scholarly journals Water Resistance of Photosensitive Poly(Vinyl Alcohol) Films.

2001 ◽  
Vol 14 (2) ◽  
pp. 293-294 ◽  
Author(s):  
Yoichi Shindo ◽  
Masatoshi Hasegawa ◽  
Junichi Kawanobe ◽  
Kazuo Inoue
2016 ◽  
Vol 852 ◽  
pp. 979-983
Author(s):  
Ping Rui Meng ◽  
Liang Bo Li

Sodium acrylate (NaAA) and acrylamide (AM) were grafted onto poly (vinyl alcohol) (PVA) using potassium persulfate as an initiator, Graft copolymerization namely poly (vinyl alcohol)-g-poly (acrylamide/sodium acrylate) (PVA-g-PAM/SAC). The poly (vinyl alcohol)-g-poly (vinylamine/sodium acrylate) (PVAMC) was prepraed by Hofmann rearrangement.The PVAMC homogeneous membrane was characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM).The water resistance of the PVAMC membranes is the best when pH of the PVAMC solutions was 4, at that time the numbers of-NH3+ and-COO- groups trended to be equal, so the isoelectric point was pH=4. At 90 °C the pervaporation of PVAMC composite membrane was tested and showed that the separation factor and the permeate flux were about 1001 and 1341 g/(m2·h) for 90wt% ethanol aqueous solution, and they were about 1297 and 1040 g/(m2·h) for 90wt% isopropanol aqueous solution.


2011 ◽  
Vol 45 (11) ◽  
pp. 1201-1207 ◽  
Author(s):  
Toh Wen Yee ◽  
Lai Jau Choy ◽  
Wan Aizan Wan Abdul Rahman

A series of blends of sago pith waste (SPW) and poly(vinyl alcohol) (PVA) were prepared. Mechanical and water absorption properties of the composites have been investigated. In this study, variable amounts of plasticized SPW (pSPW) and PVA (pPVA) were processed in the presence of glycerol as plasticizers. Composites were compression molded and evaluated. The addition of pSPW reduced the tensile properties of the composites, lowering the elongation and increasing Young’s modulus. The reduction in mechanical strength with the addition of pSPW was a general phenomenon due to the poor interfacial adhesion between the pPVA and Pspw, which can be proved by the scanning electron microscope observations. The percentage of water absorbed of the pPVA/pSPW biocomposites was higher than either the pPVA or pSPW alone while pSPW showed better water resistance compared to pPVA because of the restricted mobility exerted by the cellulose fibers. The incorporation of SPW into PVA decreased both the mechanical and water absorption properties.


1963 ◽  
Vol 1 (12) ◽  
pp. 697-699 ◽  
Author(s):  
Kiyoshi Fujii ◽  
Takani Mochizuki ◽  
Junji Ukida ◽  
Masakazu Matsumoto

e-Polymers ◽  
2010 ◽  
Vol 10 (1) ◽  
Author(s):  
Qun Wang ◽  
Lu Qi

AbstractA group of films mainly composed of sericin and poly(vinyl alcohol) (PVA), using boric acid (BA) as a modifier, were prepared by a technique of solution casting. In this work, the effect of BA and sericin on the mechanical properties and water resistance of the films was analyzed, the interior morphology of the films were described by a scanning electron microscopy (SEM), the thermal stability of the films was characterized by differential scanning calorimetry (DSC), and the reaction mechanism was proposed according to the previous literature and the test of Fourier transform infrared spectrum (FTIR). Results indicated that, the properties of the membrane were the functions of the blend ratio of sercin to PVA and the content of BA. The use of BA increased the tensile strength, improved the water resistance and the thermal stability, and varied the interior morphology of the films. The content of sericin greatly influenced the combination of properties of the films, especially the mechanical properties, interior morphology, thermal stability, and water resistance reducing with the increasing of sericin content. The films have potential to be used in materials, such as skin-care coatings for beauty, percutaneous drug delivery systems for exterior intact skin, due to the characteristics of the components and the good mechanical properties of the films.


2007 ◽  
Vol 106 (5) ◽  
pp. 3430-3434 ◽  
Author(s):  
Sung Jun Lee ◽  
Se Geun Lee ◽  
Hoyoung Kim ◽  
Won Seok Lyoo

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