scholarly journals The Effects of Cigarette Filter Ventilation on Delivery and Retention of Organic Acids

2021 ◽  
Vol 30 (4) ◽  
pp. 199-211
Author(s):  
Deng Qixin ◽  
Xie Wei ◽  
Liu Zechun ◽  
Liu Jiangsheng ◽  
Zhang Tingui ◽  
...  
Keyword(s):  
Particulate Matter ◽  
Organic Acids ◽  
Cigarette Smoke ◽  
Spatial Concentration ◽  
Total Particulate Matter ◽  
Yield Increase ◽  
Acid Base Equilibrium ◽  
Air Compression ◽  
Simultaneous Identification ◽  
Mainstream Cigarette Smoke

Summary A method for simultaneous identification and quantitative determination of 30 organic acids was established. The smoke yields and filter retentions of organic acids and routine smoke components, total particulate matter (TPM), nicotine-free dry particulate matter (NFDPM), nicotine and carbon monoxide (CO) at different filter ventilation levels were determined under both International Organization for Standardization (ISO) and Health Canadian Intense (HCI) smoking regimes. As a result of smoke dilution during filter ventilation, the yields of all organic acids were reduced in mainstream cigarette smoke. The spatial distribution pattern of the concentration of each organic acid in the filter was investigated at different ventilation levels and their filter retention determined. On one hand, the concentration of organic acids with a lower boiling point (BP) and lower molecular weight (MW) was relatively higher at the smoking end and the periphery part of the filter and spatial concentration distributions within the filter were significantly affected by smoke diffusion. On the other hand, those acids with high BPs and high MW were mainly distributed at the tobacco rod end and central part of the filter and spatial concentration distributions were only slightly influenced by their smoke diffusion within the filter whilst air compression around the filter vents also led to less change. This way, different acids in mainstream cigarette smoke were reduced to different extents which can also influence the acid-base equilibrium and sensory quality of the smoke. Compared with ISO smoking regime, the vent blocking and more intense smoking HCI regime led to different extents of yield increase for each of the studied acids. The effect of filter ventilation in the HCI smoking regime was not investigated, as the HCI smoking regime requires blocked ventilation holes. [Contrib. Tob. Nicotine Res. 30 (2021) 199–211]

scholarly journals Transfer of Maleic Hydrazide into Mainstream Cigarette Smoke

2003 ◽  
Vol 20 (5) ◽  
pp. 325-330
Author(s):  
W Wood ◽  
GL Dooly ◽  
SC Moldoveanu
Keyword(s):  
Particulate Matter ◽  
Cigarette Smoke ◽  
Transfer Rate ◽  
Maleic Hydrazide ◽  
The Other ◽  
Total Particulate Matter ◽  
The One ◽  
Relative Transfer ◽  
Different Levels ◽  
Mainstream Cigarette Smoke

AbstractThis report presents the results of a study regarding the transfer of maleic hydrazide (MH) into mainstream cigarette smoke. Cigarettes with different levels of MH were used in this study. This included cigarettes with MH preexistent in the tobacco due to the agronomical practice, and with spiked MH. Because the MH can be present in tobacco as bound and free forms, both levels of MH were measured in the tobacco section. The cigarette designs covered a range of possibilities, including Plain, Filter King Size (KS), Lights 100’s, Ultra Lights, etc. The results showed that the amount of MH in smoke, on the one hand, is a function of the total particulate matter (TPM) of the cigarette, and higher TPM levels lead to more MH in smoke. On the other hand, the transferred level of MH depends on the total amount of MH (both bound and free) in the tobacco. The relative % transfer is higher for lower MH levels than for higher MH levels in tobacco. When normalized by TPM, the transfer as an average is about 0.24% per mg of TPM from the amount of MH in 1 g of tobacco, and as high as 0.46% per mg of TPM from the amount of MH in 1 g tobacco for a nonfilter low MH level cigarette. The resulting MH transfer for a nonfilter cigarette with low tobacco MH is therefore about 8.3% from the total MH in the cigarette. For filter full flavor (FF) cigarettes with high tobacco levels of MH, the transfer is about 5.8%. This relative transfer rate appears to be lower from higher MH levels in tobacco.

scholarly journals Dioxin Levels in Mainstream Smoke from Cigarettes with Different TPM Deliveries

2004 ◽  
Vol 21 (4) ◽  
pp. 205-209 ◽  
Author(s):  
CJ Smith ◽  
DC Sykes ◽  
DW Cantrell ◽  
SC Moldoveanu
Keyword(s):  
Particulate Matter ◽  
Cigarette Smoke ◽  
Previous Literature ◽  
Mainstream Smoke ◽  
Total Particulate Matter ◽  
Toxic Equivalents ◽  
Light Cigarettes ◽  
Mainstream Cigarette Smoke ◽  
Chlorinated Dibenzofurans

AbstractThe presence of dioxin-like compounds, such as chlorinated dibenzodioxins, chlorinated dibenzofurans and chlorinated biphenyls, in mainstream cigarette smoke has been investigated for seven cigarette brands covering a range of ‘tar’ deliveries from 1 mg to 14 mg. Adjusted per milligram of total particulate matter (TPM), ultra-light cigarettes had the highest concentrations of toxic equivalents (TEQ) of 10 fg/mg TPM. As the ‘tar’ delivery increased, lower concentration values were found in lights and full-flavor cigarettes. Calculated on the basis of a pack of twenty cigarettes, mainstream smoke from the ultra-lights and lights products produced values around 200 fg TEQ, and the full-flavor brand produced 575 fg TEQ per pack. Levels of TEQ from dioxin-like compounds in the tobacco section of four cigarette brands did not show significant differences and were similar to previous literature findings.

The Control of Cigarette Smoke Deliveries Using Heat-Shrinkable Films

1975 ◽  
Vol 8 (2) ◽  
Author(s):  
R. A. Crellin ◽  
G. O. Brooks ◽  
H. G. Horsewell
Keyword(s):  
Particulate Matter ◽  
Cellulose Acetate ◽  
Cigarette Smoke ◽  
Total Particulate Matter ◽  
Puff Volume ◽  
Cigarette Paper ◽  
High Degree

AbstractA ventilating filter for cigarettes has been developed which reduces the delivery of smoke constituents from the final two to three puffs. Since the normaI delivery for these three puffs can account for up to half the total particulate matter and nicotine delivered by the whole cigarette, usefuI reductions per cigarette can be produced. The ventilating filter consists of cellulose acetate tow wrapped in heat-shrinkable film and attached to a tobacco rod using perforated tipping paper. When the cigarette is smoked, the perforations remain closed by contact with the impermeable film until transfer of heat to the filter is sufficient to soften the filter tow and shrink the film. Ventilating air now enters the cigarette and reduces the smoke deliveries. The effectiveness of the ventilating filter is increased by using films which have a low shrink temperature, high shrink tension and a high degree of biaxiaI shrinkage. Increases in filter plasticiser level, tipping perforation area and puff volume improve the effectiveness of the ventilating filter but increases in cigarette paper porosity and tobacco butt length reduce the effectiveness

scholarly journals Composition Studies on Tobacco: XLV. Use of Cigarette Additives to Alter the Composition and Reducing Properties of Cigarette Smoke

1972 ◽  
Vol 6 (3) ◽  
Author(s):  
L. Lakritz ◽  
E.D. Strange ◽  
D.G. Bailey ◽  
R.L. Stedman
Keyword(s):  
Particulate Matter ◽  
Cigarette Smoke ◽  
Composition Studies ◽  
Sodium Thiosulfate ◽  
Rapid Reduction ◽  
Total Particulate Matter ◽  
Nicotine Content ◽  
Reducing Capacity ◽  
Reducing Properties ◽  
Reducing Potential

AbstractThe reducing potential of fresh cigarette smoke can be modified by the use of certain oxidants and reductants. The influence of these additives on smoke may be monitored by employing a system which measures changes in EMF on a puff by puff basis. The addition of the oxidant 1,4-benzoquinone to tobacco eliminates the rapid reduction in potential which normally takes place when an untreated cigarette is smoked. The addition of the benzoquinone alters the composition of the smoke by increasing the levels of the total particulate matter and possibly the phenols, while decreasing the nicotine content without affecting the amount of benzo[a]pyrene formed. The addition of sodium thiosulfate to tobacco causes a significant increase in the reducing capacity of cigarette smoke. It also brings about increases in the smoke BAP, phenols and TPM. The level of nicotine in these cigarettes, however, is lowered.

scholarly journals Numerical Simulation of the Distribution of In Situ Cigarette Combustion-Generated Particulate Matter

2020 ◽  
Vol 4 (4) ◽  
pp. 59
Author(s):  
Shi Chen ◽  
Hanqing Liu ◽  
Zhiguo Sun ◽  
Hongyong Xie
Keyword(s):  
Mathematical Model ◽  
Particulate Matter ◽  
Cigarette Smoke ◽  
Cross Section ◽  
Constant Pressure ◽  
Particle Diameter ◽  
Axial Position ◽  
Number Density ◽  
Total Particulate Matter

This paper has established a two-dimensional (2D) mathematical model for the generation, growth, and deposition of cigarette total particulate matter (TPM) in the smoldering state. The model has covered the chemical reactions and mass transfer as well as the mechanism of generation, flow, and condensation of particulate matter inside a burning cigarette. Cigarette smoke was generated by puffing under a constant pressure, and the pressure of the filter outlet was −274 Pa. The peak of the concentration of particulate matter was spatially overlapped with the peaks of pyrolysis and oxidation. Pertaining to the cross section of the cigarette at the same axial position, the peak of the diameter of particulate matter along the radial distribution first appeared in the zone near the edge of the cigarette cross section, and then gradually moved to the center of the cigarette with the cigarette smoke moving away from the combustion cone. The maximum number density of particulate matter calculated by the 2D mathematical model at the same axial position of the cigarette and the corresponding particle diameter, as well as the filtration efficiency of the filter rod, are in good accordance with the experimental data reported in previous studies.

scholarly journals Total particulate matter concentration skews cigarette smoke's gene expression profile

2016 ◽  
Vol 2 (4) ◽  
pp. 00029-2016 ◽  
Author(s):  
Anna Dvorkin-Gheva ◽  
Gilles Vanderstocken ◽  
Ali Önder Yildirim ◽  
Corry-Anke Brandsma ◽  
Ma'en Obeidat ◽  
...  
Keyword(s):  
Gene Expression ◽  
Particulate Matter ◽  
Cigarette Smoke ◽  
Gene Expression Profile ◽  
Expression Profile ◽  
Smoke Exposure ◽  
Cigarette Smoke Exposure ◽  
Chronic Obstructive ◽  
Total Particulate Matter ◽  
Xenobiotic Detoxification

Exposure of small animals to cigarette smoke is widely used as a model to study the pathogenesis of chronic obstructive pulmonary disease. However, protocols and exposure systems utilised vary substantially and it is unclear how these different systems compare.We analysed the gene expression profile of six publically available murine datasets from different cigarette smoke-exposure systems and related the gene signatures to three clinical cohorts.234 genes significantly regulated by cigarette smoke in at least one model were used to construct a 55-gene network containing 17 clusters. Increasing numbers of differentially regulated clusters were associated with higher total particulate matter concentrations in the different datasets. Low total particulate matter-induced genes mainly related to xenobiotic/detoxification responses, while higher total particulate matter activated immune/inflammatory processes in addition to xenobiotic/detoxification responses. To translate these observations to the clinic, we analysed the regulation of the revealed network in three human cohorts. Similar to mice, we observed marked differences in the number of regulated clusters between the cohorts. These differences were not determined by pack-year.Although none of the experimental models exhibited a complete alignment with any of the human cohorts, some exposure systems showed higher resemblance. Thus, depending on the cohort, clinically observed changes in gene expression may be mirrored more closely by specific cigarette smoke exposure systems. This study emphasises the need for careful validation of animal models.

Determination of Total Particulate Matter, Nicotine, and Water in Cigarette Smoke

1962 ◽  
Vol 45 (3) ◽  
pp. 540-545
Author(s):  
C L Ogg ◽  
W W Bates ◽  
E C Cogbill ◽  
R H Blackmore ◽  
E L Petersen
Keyword(s):  
Particulate Matter ◽  
Cigarette Smoke ◽  
Total Particulate Matter
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