovered through the action of an external magnetic field, so it can be used as an effective sediment modifier to control the sediment the release of phosphorus.

2013 ◽  
Vol 295-298 ◽  
pp. 1663-1666
Author(s):  
Jian Hang Qu ◽  
Xiao Bing He ◽  
Hai Feng Li ◽  
Huan Chen Zhai ◽  
Yuan Sen Hu

Phosphorus is the key restraining factor for algal growth and water eutrophication, which is a global problem of environmental pollution. Using a sequential phosphorus extraction method, the phosphorus forms in sediment and their distribution from different trophic area of Taihu Lake (China) and their temporal changes were studied. Results showed that, concentration of Fe-P in sediment was the highest and successively Al-P, which was much higher than that of Ca2-P, Ca10-P, Ca8-P and O-P. All the phosphorus forms were more abundant in sediment 16# of eutrophic lake area, higher than that of moderate eutrophic and the lower-grade trophic area, with the last as relatively the lowest. Phosphorus concentration in June and September was much higher than that of March. Phosphorus in sediment of Taihu Lake had great releasing potential to the overlying water.


2021 ◽  
Author(s):  
Sanshan Li ◽  
Tangming Ma ◽  
Chaoqun Zheng ◽  
Zhaofang He ◽  
Liuyan Yang ◽  
...  

Abstract In order to testify the effect of electrolysis and microbial remediation technology in polluted river sediment. Here, we explored the possibility of electrochemically removing ammoniacal nitrogen-nitrogen (NH3-N), nitrate-nitrogen (NO3−-N) and phosphate ions-phosphorous (PO43−-P) by using a titanium (Ti) mesh cathode, a Ti/Ti dioxide (TiO2)/Ruthenium (IV) oxide (RuO2) (RuO2-IrO2/Ti) mesh, and a magnesium-aluminum (Mg–Al) alloy anode placed within the sediment and overlying water. Results showed that approximately 151.82 ± 21.69 mg TN was removed which was five times more effective than the non-electrolytic controls (30.21 ± 13.73 mg), NH3-N concentration in the sediment was substantially reduced (up to 2.9 times) compared to the non-electrolytic controls. Its efficiency lies in the electrolysis process, which may directly remove NH3-N through electrochemical oxidation and simultaneously produce oxygen which helps nitrifying bacteria to convert NH3-N into NO3−-N by the role of anode; and electrolysis may directly remove NO3−-N in the overlying water through electrochemical reduction while simultaneously producing hydrogen electron donor for hydrogen autotrophic microorganism as Hydrogenophohaga, to be the dominant species in sediment to enhance the removal of NO3−-N by the role of cathode. Electrolysis also reduced the PO43−-P through electro-coagulation since Mg2+ ions could also produce since sacrificial Mg–Al alloy anode was used and electro-deposition on Ti mesh cathode both to increase PO43−-P removal in overlying water and sediment. This study verifies the benefits of electrolysis-driven bioremediation as a sustainable technology for the bioremediation of N and P polluted river sediments.


2014 ◽  
Vol 68 (8) ◽  
Author(s):  
Jitka Malá ◽  
Marcela Lagová

AbstractIn this study, four digestion methods used to determine total phosphorus in river sediments, including Na2CO3 fusion, the H2SO4 and H2SO4 + H2O2 methods and the SMT protocol were investigated. Interference effects of iron, calcium and organic matter in river sediments, and the substances contained in the digestion agents on the photometric determination of the phosphates were analysed. The digestion methods were tested on ten river sediment samples. Statistical analysis of the results showed significant differences between sample treatments relating to the mean total phosphorus concentration.


Author(s):  
Wen ◽  
Wu ◽  
Yang ◽  
Jiang ◽  
Zhong

Nutrients released from sediments have a significant influence on the water quality in eutrophic lakes and reservoirs. To clarify the internal nutrient load and provide reference for eutrophication control in Yuqiao Reservoir, a drinking water source reservoir in China, pore water profiles and sediment core incubation experiments were conducted. The nutrients in the water (soluble reactive P (SRP), nitrate-N (NO3−-N), nitrite-N (NO2−-N), and ammonium-N (NH4+-N)) and in the sediments (total N (TN), total P (TP) and total organic carbon (TOC)) were quantified. The results show that NH4+-N was the main component of inorganic N in the pore water. NH4+-N and SRP were higher in the pore water than in the overlying water, and the concentration gradient indicated a diffusion potential from the sediment to the overlying water. The NH4+-N, NO3−-N, and SRP fluxes showed significant differences amongst the seasons. The NH4+-N and SRP fluxes were significantly higher in the summer than in other seasons, while NO3−-N was higher in the autumn. The sediment generally acted as a source of NH4+-N and SRP and as a sink for NO3−-N and NO2−-N. The sediments release 1133.15 and 92.46 tons of N and P, respectively, to the overlying water each year.


Agriculture ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 553
Author(s):  
Inga-Mareike Bach ◽  
Lisa Essich ◽  
Torsten Müller

Despite phosphorus resources on Earth being limited, over fertilization in many agricultural situations causes significant resource consumption. Phosphorus-recycling within agricultural production can reduce global dilution into the environment and is thus essential to secure sustainable future supply. This study investigated the fertilization efficacy of phosphorus fertilizers recycled from biogas digestates in maize shoots grown under controlled greenhouse conditions, in two soils, in a pot experiment. Variables investigated were plant-available phosphorus in soil, plant biomass production, and concentration of phosphorus, calcium, and magnesium in shoots. Soils were treated with three different fertilizer fractions, separated from biogas digestates, at equivalent phosphorus concentrations, using different combinations and application techniques, isolated or in combination, and compared to triple superphosphate (TSP) as a reference. One of the fractions (P-Salt) had effects on biomass production and plant phosphorus concentration equivalent to TSP in agricultural surface soil. In the second soil (with less active soil life and nutrient content), equivalence to TSP was achieved with combinations of two recycled fractions (P-Salt and dried solids). The enhancement of the phosphorus fertilizing effect by the solids was synergistic, indicating that the solids had a soil conditioning effect. The results show that biogas digestates are a valuable source for phosphorus recycling of fractions that have equivalent or even superior fertilizing properties compared to TSP.


2018 ◽  
Vol 78 (11) ◽  
pp. 2247-2255 ◽  
Author(s):  
Wei Zhang ◽  
Xing Zhong ◽  
Wu Che ◽  
Huichao Sun ◽  
Hailong Zhang

Abstract In this study, laboratory-scale green (e.g. living) roof platforms were established to assess the potential use of polluted river sediment in their substrate mixture. The mean runoff retention of the green roof platforms, which contained peat and/or river sediment, after 11 artificial rainfall events was >72%, significantly higher than traditional roofs. However, green roof platforms that had been filled with peat soil showed chemical oxygen demand (COD), total nitrogen (TN) and total phosphorus (TP) leaching. Green roofs that had used river sediment showed good leaching control for COD, TN and TP. The cumulative leaching masses from the green roofs contained 30% (COD), 42% (TN) and 47% (TP) as much as the total leaching mass from traditional roofs, and the Cu, Zn, Cd and Pb leaching risk from green roofs when river sediments are used as part of a substrate mixture was relatively low. Despite some nutrient leaching in the initial phase of runoff from the green roofs, river sediment has the potential to be used as a substrate for extensive green roofs.


1993 ◽  
Vol 73 (1) ◽  
pp. 123-128 ◽  
Author(s):  
C. A. Campbell ◽  
R. P. Zentner

In the Canadian prairie, producers generally sample soils in the autumn for nutrient analyses, whereas calibration of crop responses has been made based on soils sampled in the spring prior to seeding. A recent report suggests that available phosphorus (P) in soil increases between autumn and spring. At Swift Current, Saskatchewan, we have monitored bicarbonate-extractable P (Olsen P) every autumn and spring for the past 24 years, in four cropping systems: continuous wheat (Cont W), fallow-wheat (F-W), and two fallow-wheat-wheat (F-W-W) rotations. The first three systems received nitrogen (N) and P each crop year, with one F-W-W rotation receiving only N. These data were analyzed to test the authenticity of the aforementioned observations. We found that although there were some apparent overwinter increases in Olsen P there were also some decreases. Further, because of the considerable variability in Olsen P, relatively few of the overwinter changes were significant (P = 0.10). Efforts to correlate the changes in Olsen P to overwinter temperature or precipitation were unsuccessful. We concluded that Saskatchewan soil testing laboratories need not make adjustments to P fertilizer recommendations to account for changes in overwinter soil test P levels. Key words: Soil testing, bicarbonate-extractable P, crop rotations, available P


2020 ◽  
Vol 15 (3) ◽  
pp. 624-631
Author(s):  
Vijaya Kumar Kallushettihalli Mallappa ◽  
Vijaya Kumara

The present study was carried out to determine the periodic variation in physico-chemical characteristics of mangrove soil samples. The soil samples had been accrued from four distinctive places of Kundapura mangrove areas in three seasons, monsoon, pre-monsoon and post-monsoon. Soil analysis pertaining to various variables such as total Nitrogen, Phosphorus, Potassium, pH and Electrical conductivity. Soil pH is assorted from 3.84 to 6.66. Electrical conductivity is assorted from 0.02 dSm-1 to 9.60 dSm-1. Available nitrogen is assorted from 30.7 kg/ha to 323 kg/ha. Available phosphorus concentration has ranged between 1.37 kg/ha and 47.27 kg/ha. Available potassium is differed from 117.43 kg/ha to 537.63 kg/ha. The results confirmed variations in all of the analyzed parameters of the soils amassed from four stations.


2005 ◽  
Vol 85 (5) ◽  
pp. 589-597 ◽  
Author(s):  
Chi Chang, Joann K. Whalen ◽  
Xiying Hao

Migration of P from soils to water resources poses a risk of surface water eutrophication, and increase in P concentration in soils through manure or fertilizer addition would exace rbate this problem. Investigating the rate of increase in P concentration of surface soil receiving livestock manure is crucial to the development of best manure management strategies and prevention of eutrophication of aquatic systems. In this study, the changes in P concentrations of surface soils (0- to 15-cm depth) receiving 25 annual manure applications at rates of 0, 30, 60 and 90 Mg ha-1 yr-1 under non-irrigated conditions and at rates of 0, 60, 120 and 180 Mg ha-1 yr-1 under irrigated conditions were examined. The soil test P (STP) and total P (TP) of the surface soil increased with the TP through manure application over a 25-yr period. The STP pool was about 38% of the soil TP pool, similar to ratios of STP to TP in feedlot cattle manure. While the high proportion of STP to TP could be beneficial for crop production, it could also increase the potential for P losses from these soils through runoff and leaching. The changes in TP and STP concentrations of the surface soil were modelled with an expone ntial rise to maximum function: TP = 0.69 + 5.06 (1 − e(−0.087x)) and STP = 0.029 + 2.21 (1 − e(−0.082x)) where x is the cumulative TP applied. Although the model was developed for a specific soil and type of manure, it could be adapted to other soils or manure sources by adjusting the model coefficients for the particular soil and/or manure type. These adjustments would not require as extensive a data set as was required to develop the original model. This model could be used to determine the amount of TP that could be applied for a given critical STP. Producers, regulatory agencies, planners, and extension specialists could also use this model to make decisions on manure P management. Key words: Long-term cattle manure application, total phosphorus, available phosphorus, rate of accumulation, non-irrigated and irrigated cropping


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