scholarly journals Solid Phase Supports for Flue Gas CO2 Separation with Molten Electrolytes; Final Report for CRADA TC02262

2021 ◽  
Author(s):  
P Campbell ◽  
M Merrill

1976 ◽  
Author(s):  
E Aul, Jr ◽  
R Delleney ◽  
G Brown ◽  
G Page ◽  
D Stuebner


2015 ◽  
Vol 448 ◽  
pp. 41-50 ◽  
Author(s):  
Alessandro Erto ◽  
Ana Silvestre-Albero ◽  
Joaquín Silvestre-Albero ◽  
Francisco Rodríguez-Reinoso ◽  
Marco Balsamo ◽  
...  


1979 ◽  
Vol 101 (4) ◽  
pp. 615-619 ◽  
Author(s):  
T. D. Brown ◽  
G. K. Lee ◽  
H. A. Bambrough

A pilot-scale research boiler (750 kg steam/hr) has been used to study the degree of sulphur neutralization during combustion experiments with three lignites. A series of four closely controlled experiments showed that sulphur balances close to 100 percent could be achieved in the pilot-scale system burning Gascoyne lignite; in these experiments the sulphur retained in solid phase residues varied between 21 and 24 percent of the input sulphur. It was also demonstrated with Utility lignite that external recirculation of flue-gas was moderately effective in reducing nitric oxide emissions at the expense of major increased in the carry-over of unburnt carbon. However, sulphur dioxide neutralization by the coal-ash cations remained essentially unchanged as the recirculation ratio increased. Enhancement of sulphur neutralization by dry lime addition to Poplar River lignite was only found to be effective at addition rates above 1/2 percent lime by weight. The effectiveness of the lime was found to increase as the excess-air level increased.



Author(s):  
Bruce Sass ◽  
Bruce Monzyk ◽  
Stephen Ricci ◽  
Abhishek Gupta ◽  
Barry Hindin ◽  
...  
Keyword(s):  
Flue Gas ◽  




2020 ◽  
Vol 394 ◽  
pp. 124916 ◽  
Author(s):  
H. Mert Polat ◽  
Safiyye Kavak ◽  
Harun Kulak ◽  
Alper Uzun ◽  
Seda Keskin


Materials ◽  
2019 ◽  
Vol 12 (13) ◽  
pp. 2088 ◽  
Author(s):  
Elizabeth Rodriguez Acevedo ◽  
Farid B. Cortés ◽  
Camilo A. Franco ◽  
Francisco Carrasco-Marín ◽  
Agustín F. Pérez-Cadenas ◽  
...  

The implementation of carbon capture and storage process (CCS) has been unsuccessful to date, mainly due to the technical issues and high costs associated with two main stages: (1) CO2 separation from flue gas and (2) CO2 injection in deep geological deposits, more than 300 m, where CO2 is in supercritical conditions. This study proposes, for the first time, an enhanced CCS process (e-CCS), in which the stage of CO2 separation is removed and the flue gas is injected directly in shallow reservoirs located at less than 300 m, where the adsorptive phenomena control CO2 storage. Nitrogen-rich carbon nanospheres were used as modifying agents of the reservoir porous texture to improve both the CO2 adsorption capacity and selectivity. For this purpose, sandstone was impregnated with a nanofluid and CO2 adsorption was evaluated at different pressures (atmospheric pressure and from 3 × 10−3 MPa to 3.0 MPa) and temperatures (0, 25, and 50 °C). As a main result, a mass fraction of only 20% of nanomaterials increased both the surface area and the molecular interactions, so that the increase of adsorption capacity at shallow reservoir conditions (50 °C and 3.0 MPa) was more than 677 times (from 0.00125 to 0.9 mmol g−1).



Energies ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 4556
Author(s):  
Xiaoya Zang ◽  
Na Zhang ◽  
Xuebing Zhou ◽  
Lihua Wan ◽  
Deqing Liang

Coal combustion flue gas contains CO2, a greenhouse gas and driver of climate change. Therefore, CO2 separation and removal is necessary. Fortunately, 5A zeolites are highly porous and can be used as a CO2 adsorbent. In addition, they act as nuclei for hydrate formation. In this work, a composite technology, based on the physical adsorption of CO2 by 5A zeolite and hydrate-based gas separation, was used to separate CO2/N2 gas mixtures. The influence of water content, temperature, pressure, and particle size on gas adsorption and CO2 separation was studied, revealing that the CO2 separation ability of zeolite particles sized 150–180 μm was better than that of those sized 380–830 μm at 271.2 K and 273.2 K. When the zeolite particles were 150–180 μm (type-B zeolite) with a water content of 35.3%, the gas consumption per mole of water (ngas/nH2O ) reached the maximum, 0.048, and the CO2 separation ratio reached 14.30%. The CO2 molar concentration in the remaining gas phase (xCO2gas) was lowest at 271.2 K in the type-B zeolite system with a water content of 47.62%. Raman analysis revealed that CO2 preferentially occupied the small hydrate cages and there was a competitive relationship between N2 and CO2.



2020 ◽  
Vol 59 (29) ◽  
pp. 12955-12963
Author(s):  
Qiang Ma ◽  
Lijuan Jia ◽  
Xueqian Wang ◽  
Ping Ning ◽  
Langlang Wang ◽  
...  


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