Application of Benzoyl-Acetone as a Cation Carrier in Mercury (II) Extraction by Using Liquid Membrane Emulsion Technique

2019 ◽  
Vol 811 ◽  
pp. 80-85
Author(s):  
Baharuddin Hamzah ◽  
Sitti Rahmawati ◽  
Ririen Hardani
Keyword(s):  
Liquid Membrane ◽  
Acidic Solution ◽  
Complexing Agent ◽  
Mixed Surfactant ◽  
Optimum Conditions ◽  
Membrane Phase ◽  
Internal Phase ◽  
External Phase ◽  
Phase Solution

Mercury (II) extraction from acidic solution with benzoyl-acetone as a cation carrier by liquid membrane emulsion (LME) technique was researched. The liquid membrane emulsion was made by mixing 15 mL the membrane phase solution (containing 2% mixed surfactant of span-80 & span-20, 0.020 M of Benzoyl-acetone in kerosene) and 15 mL the internal phase solution (containing nitric acid) with emulsification rate of 2000 rpm. The optimum condition for mercury (II) extraction were found as follows : extraction time with 300 rpm rate is 10 minutes, pH of the external phase is 2, concentration of HNO3 in the internal phase is 2 M. Determination of mercury (II) in the external phase after extraction was done by Viscible Spectrophotometer (490 nm) with dithizone as a complexing agent. By using these optimum conditions, 30 ml of LME can extract 30 ppm of mercury (II) within 150 ml of the external phase with extraction percentage of 96.8.

scholarly journals Pengaruh Ion Kadmium(II) dan Nikel(II) pada Ekstraksi Ion Tembaga(II) dengan Ekstraktan 4-Benzoil -1-Fenil-3-Metil- 2- Pirazolin-5-On Menggunakan Emulsi Membran Cair

2012 ◽  
Vol 13 (3) ◽  
pp. 269 ◽  
Author(s):  
Baharuddin Hamzah ◽  
Noor Jalaluddin ◽  
Abdul Wahid Wahab ◽  
Ambo Upe
Keyword(s):  
Optimum Condition ◽  
Liquid Membrane ◽  
Phase 1 ◽  
Volume Ratio ◽  
Mixed Surfactant ◽  
Membrane Phase ◽  
Internal Phase ◽  
External Phase ◽  
Percentage Extraction ◽  
Span 80

The effects of cadmium(II) and nickel(II) ions to copper(II) extraction using liquid membrane emulsion with 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-on (HPMBP) as an extractant was studied. The optimum condition forcopper(II) extraction were as follows: emulsification rate=2000 rpm, emulsification time=10 minutes, extractionrate=300 rpm, extraction time=15 minutes, concentration of mixed surfactant (span 80+span 20)=3%, volumeratio of membrane phase and internal phase=1:1, concentration of HPMBP=0.020 M, concentration of HCl=1M,volume ratio of emulsion and external phase=1:7. The result showed that the extraction of copper(II) by liquidmembrane emulsion with HPMBP as an extractant was selective to cadmium(II) and nickel(II) ions, relatively. Theresult also showed that in the extraction of 500 mg/l copper(II), the presence of 500 mg/l of nickel(II) was decreasingthe percentage of copper(II) extraction to be 83.73. While, the presence of 500 mg/l of cadmium(II) does notinfluence the percentage extraction of copper(II), relatively.

scholarly journals Emulsion Liquid Membrane Design in Vitro for Removal of Lead from Aqueous Solution

2018 ◽  
Vol 34 (6) ◽  
pp. 2747-2754 ◽  
Author(s):  
Masoud Nasiri Zarandi ◽  
Amirhossein Soltani
Keyword(s):  
Sulfuric Acid ◽  
Liquid Membrane ◽  
Volume Ratio ◽  
Lead Extraction ◽  
Membrane Phase ◽  
Emulsion Liquid Membrane ◽  
Phase Contact Time ◽  
Internal Phase ◽  
External Phase

The purpose of this study was to investigate the extraction of lead by emulsion liquid membrane as an effective alternative to conventional lead extraction methods. The emulsion included D-2-ethylhexyl phosphoric acid (D2EHPA) as a carrier, paraffin and kerosene composition as an organic solvent, Span 80 as an emulsifier and sulfuric acid as an internal stripping phase. In this project, 7 effective factors in extraction of lead were chosen by emulsion liquid membrane, which included concentration of sulfuric acid in the internal phase, volume ratio of the emulsion to external phase (Rew), the ratio of organic phase to internal phase (Roi), initial pH of external phase, contact time of the emulsion and external phase, carrier concentration and concentration of surfactant in the membrane phase. After the initial experiments to make a stable emulsion, membrane phase mix (70% paraffin and 30% kerosene), homogenizer speed (12000 rpm) and mixer speed (309 rpm) were selected. The final experiments were designed by Taguchi statistical method. Optimization was done according to higher extraction rate and the effect of each of these factors and their optimal values as well as optimal conditions were determined. By verification test, it was shown that more than 92% of lead can be extracted from a solution with a concentration of 2000 ppm.

scholarly journals EFFECT OF MATRICES ON PERCENT EXTRACTION OF SILVER (II) FROM BLACK/WHITE PRINTING PHOTOGRAPHIC WASTE USING EMULSION LIQUID MEMBRANE TECHNIQUE

2010 ◽  
Vol 1 (3) ◽  
pp. 149-156
Author(s):  
Imam Santoso ◽  
Buchari Buchari
Keyword(s):  
Optimum Condition ◽  
Liquid Membrane ◽  
Ammonium Bromide ◽  
Phase Volume ◽  
Membrane Phase ◽  
Emulsion Liquid Membrane ◽  
Internal Phase ◽  
Membrane Technique ◽  
External Phase ◽  
Percent Extraction

Extraction of silver (I) has been studied from black/white printing photographic waste by emulsion liquid membrane technique. Composition emulsion at the membrane phase was cerosene as solvent, sorbitan monooleat (span 80) as surfactant, dimethyldioctadesyl-ammonium bromide as carrier and as internal phase was HNO3. Optimum condition was obtained: ratio of internal phase volume and membrane phase volume was 1:1 : concentration of surfactant was 2% (v/v) : time of making emulsion was 20 second : rate of stiring emulsion was 1100 rpm : rest time emulsion was 3 second : rate of emulsion volume and external phase volume was 1:5 : emulsion contact rate 500 rpm : emulsion contact time was 40 second : concentration of silver thiosulfate as external phase was 100 ppm : pH of external phase was 3 and pH of internal phase was 1. Optimum condition was applied in silver(I) extraction from black/white printing photographic waste. It was obtained 77.33% average which 56.06% silver (I) average of internal phase and 22.66% in the external phase. Effect of matrices ion decreased silver(I) percent extraction from 96,37% average to 77.33% average. Keyword: photographics waste, silver extraction

scholarly journals Penentuan Kondisi Optimum (Konsentrasi HCl dan Konsentrasi Ion Merkuri) pada Ekstraksi Ion Hg2+ Menggunakan Teknik Emulsi Membran Cair

2018 ◽  
Vol 6 (3) ◽  
pp. 175 ◽  
Author(s):  
Tri Octivan Supriyatno ◽  
Baharuddin Hamzah ◽  
Irwan Said
Keyword(s):  
Liquid Membrane ◽  
Mercury Ion ◽  
Membrane Phase ◽  
Ion Extraction ◽  
Internal Phase ◽  
Membrane Technique ◽  
External Phase ◽  
Optimum Extraction ◽  
Percent Extraction ◽  
Hcl Solution

Study on the extraction of mercury ion had been done using emulsion liquid membrane technique. The aim of this study was to determine the optimum condition on mercury ion extraction in solutions those include variations in concentration of HCl solution (0.5 to 2.5) M and variation in concentration of mercury (15-35) ppm.This study was conducted using laboratory experimental method with benzoyl acetone as cation carrier, kerosene as membrane phase, HCl solution as an internal phase, Span-80 and Span-20 as surfactants, and mercury solution as the sample. Determination concentration of mercury ion in external phase was analysed using UV-Vis spectrophotometer. The result showed that the concentration of HCl solution resulted in the optimum percentage of extraction with the percent extraction of 95.31% was at 2 M. In addition, the concentration of mercury solution resulted in percent optimum extraction of 96.58% was at a concentration of 30 ppm.

Removal of Phenol by a New Emulsion Liquid Membrane System and its Heat-Induced Demulsification

2011 ◽  
Vol 356-360 ◽  
pp. 1675-1678 ◽  
Author(s):  
Wei Peng ◽  
Chun Jian Xu
Keyword(s):  
Aqueous Solution ◽  
Liquid Membrane ◽  
Ph Value ◽  
Volume Ratio ◽  
Membrane System ◽  
Membrane Phase ◽  
Emulsion Liquid Membrane ◽  
Internal Phase ◽  
External Phase ◽  
Demulsification Efficiency

Removal of phenol from aqueous solution by a new emulsion liquid membrane (ELM) system and its heat-induced demulsification have been investigated. The ELM consists of commercial kerosene as organic solvent, OP-4 as surfactant agent, hydrochloric acid as the stripping phase. Effect of different operating parameters such as internal phase concentration, surfactant concentration, stirring speed, PH value in external phase, volume ratio of membrane phase to internal phase and volume ratio of membrane phase to external phase were investigated for the removal of phenol from aqueous solution. At the optimum condition about 95.7% phenol is removed in less than 20min of contact time. The demulsification efficiency was investigated under different temperature and time and proved to be high at 80°C.

CADMIUM REMOVAL USING VEGETABLE OIL BASED EMULSION LIQUID MEMBRANE (ELM): MEMBRANE BREAKAGE INVESTIGATION

2015 ◽  
Vol 75 (1) ◽  
Author(s):  
A. L. Ahmad ◽  
M. M. H. Shah Buddin ◽  
B. S. Ooi ◽  
Adhi Kusumastuti
Keyword(s):  
Vegetable Oil ◽  
Liquid Membrane ◽  
Corn Oil ◽  
Volume Ratio ◽  
Aliquat 336 ◽  
Emulsion Liquid Membrane ◽  
Cadmium Removal ◽  
Internal Phase ◽  
External Phase ◽  
Span 80

The aim of this research is to quantify the occurrence of membrane breakage in vegetable oil based Emulsion Liquid Membrane (ELM). Basically, ELM consists of three main phases; internal, external and membrane. In this work, the membrane phase was prepared by dissolving Span 80 as surfactant and Aliquat 336 as carrier in commercial grade corn oil. As a way to promote sustainable development, vegetable oil which is environmentally benign diluent was incorporated in the formulation of ELM. The influence of several important parameters towards membrane breakage were studied. They are carrier and surfactant concentration, W/O volume ratio, emulsification time, internal phase concentration as well as stirring speed. Based on the data obtained, emulsion prepared using 4 wt% Aliquat 336 and 3 wt% Span 80 resulted in the most stable emulsion with only 0.05% membrane breakage. The emulsion was produced using W/O volume ratio of 1/3 and it was homogenized with the assistance of ultrasound for 15 min. Moreover, emulsion produced able to provide a fair balance between emulsion stability and Cd(II) permeability as it able to remove 98.20% Cd(II) ions from the external phase. 

scholarly journals PENAMBAHAN ASAM OLEAT TERHADAP Sistem transpor Cu(II) dengan zat pembawa oksin melalui teknik membran cair fasa ruah

2015 ◽  
Vol 2 (1) ◽  
pp. 45
Author(s):  
Olly Norita Tetra ◽  
Zaharasmi ◽  
Refinel
Keyword(s):  
Aqueous Solutions ◽  
Liquid Membrane ◽  
Bulk Liquid ◽  
Optimum Conditions ◽  
Membrane Phase ◽  
Bulk Liquid Membrane ◽  
Phase 0 ◽  
Interface System ◽  
Source Phase ◽  
Feed Phase

 ABSTRACT The removal of Cu(II) from aqueous solutions had been employed throught bulk liquid membrane techniques with arrange the optimization conditions of transport Cu(II) interface system. The optimum conditions of transport were found to be 3.1510-4 M of Cu(II) at pH 3  in the source phase,  17.510-4 M oxine dissolved into chloroform as membrane phase, 0,15 M H2SO4 as acceptor in  receiving phase, stirring rate was 340 rpm and  it was found that the transport of Cu(II) to receiving phase reached 97.41% during 6 hours. The effect of addition  oleat acid 1.57  10-3 M as surfactant  in membrane phase resulted a rapidly time of  transport Cu(II) to be 3 hours, wherein Cu(II) transported  into  the receive phase reached 97.83%  and remained  in feed phase 0%. Keywords: bulk liquid membrane, oxine, oleat acid, Cu(II) )transport

A two-step approach for copper and nickel extracting and recovering by emulsion liquid membrane

2016 ◽  
Vol 74 (10) ◽  
pp. 2454-2461
Author(s):  
Qiang Bi ◽  
Juanqin Xue ◽  
Yingjuan Guo ◽  
Guoping Li ◽  
Haibin Cui
Keyword(s):  
Liquid Membrane ◽  
Volume Fraction ◽  
Process Variable ◽  
Phase Volume ◽  
Optimum Conditions ◽  
Application Technology ◽  
Emulsion Liquid Membrane ◽  
Phase Volume Fraction ◽  
Internal Phase ◽  
Valuable Metals

The recycling of copper and nickel from metallurgical wastewater using emulsion liquid membrane (ELM) was studied. P507 (2-ethylhexyl phosphonic acid-2-ethylhexyl ester) and TBP (tributyl phosphate) were used as carriers for the extraction of copper and nickel by ELMs, respectively. The influence of four emulsion composition variables, namely, the internal phase volume fraction (ϕ), surfactant concentration (Wsurf), internal phase stripping acid concentration (Cio) and the carrier concentration (Cc), and the process variable treat ratio on the extraction efficiencies of copper or nickel were studied. Under the optimum conditions, 98% copper and nickel were recycled by using ELM. The results indicated that ELM extraction is a promising industrial application technology to retrieve valuable metals in low concentration metallurgical wastewater.

scholarly journals Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion

2010 ◽  
Vol 7 (1) ◽  
pp. 239-245 ◽  
Author(s):  
Baharuddin Hamzah ◽  
Noor Jalaluddin ◽  
Abdul Wahid Wahab ◽  
Ambo Upe
Keyword(s):  
Nitric Acid ◽  
Acid Solution ◽  
Nitric Acid Solution ◽  
Liquid Membrane ◽  
Volume Ratio ◽  
Yellow Crystal ◽  
H Nmr ◽  
Internal Phase ◽  
External Phase ◽  
Synthesis Yield

Copper(II) extraction from nitric acid solution with 1-phenyl-3-methyl-4-benzoil-5-pyrazolone (HPMBP) as a cation carrier by liquid membrane emulsion (LME) was investigated. The HPMBP initially was synthesized and the synthesis yield is a yellow crystal with melting point of 87-89°C. The synthesis efficiency is 72.04% and generally the spectra of IR,1H NMR and13C NMR agree with HPMBP structure. The optimum condition for copper(II) extraction were found as follows: concentration of mixed surfactant (span 80+span 20) was 3%, volume ratio of membrane and internal phase was 1, concentration of HPMBP was 0.020 M, concentration of HCl was 1 M, volume ratio of emulsion and external phase was 0.143. By using these optimum conditions, 30 mL of LME can extract 1000 ppm of copper(II) within 210 mL of nitric acid solution with extraction percentage of 97.97%.

Carrier Assisted Emulsion Liquid Membrane Process for Recovery of Basic Dye from Wastewater using Continuous Extractor

2014 ◽  
Vol 67 (2) ◽  
Author(s):  
Norasikin Othman ◽  
Ooi Zing-Yi ◽  
Norlisa Harruddin ◽  
Raja Norimie ◽  
Norela Jusoh ◽  
...  
Keyword(s):  
Textile Industry ◽  
Liquid Membrane ◽  
Volume Ratio ◽  
Extraction Process ◽  
Membrane Phase ◽  
Emulsion Liquid Membrane ◽  
Sorbitan Monooleate ◽  
Internal Phase ◽  
Span 80 ◽  
Dye Extraction

Nowadays, water pollution has become major issue especially dye contaminated wastewaters from the textile industry. Dye causes serious environmental pollution and health problems. The removal of color from dye-contaminated wastewaters in the related industries becomes a major concern all over the world. In this research, several parameters of dye extraction and recovery in the continuous emulsion liquid membrane (ELM) process were investigated. This process consisted of three phases which are external (feed) phase, membrane phase and internal phase. The membrane phase was prepared by dissolving extractant bis(2-ethylhexyl)phosphoric acid (D2EHPA) and hydrophobic surfactant sorbitan monooleate (Span 80) in kerosene as diluents. The internal phase consisted of an aqueous solution of sulfuric acid (H2SO4). The important parameters governing the extraction process of dye such as stirring speed, initial dye concentration, Span 80 concentration and treat ratio (volume ratio of emulsion to external phase) were studied. The results showed that the optimum condition for 25ppm initial concentration of dye extraction are 250 rpm stirring speed, 5% (w/v) Span 80 and treat ratio 1:5. At this condition, the percentage of dye extraction, stripping and recovery were 98%, 82% and 81% respectively. Hence, continuous ELM technique is proven to be a very promising technique in industrial wastewater treatment and recovery of dye.

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