scholarly journals Фосфоресценция кислорода при возбуждении на длине волны 765 nm

2021 ◽  
Vol 129 (4) ◽  
pp. 467
Author(s):  
В.М. Киселев ◽  
И.В. Багров ◽  
А.С. Гренишин

Abstract — The phosphorescence of oxygen in the liquid phase and in a solution in carbon tetrachloride was studied upon excitation at a wavelength of 765 nm using an LED array as a source of direct optical excitation. A comparison is made of the observed efficiency of oxygen phosphorescence at a wavelength of 1270 nm upon its excitation at a wavelength of 765 nm with its excitation at other wavelengths, which partially or completely coincide with the absorption lines of molecular oxygen complexes. Key words: phosphorescence, singlet oxygen, molecular complexes, optical excitation, LED matrices.

2020 ◽  
Vol 128 (1) ◽  
pp. 58
Author(s):  
И.В. Багров ◽  
Н.Г. Гоголева ◽  
А.С. Гренишин ◽  
В.М. Киселев

The phosphorescence of liquid oxygen were studied upon its excitation at the cooperative transitions of O2-O2 molecular oxygen complexes with using for direct optical excitation of LED matrices with radiation in the near UV and visible spectral regions with wavelengths partially or completely coinciding with the absorption lines of molecular complexes


2020 ◽  
Author(s):  
busenur Aslanoglu ◽  
Ilya Yakavets ◽  
Vladimir Zorin ◽  
Henri-Pierre Lassalle ◽  
Francesca Ingrosso ◽  
...  

Computational tools have been used to study the photophysical and photochemical features of photosensitizers in photodynamic therapy (PDT) –a minimally invasive, less aggressive alternative for cancer treatment. PDT is mainly based by the activation of molecular oxygen through the action of a photoexcited sensitizer (photosensitizer). Temoporfin, widely known as mTHPC, is a second-generation photosensitizer, which produces the cytotoxic singlet oxygen when irradiated with visible light and hence destroys tumor cells. However, the bioavailability of the mostly hydrophobic photosensitizer, and hence its incorporation into the cells, is fundamental to achieve the desired effect on malignant tissues by PDT. In this study, we focus on the optical properties of the temoporfin chromophore in different environments –in <i>vacuo</i>, in solution, encapsulated in drug delivery agents, namely cyclodextrin, and interacting with a lipid bilayer.


Author(s):  
Gui Chen ◽  
Kuiyi You ◽  
Xiangbo Gong ◽  
Fangfang Zhao ◽  
Zhenpan Chen ◽  
...  

An efficient method for highly selective preparation of the high value-added benzyl alcohol (BOL) and benzaldehyde (BAL) from liquid-phase catalytic oxidation of toluene with molecular oxygen over CeO2-MnOx composite oxides...


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