scholarly journals Ekstraksi Ion Merkuri MenggunakanTeknik Emulsi Membran Cair dengan Variasi Konsentrasi Benzoil Aseton dalam Fasa Membran dan Variasi pH Fasa Eksternal

2018 ◽  
Vol 6 (4) ◽  
pp. 232
Author(s):  
Sulniawati Sulniawati ◽  
Baharuddin Hamzah ◽  
Paulus Hengky Abram
Keyword(s):  
Liquid Membrane ◽  
Mercury Ion ◽  
Phase 2 ◽  
Mercury Ions ◽  
Membrane Phase ◽  
Emulsion Technique ◽  
Ion Extraction ◽  
External Phase ◽  
Percent Extraction

Mercury ion extraction using the liquid membrane emulsion technique with the variation of benzoil aseton concentration in membrane phase and variation of pH of external phase has been done. The sample containing Hg2+ ions with a concentration of 20 mg/L. Variation of benzoil aseton were concentration of 0.01 M, 0.015 M, 0.02 M and 0.025 M, whereas variation of external phase pH used were 1,5; 2; 2,5; 3 and 3,5. The measurement of extraction was conducted by using UV-Vis spectrophotometer. The results showed that the largest percent extraction on the extraction of mercury ions in solution by using liquid membrane emulsion was at a concentration of benzoil aseton 0.02 M with the percentage of extraction 79.33% and the pH external phase 2 with the percentage of extraction 85.30%.

scholarly journals Penentuan Kondisi Optimum (Konsentrasi HCl dan Konsentrasi Ion Merkuri) pada Ekstraksi Ion Hg2+ Menggunakan Teknik Emulsi Membran Cair

2018 ◽  
Vol 6 (3) ◽  
pp. 175 ◽  
Author(s):  
Tri Octivan Supriyatno ◽  
Baharuddin Hamzah ◽  
Irwan Said
Keyword(s):  
Liquid Membrane ◽  
Mercury Ion ◽  
Membrane Phase ◽  
Ion Extraction ◽  
Internal Phase ◽  
Membrane Technique ◽  
External Phase ◽  
Optimum Extraction ◽  
Percent Extraction ◽  
Hcl Solution

Study on the extraction of mercury ion had been done using emulsion liquid membrane technique. The aim of this study was to determine the optimum condition on mercury ion extraction in solutions those include variations in concentration of HCl solution (0.5 to 2.5) M and variation in concentration of mercury (15-35) ppm.This study was conducted using laboratory experimental method with benzoyl acetone as cation carrier, kerosene as membrane phase, HCl solution as an internal phase, Span-80 and Span-20 as surfactants, and mercury solution as the sample. Determination concentration of mercury ion in external phase was analysed using UV-Vis spectrophotometer. The result showed that the concentration of HCl solution resulted in the optimum percentage of extraction with the percent extraction of 95.31% was at 2 M. In addition, the concentration of mercury solution resulted in percent optimum extraction of 96.58% was at a concentration of 30 ppm.

scholarly journals Pengaruh Konsentrasi Surfaktan dan Perbandingan Volume Emulsi dengan Volume Fasa Eksternal Pada Ekstraksi Ion Merkuri Menggunakan Teknik Emulsi Membran Cair

2018 ◽  
Vol 6 (3) ◽  
pp. 165 ◽  
Author(s):  
Nurul Hidayah ◽  
Baharuddin Hamzah ◽  
Purnama Ningsih
Keyword(s):  
Surfactant Concentration ◽  
Liquid Membrane ◽  
Volume Ratio ◽  
Extraction Process ◽  
Mercury Ion ◽  
Optimal Conditions ◽  
Mercury Ions ◽  
Ion Extraction ◽  
Membrane Technique ◽  
External Phase

Mercury ion extraction has been done using emulsion liquid membrane technique a research. The aim of the study is to determine the optimal conditions at the extraction process of mercury ion with research variables, namely variations of the surfactant concentration and the volume ratio of emulsion and external phase (Ve:Veks). In this study, the sample was 20 mg/L of Hg2+ ions in concentration. The concentration of mercury ions remaining in the sample after extraction were analyze using a UV-Vis Spectrophotometer at a wavelength of 490 nm using ditizon as complexation. The optimum condition far varying concentrations surfactant was 2% and the volume ratio of emulsion (Ve) and external phase (Veks) was 1:5 with the percentage of extraction respectively 47.65% and 56.80%.

scholarly journals EFFECT OF MATRICES ON PERCENT EXTRACTION OF SILVER (II) FROM BLACK/WHITE PRINTING PHOTOGRAPHIC WASTE USING EMULSION LIQUID MEMBRANE TECHNIQUE

2010 ◽  
Vol 1 (3) ◽  
pp. 149-156
Author(s):  
Imam Santoso ◽  
Buchari Buchari
Keyword(s):  
Optimum Condition ◽  
Liquid Membrane ◽  
Ammonium Bromide ◽  
Phase Volume ◽  
Membrane Phase ◽  
Emulsion Liquid Membrane ◽  
Internal Phase ◽  
Membrane Technique ◽  
External Phase ◽  
Percent Extraction

Extraction of silver (I) has been studied from black/white printing photographic waste by emulsion liquid membrane technique. Composition emulsion at the membrane phase was cerosene as solvent, sorbitan monooleat (span 80) as surfactant, dimethyldioctadesyl-ammonium bromide as carrier and as internal phase was HNO3. Optimum condition was obtained: ratio of internal phase volume and membrane phase volume was 1:1 : concentration of surfactant was 2% (v/v) : time of making emulsion was 20 second : rate of stiring emulsion was 1100 rpm : rest time emulsion was 3 second : rate of emulsion volume and external phase volume was 1:5 : emulsion contact rate 500 rpm : emulsion contact time was 40 second : concentration of silver thiosulfate as external phase was 100 ppm : pH of external phase was 3 and pH of internal phase was 1. Optimum condition was applied in silver(I) extraction from black/white printing photographic waste. It was obtained 77.33% average which 56.06% silver (I) average of internal phase and 22.66% in the external phase. Effect of matrices ion decreased silver(I) percent extraction from 96,37% average to 77.33% average. Keyword: photographics waste, silver extraction

scholarly journals Emulsion Stability Tes and Effect of HNO3 Concentration in the Internal Phase on Cadmium Ion Extraction using Liquid Membrane Emulsion Technique

2020 ◽  
Vol 9 (1) ◽  
pp. 34-39
Author(s):  
Sahida Sahida ◽  
Baharuddin Hamzah ◽  
Siti Nuryanti
Keyword(s):  
Liquid Membrane ◽  
Emulsion Stability ◽  
Ion Concentration ◽  
Membrane Phase ◽  
Cadmium Ion ◽  
Hno3 Solution ◽  
Emulsion Technique ◽  
Extraction Percentage ◽  
Ion Extraction ◽  
Internal Phase

Study on the emulsion stability and cadmium ion extraction tests was performed using the liquid membrane emulsion technique. This study aimed to determine the emulsion stability between the membrane phase and the internal phase with the variation of the ratio (2:1, 1:1, 2:3, and 1:2), and to determine the maximum conditions of cadmium ion extraction in a solution including the various concentration of HNO3 solution 1, 1.5, 2, and 2.5 M. This study is a laboratory experimental method using benzoyl acetone compound as cation carrier, kerosene as membrane phase, HNO3 solution as the internal phase, span-20 and span-80 as surfactants, and cadmium solution as the sample solution. Cadmium ion concentration in the external phase was determined by UV-VIS spectrophotometer. The result showed that the emulsion stability test which produced the most stable emulsion was in the ratio of the membrane phase and the internal phase 1:1. In addition, the concentration of the HN03 solution resulted in a maximum extraction percentage of 1.5 M with an extraction percentage was 95.28%.

scholarly journals Effect of Copper(II) and Cadmium(II) Ions Against the Percent Mercury Ion Extraction Using Emulsion Liquid Membrane Technique

2019 ◽  
Vol 8 (4) ◽  
pp. 218-222
Author(s):  
Suhartini Musa ◽  
Baharuddin Hamzah ◽  
Daud K. Walanda
Keyword(s):  
Liquid Membrane ◽  
Mercury Ion ◽  
Sample Solution ◽  
Membrane Phase ◽  
Emulsion Liquid Membrane ◽  
Ion Extraction ◽  
Internal Phase ◽  
Membrane Technique ◽  
Span 80 ◽  
Effect Of Copper

The effect of copper(II) and cadmium(II) ions on the percent of mercury ion extraction using an emulsion liquid membrane technique have been performed. This study used HNO3 as an internal phase, mixed span 80 and span 20 as a surfactant, benzoyl acetone as cation carrier, kerosene as membrane phase, and mercury solution as a sample solution. Variations of concentrations of copper(II) and cadmium(II) ions added were 10, 20, and 30 ppm with mercury concentrations of 30 ppm. The result of the research showed that the addition of copper(II) ion with concentrations of 10 to 30 ppm decreased the percentage of mercury ion extraction 30 ppm by 12.12% and the addition of cadmium(II) ion with the concentration of 10 to 30 ppm decreased the percentage of mercury ion extraction 30 ppm by 11.74%.

scholarly journals Emulsion Liquid Membrane Design in Vitro for Removal of Lead from Aqueous Solution

2018 ◽  
Vol 34 (6) ◽  
pp. 2747-2754 ◽  
Author(s):  
Masoud Nasiri Zarandi ◽  
Amirhossein Soltani
Keyword(s):  
Sulfuric Acid ◽  
Liquid Membrane ◽  
Volume Ratio ◽  
Lead Extraction ◽  
Membrane Phase ◽  
Emulsion Liquid Membrane ◽  
Phase Contact Time ◽  
Internal Phase ◽  
External Phase

The purpose of this study was to investigate the extraction of lead by emulsion liquid membrane as an effective alternative to conventional lead extraction methods. The emulsion included D-2-ethylhexyl phosphoric acid (D2EHPA) as a carrier, paraffin and kerosene composition as an organic solvent, Span 80 as an emulsifier and sulfuric acid as an internal stripping phase. In this project, 7 effective factors in extraction of lead were chosen by emulsion liquid membrane, which included concentration of sulfuric acid in the internal phase, volume ratio of the emulsion to external phase (Rew), the ratio of organic phase to internal phase (Roi), initial pH of external phase, contact time of the emulsion and external phase, carrier concentration and concentration of surfactant in the membrane phase. After the initial experiments to make a stable emulsion, membrane phase mix (70% paraffin and 30% kerosene), homogenizer speed (12000 rpm) and mixer speed (309 rpm) were selected. The final experiments were designed by Taguchi statistical method. Optimization was done according to higher extraction rate and the effect of each of these factors and their optimal values as well as optimal conditions were determined. By verification test, it was shown that more than 92% of lead can be extracted from a solution with a concentration of 2000 ppm.

scholarly journals Pengaruh Ion Kadmium(II) dan Nikel(II) pada Ekstraksi Ion Tembaga(II) dengan Ekstraktan 4-Benzoil -1-Fenil-3-Metil- 2- Pirazolin-5-On Menggunakan Emulsi Membran Cair

2012 ◽  
Vol 13 (3) ◽  
pp. 269 ◽  
Author(s):  
Baharuddin Hamzah ◽  
Noor Jalaluddin ◽  
Abdul Wahid Wahab ◽  
Ambo Upe
Keyword(s):  
Optimum Condition ◽  
Liquid Membrane ◽  
Phase 1 ◽  
Volume Ratio ◽  
Mixed Surfactant ◽  
Membrane Phase ◽  
Internal Phase ◽  
External Phase ◽  
Percentage Extraction ◽  
Span 80

The effects of cadmium(II) and nickel(II) ions to copper(II) extraction using liquid membrane emulsion with 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-on (HPMBP) as an extractant was studied. The optimum condition forcopper(II) extraction were as follows: emulsification rate=2000 rpm, emulsification time=10 minutes, extractionrate=300 rpm, extraction time=15 minutes, concentration of mixed surfactant (span 80+span 20)=3%, volumeratio of membrane phase and internal phase=1:1, concentration of HPMBP=0.020 M, concentration of HCl=1M,volume ratio of emulsion and external phase=1:7. The result showed that the extraction of copper(II) by liquidmembrane emulsion with HPMBP as an extractant was selective to cadmium(II) and nickel(II) ions, relatively. Theresult also showed that in the extraction of 500 mg/l copper(II), the presence of 500 mg/l of nickel(II) was decreasingthe percentage of copper(II) extraction to be 83.73. While, the presence of 500 mg/l of cadmium(II) does notinfluence the percentage extraction of copper(II), relatively.

Application of Benzoyl-Acetone as a Cation Carrier in Mercury (II) Extraction by Using Liquid Membrane Emulsion Technique

2019 ◽  
Vol 811 ◽  
pp. 80-85
Author(s):  
Baharuddin Hamzah ◽  
Sitti Rahmawati ◽  
Ririen Hardani
Keyword(s):  
Liquid Membrane ◽  
Acidic Solution ◽  
Complexing Agent ◽  
Mixed Surfactant ◽  
Optimum Conditions ◽  
Membrane Phase ◽  
Internal Phase ◽  
External Phase ◽  
Phase Solution

Mercury (II) extraction from acidic solution with benzoyl-acetone as a cation carrier by liquid membrane emulsion (LME) technique was researched. The liquid membrane emulsion was made by mixing 15 mL the membrane phase solution (containing 2% mixed surfactant of span-80 & span-20, 0.020 M of Benzoyl-acetone in kerosene) and 15 mL the internal phase solution (containing nitric acid) with emulsification rate of 2000 rpm. The optimum condition for mercury (II) extraction were found as follows : extraction time with 300 rpm rate is 10 minutes, pH of the external phase is 2, concentration of HNO3 in the internal phase is 2 M. Determination of mercury (II) in the external phase after extraction was done by Viscible Spectrophotometer (490 nm) with dithizone as a complexing agent. By using these optimum conditions, 30 ml of LME can extract 30 ppm of mercury (II) within 150 ml of the external phase with extraction percentage of 96.8.

Removal of Phenol by a New Emulsion Liquid Membrane System and its Heat-Induced Demulsification

2011 ◽  
Vol 356-360 ◽  
pp. 1675-1678 ◽  
Author(s):  
Wei Peng ◽  
Chun Jian Xu
Keyword(s):  
Aqueous Solution ◽  
Liquid Membrane ◽  
Ph Value ◽  
Volume Ratio ◽  
Membrane System ◽  
Membrane Phase ◽  
Emulsion Liquid Membrane ◽  
Internal Phase ◽  
External Phase ◽  
Demulsification Efficiency

Removal of phenol from aqueous solution by a new emulsion liquid membrane (ELM) system and its heat-induced demulsification have been investigated. The ELM consists of commercial kerosene as organic solvent, OP-4 as surfactant agent, hydrochloric acid as the stripping phase. Effect of different operating parameters such as internal phase concentration, surfactant concentration, stirring speed, PH value in external phase, volume ratio of membrane phase to internal phase and volume ratio of membrane phase to external phase were investigated for the removal of phenol from aqueous solution. At the optimum condition about 95.7% phenol is removed in less than 20min of contact time. The demulsification efficiency was investigated under different temperature and time and proved to be high at 80°C.

scholarly journals Penentuan Perbandingan Volume Fasa Membran dan Volume Fasa Internal serta Lama Waktu Ekstraksi pada Proses Ekstraksi Ion Merkuri Menggunakan Teknik Emulsi Membran Cair

2018 ◽  
Vol 6 (3) ◽  
pp. 143
Author(s):  
Fulgensia Genefefa T. ◽  
Baharuddin Hamzah ◽  
Purnama Ningsih
Keyword(s):  
Optimum Condition ◽  
Volume Ratio ◽  
Extraction Process ◽  
Extraction Time ◽  
Phase Volume ◽  
Mercury Ions ◽  
Membrane Phase ◽  
Internal Phase ◽  
Chelating Compounds ◽  
Percent Extraction

This study aimed to determine the optimum condition on the extraction process of mercury ions with the variables of study on the ratio of membrane phase volume and internal phase volume (Mp:Ip) and the extraction time which will provide the greatest percent extraction. Sample used in this study was an artificial sample containing Hg(II) ions with a concentration of 10 mg/L. Hg(II) ions will be distributed into internal phase through membrane phase formed from a mixture of surfactants, kerosene and chelating compounds. Concentration of mercury ions remained in the samples was analyzed using a UV-VIS spectrophotometer at a wavelength of 490 nm with ditizon as a complex. The optimum condition was achieved at a volume ratio of membrane phase (Mp) with internal phase (Ip) of 2:2, and the extraction time was for 10 minutes, where percent extractions were 66.11% and 82.23%, respectively.

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