scholarly journals Combustion Synthesis Ironmaking: Investigation on Required Carbon Amount in Raw Material from the Viewpoint of Adiabatic Flame Temperature Calculation

2019 ◽  
Vol 19 (3) ◽  
pp. 696 ◽  
Author(s):  
Keisuke Abe ◽  
Ade Kurniawan ◽  
Masafumi Sanada ◽  
Takahiro Nomura ◽  
Tomohiro Akiyama
Keyword(s):  
Combustion Synthesis ◽  
Iron Ore ◽  
Flame Temperature ◽  
Target Material ◽  
Molten Iron ◽  
Raw Material ◽  
Sample Temperature ◽  
Fast Method ◽  
Adiabatic Flame Temperature ◽  
Temperature Calculation

Combustion synthesis (CS) is a simple and very fast method to synthesize a target material. New ironmaking method via the CS using carbon-infiltrated iron ore was proposed, and the possible conditions for the method were investigated. Adiabatic flame temperatures (Tad) of the CS reaction, maximum reachable temperatures in an adiabatic system, were calculated to estimate the sample temperature during the CS. To reach the adiabatic temperature of 1811 K, 23.9, 27.9, and 29.3 wt.%-C were required for Fe2O3, Fe3O4, and FeO, respectively. When the carbon amount is higher than the calculated one, molten iron which is separated from slag components should be obtained via the CS.

scholarly journals Microwave-Assisted Combustion Synthesis of Nanocrystalline ZnO Powders Using Zinc Nitrate and Various Amount of Organic Fuels as Reactants: Influence of Reactant Parameters - A Status Review

Nano Hybrids ◽  
2014 ◽  
Vol 6 ◽  
pp. 75-110
Author(s):  
L.C. Nehru ◽  
C. Sanjeeviraja
Keyword(s):  
Combustion Synthesis ◽  
Flame Temperature ◽  
Synthesis Method ◽  
Zinc Nitrate ◽  
Adiabatic Flame Temperature ◽  
Molar Ratios ◽  
Microwave Assisted ◽  
Organic Fuels ◽  
Zno Powders ◽  
Xrd Techniques

Nanocrystalline ZnO powders have been synthesized by a novel and simple microwave-assisted combustion synthesis method using urea, glycine, carbohydrazine and citric acid as fuels and zinc nitrate as oxidant. The starting materials were directly mixed and a slurry precursor with high homogeneity was formed due to the hygroscopicity of the reactants. The precursor could be ignited at room temperature, resulting in dry, loose and voluminous ZnO powders. An interpretation based on an adiabatic flame temperature, amount of gases produced during reaction for various fuel-to-oxidizer molar ratios (ψ), has been proposed for the nature of combustion and its correlation with the characteristics of as-synthesized product. The variation of adiabatic flame temperature (Tad) with the ψ value was calculated theoretically according to the thermodynamic concept. The reaction process of the precursor was investigated by XRD techniques.

Study on the Effect of Adiabatic Flame Temperature on NOx Formation Using Ethanol Gasoline Blend in SI Engine

2013 ◽  
Vol 781-784 ◽  
pp. 2471-2475 ◽  
Author(s):  
B. M. Masum ◽  
M.A. Kalam ◽  
H.H. Masjuki ◽  
S. M. Palash
Keyword(s):  
Equivalence Ratio ◽  
Gasoline Engine ◽  
Flame Temperature ◽  
Inlet Temperature ◽  
Si Engine ◽  
Nox Formation ◽  
Adiabatic Flame Temperature ◽  
No Formation ◽  
Blended Fuel ◽  
Active Research

Active research and development on using ethanol fuel in gasoline engine had been done for few decades since ethanol served as a potential of infinite fuel supply. This paper discussed analytically and provides data on the effects of compression ratio, equivalence ratio, inlet temperature, inlet pressure and ethanol blend in cylinder adiabatic flame temperature (AFT) and nitrogen oxide (NO) formation of a gasoline engine. Olikara and Borman routines were used to calculate the equilibrium products of combustion for ethanol gasoline blended fuel. The equilibrium values of each species were used to predict AFT and the NO formation of combustion chamber. The result shows that both adiabatic flame temperature and NO formation are lower for ethanol-gasoline blend than gasoline fuel.

Adjustment of a technology of cast iron smelting in the blast furnace of jsc "ural steel" w ith a volume of 1232 см3 with charge h a v in g 95% share of Mikhailovskii GOK pellets

2021 ◽  
Vol 77 (7) ◽  
pp. 768-775
Author(s):  
I. F. Iskakov ◽  
G. A. Kunitsyn ◽  
D. V. Lazarev ◽  
А. А. Red`kin ◽  
S. A. Trubitsyn ◽  
...  
Keyword(s):  
Blast Furnace ◽  
Iron Ore ◽  
Raw Materials ◽  
Raw Material ◽  
Material Base ◽  
Hot Metal ◽  
Charging System ◽  
Iron Smelting ◽  
Gas Consumption ◽  
A Charge

To use effectively internal raw material base, JSC “Ural Steel” accomplished I category major overhaul of the blast furnace No. 2. The main purpose of the overhaul was to design a rational profile which could ensure an ability to operate with a charge containing 95 % of Mikhailovskii GOK (mining and concentrating plant) pellets having basicity of 0.5 by CaO/SiO2. The blast furnace No. 2 having useful volume of 1232 m3, was constructed by design of Danieli Corus, the Netherlands, and was blown in on December 30, 2020. In the process of guarantee tests, step-by-step increase of Mikhailovskii GOK pellets (Fetotal = 60.5 %, CaO/SiO2 = 0.5) content in the charge iron ore part was being accomplished from 55 to 95.1%. Charging of the blend containing pellets in the amount of 55% of iron ore part, was done by charging system 4OOCC + 1COOCC (Ore - Coke) with filling level 1.5 m. Under conditions of pellets part increase in the blend, the charging system was changed to decrease their content at the periphery, to increase it in the ore ridge zone and make it intermediate between periphery and the ore ridge. At the pellets share in the iron ore raw materials 0.75 the charging system was used as the following: 3OOCC + 1COOC + 1COOCC, while at the content 95.1% the following charging system was used: 2COOC + 2COOC + 1COOCC. It was noted that in the period of guarantee tests the furnace running was smooth. The average silicon content in the hot metal was 0.70% at the standard deviation 0.666. Sulfur content in the hot metal did not exceed 0.024%, the blowing and natural gas consumption figures were 2100 m3/min and 11000 m3/min correspondently, oxygen content in the blowing 26.5%, hot blowing and top smoke pressure figures were 226.5 and 109.8 KPa correspondently. The productivity of the furnace was reached as high as 2358 t/day at the specific coke rate 433 kg/t of hot metal. After guarantee tests completion, the pellets content in the iron ore part was decreased gradually from 95 down to 50%. The decreasing was made by 5% in every 6 hours of operation. Application of the mastered technology of the blast furnace No. 2 with the increased share of pellets will enable to stably supply the blast furnaces No. 1, 3 and 4 by iron ore raw materials in the proportion of 30-35% of pellets and 65-70% of sinter.

scholarly journals GLOBALIZATION AS A CHALLENGE TO UKRAINIAN EXPORTERS OF IRON ORE RAW MATERIAL

2018 ◽  
Vol 4 (1) ◽  
pp. 85-92
Author(s):  
Olha Hrybinenko ◽  
◽  
Svitlana Shahoian ◽  
Keyword(s):  
Iron Ore ◽  
Raw Material

Reduction Behavior and Mechanism of Iron Ore in Molten Iron in the Process of Converter Steelmaking

2019 ◽  
Vol 17 (8) ◽  
Author(s):  
Deng Nanyang ◽  
Zhou Di ◽  
Wei Rufei ◽  
Deng Aijun ◽  
Xia Yunjin ◽  
...  
Keyword(s):  
Iron Ore ◽  
Gas Diffusion ◽  
Reduction Reaction ◽  
Molten Iron ◽  
Reduction Behavior ◽  
Gaseous Products ◽  
Maximum Reaction ◽  
Reduction Effect ◽  
Solid Liquid ◽  
Reaction Activation Energy

Abstract XRD and SEM methods were applied to the reduction behavior and mechanism of iron ore in molten iron at temperatures of 1400 °C, 1450 °C, and 1500 °C. The results showed that iron ore could be reduced by carbon in molten iron. When the reduction of iron oxide occurred at the reaction interface, carbon in the molten iron was affected by the concentration gradient. This promoted reduction and the reduction effect improved with increase in reaction temperature. After the carbon in the molten iron almost disappeared, the surfaces of the iron ore and molten iron exhibited oxidizing atmospheres causing different degrees of oxidation of the reduced metal iron and molten iron at 1500 °C. Through analysis of the reduction mechanism of iron ore, it was known that the maximum reaction activation energy during gas phase diffusion was 1612.1 kJ/mol, which restricts the iron ore reduction reaction. At low temperatures, the diffusion of gaseous products in solid-liquid is difficult. Increasing the temperature and stirring accelerate the reduction reaction while increasing gas diffusion.

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