<p><span>It has been long understood that green infrastructure helps to mitigate urban heat island formation and therefore should be a key strategy in future urban planning practices. Due to its high level of heat resilience, the sycamore tree (Platanus) dominates the appearance of urban landscapes in central Europe. Under extreme climate conditions however, these species tend to emit high levels of biogenic volatile organic compounds (BVOCs) which in turn can act as precursors for tropospheric ozone, especially in highly NOx polluted environments such as urban areas. </span></p><p><span>Assessing the ozone air quality of a large urban area in Germany we use the state-of-the art regional chemical transport model MECO(n), with chemistry coming from the Modular Earth Submodel System (MESSy) and meteorology being calculated by COSMO. Including the latest version of TERRA_URB, the model is configured for the Rhine-Main urban area. In a second step, we implement parts of the regional atmospheric chemistry mechanism in the ENVI-met model framework in order to investigate the impact of isoprene emissions on ozone concentration at street level for the urban area of Mainz, Germany. </span></p><p><span>Whereas mesoscale model results only show moderate mean ozone pollution over the model area, at micro-scale level on selected hot spots we find a clear relationship between urban layout, proximity to NOx emitters, tree-species-dependent isoprene emission capacity and increase in ozone concentration. The ENVI-met study reveals, that next to tree species, its location is a key factor for its micro-climatic UHI and air pollution mitigation potential. We could show, that isoprene related ozone concentration is highly sensitive to leaf temperature, photosynthetic active radiation as well as to the proximity to NO2 pollution sources. In a street canyon with high traffic load we find significant correlations between diurnal boundary layer dynamics, morning and evening rush hour and ambient ozone levels. For a hot summer day in particular, we simulate ozone concentrations rising up to 500% within a weakly ventilated street canyon with a high amount of strong isoprene emitters being present.</span></p><p><span>We summarize that combining findings from meso- and microscale model systems can be an important asset for science tools for cities in the framework of climate change adaption and mitigation </span><span>and air pollution abatement</span><span> strategies.</span></p>
Measurements and modeling pollution from traffic in a street canyon: Assessing and ranking the influences
