Effect of Methacryloyloxydecyl Dihydrogen Phosphate–Containing Silane and Adhesive Used Alone or in Combination on the Bond Strength and Chemical Interaction With Zirconia Ceramics Under Thermal Aging

2020 ◽  
Vol 45 (5) ◽  
pp. 516-527 ◽  
Author(s):  
MF Gutierrez ◽  
J Perdigão ◽  
P Malaquias ◽  
AM Cardenas ◽  
F Siqueira ◽  
...  
Keyword(s):  
Bond Strength ◽  
Computer Aided Design ◽  
Chemical Interaction ◽  
Interaction Analysis ◽  
Resin Cement ◽  
Dihydrogen Phosphate ◽  
Universal Adhesive ◽  
Adhesive Application ◽  
Aided Design ◽  
Silane Solution

Clinical Relevance Achieving durable bonding to zirconia is fundamental for the application of a methacryloyloxydecyl dihydrogen phosphate (MDP)–containing silane solution or an MDP-containing silane solution associated with an MDP-containing universal adhesive. SUMMARY Objectives: To evaluate the effect of a methacryloyloxydecyl dihydrogen phosphate (MDP)–containing silane coupling agent and universal adhesive, used alone or in combination, on the microshear bond strength (μSBS) to zirconia after 24 hours of water storage (24h) and after 10,000 thermocycles (TC), complemented with chemical analysis of the surface to establish the presence of MDP on the surface of the zirconia after bonding procedures. Methods and Materials: Thirty computer-aided design/computed-aided manufacturing blocks of zirconia were cut into four sections (6×6×6 mm) and sintered. Zirconia sections (n=96) were assigned to 24 groups according to three factors: 1) silane (no silane, Monobond S [MBS], Monobond P [MB+]), 2) adhesive + resin cement (no adhesive + Enforce [ENF], no adhesive + RelyX Ultimate [REX], Prime&Bond Elect + Enforce [PBE/ENF], Scotchbond Universal + RelyX Ultimate [SBU/REX]), and 3) thermocycling (no thermocycling [24h], 10,000 thermocycles [TC]). Upon silane/adhesive application, cylinder-shaped matrices were filled with resin cement and light cured. Specimens were tested in μSBS (1.0 mm/min) after 24h or TC. The μSBS data were analyzed using twoway ANOVA and Tukey’s post hoc test (α=0.05). In addition, micro-Raman spectroscopy was used to analyze the zirconia surface for immediate chemical interaction analysis (n=24). Results: For the 24h condition, PBE/ENF resulted in lower mean μSBS than both groups with silane without PBE (MBS and MB+ groups; p<0.001). SBU alone or MB+ alone and MB+ associated with SBU showed the highest mean μSBS (p<0.001). For the TC condition, all groups showed a significant decrease in mean μSBS compared with those of 24h (p<0.001), with the exception of MB+ associated to SBU (p>0.05). However, the application of MB+ alone or MB+ associated to SBU resulted in higher mean μSBS (p<0.001) after TC than the remaining TC groups. In terms of chemical interaction, only the SBU groups, alone or combined with both of the silane agents, were associated with the methacrylate groups after rinsing. Conclusions: The results of the current study support the use of an MDP-containing silane solution or an MDP-containing silane solution associated with an MDP-containing universal adhesive for bonding to air-abraded zirconia, as a more stable bonding after thermocycling.

scholarly journals Anterosuperior rehabilitation with metal-free fixed prosthesis based on zirconia

2017 ◽  
Vol 11 (02) ◽  
pp. 253-257 ◽  
Author(s):  
Sthelen Nayara Cenci ◽  
Igor Alessandro Gontarsky ◽  
Marcella Goetz Moro ◽  
Lidia Olga Bach Pinheiro ◽  
Adriana Postiglione Bührer Samra
Keyword(s):  
Computer Aided Design ◽  
Internal Surface ◽  
Psychosocial Problems ◽  
Adhesive System ◽  
Resin Cement ◽  
Ceramic Technology ◽  
Tissue Loss ◽  
Dihydrogen Phosphate ◽  
Universal Adhesive ◽  
Computer Aided

ABSTRACTThe loss of upper front dental elements causes functional and psychosocial problems to the affected individuals. In this case report, the treatment planning considered hard and soft tissue loss for a complex fixed partial denture (FPD) rehabilitation. The six-element, all-ceramic FPD was manufactured using a computer-aided design/computer-aided manufacturing system with zirconia framework, veneered with leucite-reinforced ceramic. Ceramic artificial gum was also produced to guarantee tooth-facial proportions as well as lip support, promoting both esthetics and phonetics. The material's mechanical properties allowed for the coupling of the esthetic and mechanical requirements, proving an alternative to the well-established metal-ceramic technology, optimizing biomimetic. One of the endodontic-treated abutment teeth required a radicular retainer with cast metal post, but because of the opacity of zirconia, the esthetics of the prosthesis was not compromised. The low silica content of high resistance ceramics such as zirconia hampers the adhesive cementation, with numerous studies advocating for different cementation protocols, with no clear scientific consensus so far. In the present case, the internal surface of the FPD was initially blasted with aluminum oxide, followed by the application of a universal adhesive system containing 10-methacryloyloxydecyl dihydrogen phosphate. Finally, cementation to the dental structure was conducted with dual-cure self-adhesive resin cement.

scholarly journals Effect of hydrogen peroxide and universal adhesive application on the bond strength of glass fiber posts

2017 ◽  
Vol 16 ◽  
pp. 1-9
Author(s):  
Fernando Dalitz ◽  
Orides Ferrari de Oliveira Junior ◽  
Raisa Carolina Hintz ◽  
Gisele Maria Correr ◽  
Leonardo Fernandes da Cunha ◽  
...  
Keyword(s):  
Bond Strength ◽  
Surface Treatment ◽  
Glass Fiber ◽  
Resin Cement ◽  
Universal Adhesive ◽  
Pull Out ◽  
Fiber Posts ◽  
Glass Fiber Posts ◽  
Simplified Procedure ◽  
Adhesive Application

Aim: This study aims to evaluate the effect of different surface treatments on the bond strength of glass fiber posts. Methods: Ninety unirradicular premolars had their crowns removed and were endodontically treated. After 24h, post spaces were prepared and the roots (n=15) were divided into six groups according to the post surface treatment: NT – no treatment, UA – universal adhesive (Single Bond Universal), SUA – silane (Prosil), followed by universal adhesive, H – H2O2 (Whitness HP Maxx, 35%, gel, 1 min), HUA – H2O2, followed by universal adhesive, and HSUA – H2O2, followed by silane and universal adhesive. The posts were cemented with dual-cured resin cement (RelyX Ultimate). Bond strength was evaluated with pull-out test (0.5 mm/mim) after 24h-storage in distilled water at 37oC. Data were submitted to ANOVA and Tukey's test (α=5%). Results: HSUA group showed the highest bond strength value (236.5 N) followed by HUA (206.5 N), NT (194 N) and SUA (184 N) groups. UA group showed the lowest bond strength value (60 N). Conclusion: The use of H2O2, the silane application or the combination of these two treatments significantly increased bond strength values in groups in which the universal adhesive was used. A simplified procedure, such as cleaning with alcohol, can be recommended as surface treatment for the cementation of glass fiber posts.

scholarly journals Effect of Two Immediate Dentin Sealing Approaches on Bond Strength of Lava™ CAD/CAM Indirect Restoration

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1629
Author(s):  
Hassan Faez Abdullah Gailani ◽  
Cristina Benavides-Reyes ◽  
María Victoria Bolaños-Carmona ◽  
Eva Rosel-Gallardo ◽  
Purificación González-Villafranca ◽  
...  
Keyword(s):  
Survival Analysis ◽  
Bond Strength ◽  
Computer Aided Design ◽  
Resin Cement ◽  
Competing Risk ◽  
Adhesive Resin ◽  
Computer Aided ◽  
Cad Cam ◽  
Aided Design ◽  
Type Of Failure

The objective of this work was to compare the micro-tensile bond strength (µTBS) of CAD/CAM (Computer-Aided Design/ Computer-Aided Manufacturing) specimens cemented with different pairing of adhesives and resin-cements using two Immediate Dentin Dealing (IDS) approaches in comparison with Delay Dentin Sealing (DDS). Coronal dentin from 108 molars were divided into nine groups (n = 12) depending on the adhesive/resin-cement (A-C) assigned. Lava™ Ultimate (4 × 10 × 10 mm) was cemented according to different strategies: IDS1(cementation after dentin sealing), DDS (dentin sealing and cementation at 2-weeks), IDS2 (immediate dentin sealing and cementation at 2-weeks). Samples were sectioned and tested until failure to determine the µTBS. Failure mode was categorized as dentin/cement (DC), at Lava™ Ultimate/cement (LC) and hybrid (H). Kruskal–Wallis and Mann–Whitney U tests and influence of the type of failure on the µTBS by survival analysis with competing risk was explored. Mostly, µTBS values were equal or higher in IDS2 than DDS. In general, A-Cs that showed higher µTBS, have high percentages of LC failure. Survival analysis with competing risk between DC + H and LC values showed that some A-Cs would significantly increase the µTBS values for IDS2. A-Cs with the highest adhesion values showed a high percentage of fractures at the LC interface, suggesting that the adhesion at the adhesive/dentin interface would be higher.

Chemical Interaction Analysis of an Adhesive Containing 10-Methacryloyloxydecyl Dihydrogen Phosphate (10-MDP) With the Dentin in Noncarious Cervical Lesions

2017 ◽  
Vol 42 (4) ◽  
pp. 357-366 ◽  
Author(s):  
BMB Oliveira ◽  
ALM Ulbaldini ◽  
F Sato ◽  
ML Baesso ◽  
AC Bento ◽  
...  
Keyword(s):  
Chemical Bonding ◽  
Chemical Interaction ◽  
Interaction Analysis ◽  
Dihydrogen Phosphate ◽  
Cervical Lesions ◽  
Human Teeth ◽  
Before And After ◽  
Infrared Photoacoustic Spectroscopy ◽  
Adhesive Application ◽  
Self Etch

SUMMARY The purpose of this study was to evaluate the chemical bonds of a self-etch 10-methacryloyloxydecyl dihydrogen phosphate (10-MDP) adhesive to natural noncarious cervical lesions (NCCLs) and compare them with those occurring in sclerotic dentin in artificially prepared defects (APDs). Four human teeth with natural NCCLs on the buccal surface were selected. Artificial defects matching the natural lesions were prepared on the lingual surface of the same teeth serving as control. Micro-Raman (MR) spectroscopy was used to quantify mineral content in natural NCCLs and in APDs. Fourier transform infrared-photoacoustic spectroscopy (FTIR-PAS) readouts were taken before and after adhesive application to analyze the protein matrix/mineral (M:M) ratio and chemical interactions between 10-MDP adhesive and dentin. The MR and FTIR-PAS spectra collected from natural NCCLs demonstrated a larger area of the band (961 cm−1, PO4) and lower M:M ratio, respectively, characterizing a hypermineralized dentin, compared with APDs. FTIR-PAS demonstrated emergence of a peak (1179 cm−1, P=O) in spectra after adhesive treatment, demonstrating a more intense chemical interaction in natural NCCLs. The results demonstrated that chemical bonding of 10-MDP adhesive to natural NCCLs is more intense, due to the hypermineralized surface, and suggest that it is unnecessary to remove the hypermineralized layer with burs, as this may decrease the chemical bonding potential of 10-MDP.

scholarly journals Effects of Universal Adhesive on Shear Bond Strength of Resin Cement to Zirconia Ceramic with Different Surface Treatments

2021 ◽  
Vol 2021 ◽  
pp. 1-6
Author(s):  
Zohreh Moradi ◽  
Farnoosh Akbari ◽  
Sara Valizadeh
Keyword(s):  
Bond Strength ◽  
Shear Bond Strength ◽  
Testing Machine ◽  
In Vitro Study ◽  
Surface Treatments ◽  
Resin Cement ◽  
Zirconia Ceramic ◽  
Single Bond ◽  
Universal Adhesive

Aim. This study aimed to assess shear bond strength (SBS) of resin cement to zirconia ceramic with different surface treatments by using Single Bond Universal. Methods. In this in vitro study, 50 zirconia discs (2 × 6 mm) were divided into 5 groups of (I) sandblasting with silica-coated alumina (CoJet)  + silane + Single Bond 2, (II) sandblasting with CoJet + Single Bond Universal, (III) sandblasting with alumina + Single Bond Universal, (IV) sandblasting with alumina + Z-Prime Plus, and (V) Single Bond Universal with no surface treatment. Resin cement was applied in plastic tubes (3 × 5 mm2), and after 10,000 thermal cycles, the SBS was measured by a universal testing machine. The mode of failure was determined under a stereomicroscope at × 40 magnification. Data were analyzed using one-way ANOVA. Results. The maximum (6.56 ± 4.29 MPa) and minimum (1.94 ± 1.96 MPa) SBS values were noted in groups III and I, respectively. Group III had the highest frequency of mixed failure (60%). Group V had the maximum frequency of adhesive failure (100%). Conclusion. Single Bond Universal + sandblasting with alumina or silica-coated alumina particles is an acceptable method to provide a strong SBS between resin cement and zirconia.

Lack of Neutralization of 10-MDP Primers by Zirconia May Affect the Degree of Conversion of Dual-cure Resin Cement

2021 ◽  
Vol 46 (1) ◽  
pp. 107-115
Author(s):  
DM De Paula ◽  
AD Loguercio ◽  
A Reis ◽  
S Sauro ◽  
AH Alves ◽  
...  
Keyword(s):  
Bond Strength ◽  
Testing Machine ◽  
Monomer Concentration ◽  
Positive Control ◽  
Degree Of Conversion ◽  
Resin Cement ◽  
Dihydrogen Phosphate ◽  
Resin Cements ◽  
Low Concentrations ◽  
Microshear Bond Strength

Clinical Relevance Use of zirconia primers with a low pH and a high acidic monomer concentration should be employed in combination with dual-cure resin cements that are less sensitive to an acidic environment. Primers with lower 10-MDP concentrations attain better outcomes. SUMMARY Objective: To assess the effects of different concentrations of 10-methacryloyloxydecyl dihydrogen phosphate (10-MDP) included in experimental ceramic primers on the degree of conversion (DC) and microshear bond strength (μSBS) of a dual-cure resin cement, and on the acidity neutralization potential of zirconia (ZrO2) in comparison to hydroxyapatite (HAp). Methods: Experimental ceramic primers were formulated using 5 wt%, 10 wt%, 20 wt%, or 40 wt% 10-MDP as an acidic functional monomer and camphorquinone (CQ)/amine or 1-phenyl-1,2-propanedione (PPD) as a photoinitiator system. Clearfil Ceramic Primer (Kuraray Dental, Tokyo, Japan) was used as the commercial control. Micro-Raman spectroscopy was used to assess the DC of uncured and light-cured resin cements applied onto primer-treated ZrO2 surfaces. The μSBS and pH of primers were assayed in a universal testing machine and by a digital pH meter (Tec-3MP; Tecnal, Piracicaba, Brazil), respectively. Statistical analysis was performed by one-way analysis of variance (ANOVA) and Tukey’s test (p<0.05). Results: DC was not affected until a concentration of 10% 10-MDP in CQ primer and 5% 10-MDP in PPD primer was reached, when compared with the positive control (p>0.05). Groups 10-MDP 5% in CQ and PPD primers showed the highest μSBS compared with the positive control (p>0.05); however, higher concentrations of 10-MDP induced significant DC and μSBS reduction (p<0.05). HAp neutralized 10-MDP primers, but ZrO2 provided higher acidity to the primers’ pH. Conclusion: 10-MDP monomer should be used in low concentrations in ZrO2 primers to avoid reduction of the polymerization and bond strength of resin cement.

scholarly journals Effect of Over-Etching and Prolonged Application Time of a Universal Adhesive on Dentin Bond Strength

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2902
Author(s):  
Phoebe Burrer ◽  
Hoang Dang ◽  
Matej Par ◽  
Thomas Attin ◽  
Tobias T. Tauböck
Keyword(s):  
Phosphoric Acid ◽  
Bond Strength ◽  
Linear Regression Analysis ◽  
Acid Etching ◽  
Control Group ◽  
Application Time ◽  
Universal Adhesive ◽  
Adhesive Application ◽  
Post Hoc ◽  
Phosphoric Acid Etching

This study investigated the effect of over-etching and prolonged application time of a universal adhesive on dentin bond strength. Ninety extracted human molars were ground to dentin and randomly allocated into nine groups (G1–9; n = 10 per group), according to the following acid etching and adhesive application times. In the control group (G1), phosphoric acid etching was performed for 15 s followed by application of the universal adhesive Scotchbond Universal (3M) for 20 s, as per manufacturer’s instructions. In groups G2–5, both the etching and adhesive application times were either halved, doubled, quadrupled, or increased eightfold. In groups G6–9, etching times remained the same as in G2–5 (7.5 s, 30 s, 60 s, and 120 s, respectively), but the adhesive application time was set at 20 s as in the control group (G1). Specimens were then restored with a nanofilled composite material and subjected to microtensile bond strength testing. Bond strength data were statistically analyzed by ANOVA and Tukey’s post-hoc tests (α = 0.05). The relationship of bond strength with etching and adhesive application time was examined using linear regression analysis. Treatment of dentin with halved phosphoric acid etching and adhesive application times (G2) resulted in a significant bond strength decrease compared to the control group (G1) and all other test groups, including the group with halved acid etching, but 20 s of adhesive application time (G6). No significant differences in bond strength were found for groups with multiplied etching times and an adhesive application time of 20 s or more, when compared to the control group (G1). In conclusion, a universal adhesive application time of at least 20 s is recommended when bonding to over-etched dentin.

Premolar Axial Wall Height Effect on CAD/CAM Crown Retention

2016 ◽  
Vol 41 (6) ◽  
pp. 666-671 ◽  
Author(s):  
C Gillette ◽  
R Buck ◽  
N DuVall ◽  
S Cushen ◽  
M Wajdowicz ◽  
...  
Keyword(s):  
Computer Aided Design ◽  
Lithium Disilicate ◽  
Resin Cement ◽  
Failure Resistance ◽  
All Ceramic ◽  
Computer Aided ◽  
Cad Cam ◽  
Ceramic Crowns ◽  
Aided Design ◽  
Post Hoc

SUMMARY Objective: To evaluate the significance of reduced axial wall height on retention of adhesively luted, all-ceramic, lithium disilicate premolar computer-aided design/computer-aided manufacturing (CAD/CAM) crowns based on preparations with a near ideal total occlusal convergence of 10°. Methods: Forty-eight recently extracted premolars were randomly divided into four groups (n=12). Each group received all-ceramic CAD/CAM crown preparations featuring axial wall heights of 0, 1, 2, and 3 mm, respectively, all with a 10° total occlusal convergence. Scanned preparations were fitted with lithium disilicate all-ceramic crowns that were luted with a self-etching resin cement. Specimens were tested to failure at a 45° angle to the tooth long axis with failure load converted to megapascals (MPa) based on the measured bonding surface area. Mean data were analyzed using analysis of variance/Tukey's post hoc test (α=0.05). Results: Lithium disilicate crowns adhesively luted on preparations with 0 axial wall height demonstrated significantly less failure resistance compared with the crowns luted on preparations with axial wall heights of 1 to 3 mm. There was no failure stress difference between preparations with 1 to 3 mm axial wall height. Conclusions: Under conditions of this study, adhesively luted lithium disilicate bicuspid crowns with a total occlusal convergence of 10° demonstrated similar failure resistance independent of axial wall height of 1 to 3 mm. This study provides some evidence that adhesion combined with an ideal total occlusal convergence may compensate for reduced axial wall height.

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