scholarly journals Effect of Crosslink Density on Nonlinear Stress-Strain Behavior of Epoxy Glasses Subjected to Large Deformation

2013 ◽  
Vol 62 (1) ◽  
pp. 22-26 ◽  
Author(s):  
Shin'ya YOSHIOKA ◽  
Yuichiro YOKOYAMA
1985 ◽  
Vol 58 (4) ◽  
pp. 830-856 ◽  
Author(s):  
R. J. Cembrola ◽  
T. J. Dudek

Abstract Recent developments in nonlinear finite element methods (FEM) and mechanics of composite materials have made it possible to handle complex tire mechanics problems involving large deformations and moderate strains. The development of an accurate material model for cord/rubber composites is a necessary requirement for the application of these powerful finite element programs to practical problems but involves numerous complexities. Difficulties associated with the application of classical lamination theory to cord/rubber composites were reviewed. The complexity of the material characterization of cord/rubber composites by experimental means was also discussed. This complexity arises from the highly anisotropic properties of twisted cords and the nonlinear stress—strain behavior of the laminates. Micromechanics theories, which have been successfully applied to hard composites (i.e., graphite—epoxy) have been shown to be inadequate in predicting some of the properties of the calendered fabric ply material from the properties of the cord and rubber. Finite element models which include an interply rubber layer to account for the interlaminar shear have been shown to give a better representation of cord/rubber laminate behavior in tension and bending. The application of finite element analysis to more refined models of complex structures like tires, however, requires the development of a more realistic material model which would account for the nonlinear stress—strain properties of cord/rubber composites.


1994 ◽  
Vol 33 (Part 1, No. 9B) ◽  
pp. 5341-5344 ◽  
Author(s):  
Toshio Tanimoto ◽  
Kohji Yamamoto ◽  
Tohru Morii

Author(s):  
Shinji Ogihara ◽  
Yusuke Hirakawa ◽  
Nobuo Takeda

1966 ◽  
Vol 39 (5) ◽  
pp. 1489-1495
Author(s):  
L. C. Case ◽  
R. V. Wargin

Abstract A new theoretical treatment strongly indicates that an elastomer network actually consists of a system of fused, closed, interpenetrating loops of polymer chains. This interpenetrating loop structure restricts the movement of the chains and thereby affects the stress-strain behavior of the elastomer. Methods have been developed to enable the calculation of the number of effective crosslinks caused by loop interpenetrations (virtual crosslinks). The uniaxial stress-strain behavior of an elastomer predicted using our methods can be fitted almost perfectly to published experimental data by proper selection of chain parameters. Previous theoretical treatments gave only a qualitative fit to the experimental data for the stress-strain behavior of elastomers and were not capable of predicting the correct shape of the experimental stress-strain curve. The present treatment gives a nearly perfect fit for both stress as a function of strain at constant crosslink density, and stress as a function of crosslink density at constant strain, and thus represents a vast improvement.


1991 ◽  
Vol 64 (2) ◽  
pp. 234-242
Author(s):  
R. F. Bauer ◽  
A. H. Crossland

Abstract Properties of the individual phases in a 70/30 carbon-black-loaded BR/NR blend could be successfully resolved using large deformation stress-strain modelling. Since the dispersed NR phase of the example had a lower modulus than the continuous BR phase, the interaction between the blend phases could be modelled by a simple parallel coupling arrangement. The stress behavior of each individual carbon-black-loaded polymer phase was then determined with respect to strain using a specially derived stress-strain relationship. The blend components also have to be characterized with respect to state-of-cure by empirically establishing how the parameters in the stress-strain relationship vary with respect to cure. The properties of the phases in the blend are then determined by finding the combination of component parameters which precisely reproduce the stress-strain behavior of the blend. In the demonstration example of this paper, there was evidence of a significant amount of curative migration between phases during the vulcanization process.


Polymer ◽  
2006 ◽  
Vol 47 (1) ◽  
pp. 319-329 ◽  
Author(s):  
J. Yi ◽  
M.C. Boyce ◽  
G.F. Lee ◽  
E. Balizer

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