scholarly journals Metal-Silicate Equilibrium in the Core Formation of the Earth.

1998 ◽  
Vol 27 (3) ◽  
pp. 179-184
Author(s):  
Eiji OHTANI
Keyword(s):  
Core Formation ◽  
The Core ◽  
The Earth ◽  
Metal Silicate

scholarly journals Experimental evidence for hydrogen incorporation into Earth’s core

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Shoh Tagawa ◽  
Naoya Sakamoto ◽  
Kei Hirose ◽  
Shunpei Yokoo ◽  
John Hernlund ◽  
...  
Keyword(s):  
Terrestrial Planet ◽  
Outer Core ◽  
Core Formation ◽  
Earth’S Core ◽  
Hydrogen Incorporation ◽  
Earth's Core ◽  
The Core ◽  
The Earth ◽  
Metal Silicate ◽  
Important Constituent

AbstractHydrogen is one of the possible alloying elements in the Earth’s core, but its siderophile (iron-loving) nature is debated. Here we experimentally examined the partitioning of hydrogen between molten iron and silicate melt at 30–60 gigapascals and 3100–4600 kelvin. We find that hydrogen has a metal/silicate partition coefficient DH ≥ 29 and is therefore strongly siderophile at conditions of core formation. Unless water was delivered only in the final stage of accretion, core formation scenarios suggest that 0.3–0.6 wt% H was incorporated into the core, leaving a relatively small residual H2O concentration in silicates. This amount of H explains 30–60% of the density deficit and sound velocity excess of the outer core relative to pure iron. Our results also suggest that hydrogen may be an important constituent in the metallic cores of any terrestrial planet or moon having a mass in excess of ~10% of the Earth.

Accretion and core formation: constraints from metal–silicate partitioning

2008 ◽  
Vol 366 (1883) ◽  
pp. 4339-4355 ◽  
Author(s):  
Bernard J Wood
Keyword(s):  
Oxidation State ◽  
Maximum Pressure ◽  
Magma Ocean ◽  
Core Formation ◽  
The Core ◽  
Refractory Elements ◽  
The Earth ◽  
Metal Silicate ◽  
Restricted Volume ◽  
Si Content

Experimental metal–silicate partitioning data for Ni, Co, V, Cr, Nb, Mn, Si and W were used to investigate the geochemical consequences of a range of models for accretion and core formation on Earth. The starting assumptions were chondritic ratios of refractory elements in the Earth and the segregation of metal at the bottom of a magma ocean, which deepened as the planet grew and which had, at its base, a temperature close to the liquidus of the silicate. The models examined were as follows. (i) Continuous segregation from a mantle which is chemically homogeneous and which has a fixed oxidation state, corresponding to 6.26 per cent oxidized Fe. Although Ni, Co and W partitioning is consistent with chondritic ratios, the current V content of the silicate Earth cannot be reconciled with core segregation under these conditions of fixed oxidation state. (ii) Continuous segregation from a mantle which is chemically homogeneous but in which the Earth became more oxidized as it grew. In this case, the Ni, Co, W, V, Cr and Nb contents of core and mantle are easily matched to those calculated from the chondritic ratios of refractory elements. The magma ocean is calculated to maintain a thickness approximately 35 per cent of the depth to the core–mantle boundary in the accreting Earth, yielding a maximum pressure of 44 GPa. This model yields a Si content of the core of 5.7 per cent, in good agreement with cosmochemical estimates and with recent isotopic data. (iii) Continuous segregation from a mantle which is not homogeneous and in which the core equilibrates with a restricted volume of mantle at the base of the magma ocean. This is found to increase depth of the magma ocean by approximately 50 per cent. All of the other elements (except Mn) have partitioning consistent with chondritic abundances in the Earth, provided the Earth became, as before, progressively oxidized during accretion. (iv) Continuous segregation of metal from a crystal-melt mush. In this case, pressures decrease to a maximum of 31 GPa and it is extremely difficult to match the calculated mantle contents of the highly incompatible elements Nb and W to those observed. Progressive oxidation is required to fit the observed mantle contents of vanadium. All of the scenarios discussed above point to progressive oxidation having occurred as the Earth grew. The Earth appears to be depleted in Mn relative to the chondritic reference.

scholarly journals The niobium and tantalum concentration in the mantle constrains the composition of Earth’s primordial magma ocean

2020 ◽  
Vol 117 (45) ◽  
pp. 27893-27898
Author(s):  
Dongyang Huang ◽  
James Badro ◽  
Julien Siebert
Keyword(s):  
Diamond Anvil Cell ◽  
Magma Ocean ◽  
Core Formation ◽  
The Core ◽  
Bulk Silicate Earth ◽  
Reducing Conditions ◽  
Metal Silicate ◽  
Diamond Anvil ◽  
Laser Heated ◽  
Tantalum Concentration

The bulk silicate Earth (BSE), and all its sampleable reservoirs, have a subchondritic niobium-to-tantalum ratio (Nb/Ta). Because both elements are refractory, and Nb/Ta is fairly constant across chondrite groups, this can only be explained by a preferential sequestration of Nb relative to Ta in a hidden (unsampled) reservoir. Experiments have shown that Nb becomes more siderophile than Ta under very reducing conditions, leading the way for the accepted hypothesis that Earth’s core could have stripped sufficient amounts of Nb during its formation to account for the subchondritic signature of the BSE. Consequently, this suggestion has been used as an argument that Earth accreted and differentiated, for most of its history, under very reducing conditions. Here, we present a series of metal–silicate partitioning experiments of Nb and Ta in a laser-heated diamond anvil cell, at pressure and temperature conditions directly comparable to those of core formation; we find that Nb is more siderophile than Ta under any conditions relevant to a deep magma ocean, confirming that BSE’s missing Nb is in the core. However, multistage core formation modeling only allows for moderately reducing or oxidizing accretionary conditions, ruling out the need for very reducing conditions, which lead to an overdepletion of Nb from the mantle (and a low Nb/Ta ratio) that is incompatible with geochemical observations. Earth’s primordial magma ocean cannot have contained less than 2% or more than 18% FeO since the onset of core formation.

The redox state of the mantle during and just after core formation

2008 ◽  
Vol 366 (1883) ◽  
pp. 4315-4337 ◽  
Author(s):  
D.J Frost ◽  
U Mann ◽  
Y Asahara ◽  
D.C Rubie
Keyword(s):  
Oxygen Fugacity ◽  
Oxidation State ◽  
Upper Mantle ◽  
Partition Coefficients ◽  
Metal Loss ◽  
Core Formation ◽  
The Core ◽  
Mantle Mineral ◽  
Metal Silicate ◽  
Siderophile Elements

Siderophile elements are depleted in the Earth's mantle, relative to chondritic meteorites, as a result of equilibration with core-forming Fe-rich metal. Measurements of metal–silicate partition coefficients show that mantle depletions of slightly siderophile elements (e.g. Cr, V) must have occurred at more reducing conditions than those inferred from the current mantle FeO content. This implies that the oxidation state (i.e. FeO content) of the mantle increased with time as accretion proceeded. The oxygen fugacity of the present-day upper mantle is several orders of magnitude higher than the level imposed by equilibrium with core-forming Fe metal. This results from an increase in the Fe 2 O 3 content of the mantle that probably occurred in the first 1 Ga of the Earth's history. Here we explore fractionation mechanisms that could have caused mantle FeO and Fe 2 O 3 contents to increase while the oxidation state of accreting material remained constant (homogeneous accretion). Using measured metal–silicate partition coefficients for O and Si, we have modelled core–mantle equilibration in a magma ocean that became progressively deeper as accretion proceeded. The model indicates that the mantle would have become gradually oxidized as a result of Si entering the core. However, the increase in mantle FeO content and oxygen fugacity is limited by the fact that O also partitions into the core at high temperatures, which lowers the FeO content of the mantle. (Mg,Fe)(Al,Si)O 3 perovskite, the dominant lower mantle mineral, has a strong affinity for Fe 2 O 3 even in the presence of metallic Fe. As the upper mantle would have been poor in Fe 2 O 3 during core formation, FeO would have disproportionated to produce Fe 2 O 3 (in perovskite) and Fe metal. Loss of some disproportionated Fe metal to the core would have enriched the remaining mantle in Fe 2 O 3 and, if the entire mantle was then homogenized, the oxygen fugacity of the upper mantle would have been raised to its present-day level.

Experiments on metal–silicate plumes and core formation

2008 ◽  
Vol 366 (1883) ◽  
pp. 4253-4271 ◽  
Author(s):  
Peter Olson ◽  
Dayanthie Weeraratne
Keyword(s):  
Lower Layer ◽  
High Viscosity ◽  
Primitive Mantle ◽  
Liquid Gallium ◽  
Magma Ocean ◽  
Core Formation ◽  
Thermal Plumes ◽  
The Core ◽  
Metal Silicate ◽  
Sucrose Solutions

Short-lived isotope systematics, mantle siderophile abundances and the power requirements of the geodynamo favour an early and high-temperature core-formation process, in which metals concentrate and partially equilibrate with silicates in a deep magma ocean before descending to the core. We report results of laboratory experiments on liquid metal dynamics in a two-layer stratified viscous fluid, using sucrose solutions to represent the magma ocean and the crystalline, more primitive mantle and liquid gallium to represent the core-forming metals. Single gallium drop experiments and experiments on Rayleigh–Taylor instabilities with gallium layers and gallium mixtures produce metal diapirs that entrain the less viscous upper layer fluid and produce trailing plume conduits in the high-viscosity lower layer. Calculations indicate that viscous dissipation in metal–silicate plumes in the early Earth would result in a large initial core superheat. Our experiments suggest that metal–silicate mantle plumes facilitate high-pressure metal–silicate interaction and may later evolve into buoyant thermal plumes, connecting core formation to ancient hotspot activity on the Earth and possibly on other terrestrial planets.

Composition of Earth

2021 ◽  
Author(s):  
H. Palme
Keyword(s):  
Upper Mantle ◽  
Core Formation ◽  
Formation Model ◽  
Major Element Composition ◽  
The Core ◽  
The Earth ◽  
The 1960S ◽  
Isotope Analyses ◽  
Uniform Composition

Early models of the composition of the Earth relied heavily on meteorites. In all these models Earth had different layers, each layer corresponded to a different type of meteorite or meteorite component. Later, more realistic models based on analyses of samples from Earth began with Ringwood’s pyrolite composition in the 1960s. Further improvement came with the analyses of rare MgO rich peridotites from a variety of occurrences all over the Earth, as xenoliths enclosed in melts from the upper mantle or as ultramafic massifs, tectonically emplaced on the Earth’s surface. Chemical systematics of these rocks allow the determination of the major element composition of the primitive upper mantle (PUM), the upper mantle after core formation and before extraction of basalts ultimately leading to the formation of the crust. Trace element analyses of upper mantle rocks confirmed their primitive nature. Geochemical and geophysical evidence argue for a bulk Earth mantle of uniform composition, identical to the PUM, also designated as “bulk silicate Earth” (BSE). The formation of a metal core was accompanied by the removal of siderophile and chalcophile elements into the core. Detailed modeling suggests that core formation was an ongoing process parallel to the accretion of Earth. The composition of the core is model dependent and thus uncertain and makes reliable estimates for siderophile and chalcophile element concentrations of bulk Earth difficult. Improved stable isotope analyses show isotopic similarities with noncarbonaceous chondrites (NCC), while the chemical composition of the mantle of the Earth indicates similarities with carbonaceous chondrites (CC). In detail, however, it can be shown that no single known meteorite group, nor any mixture of meteorite groups can match the chemical and isotopic composition of Earth. This conclusion is extremely important for any formation model of the Earth.

Ups and Downs

2018 ◽  
Author(s):  
Roy Livermore
Keyword(s):  
Mantle Convection ◽  
Laboratory Experiments ◽  
Inner Core ◽  
Computer Modelling ◽  
Great Depth ◽  
New Horizons ◽  
The Core ◽  
The Earth ◽  
The World ◽  
The 1960S

Despite the dumbing-down of education in recent years, it would be unusual to find a ten-year-old who could not name the major continents on a map of the world. Yet how many adults have the faintest idea of the structures that exist within the Earth? Understandably, knowledge is limited by the fact that the Earth’s interior is less accessible than the surface of Pluto, mapped in 2016 by the NASA New Horizons spacecraft. Indeed, Pluto, 7.5 billion kilometres from Earth, was discovered six years earlier than the similar-sized inner core of our planet. Fortunately, modern seismic techniques enable us to image the mantle right down to the core, while laboratory experiments simulating the pressures and temperatures at great depth, combined with computer modelling of mantle convection, help identify its mineral and chemical composition. The results are providing the most rapid advances in our understanding of how this planet works since the great revolution of the 1960s.

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