scholarly journals Aplikasi Lakase pada Proses Refining Pulp

2019 ◽  
Vol 9 (02) ◽  
pp. 65
Author(s):  
Hendro Risdianto ◽  
Sonny Kurnia Wirawan ◽  
Susi Sugesty
Keyword(s):  
Reaction Rate ◽  
Refining Process ◽  
Enzyme Treatment ◽  
Paper Strength ◽  
Tensile Index ◽  
Tear Index ◽  
Acacia Crassicarpa

Refining merupakan proses untuk memodifikasi serat dengan tujuan meningkatkan ikatan serat dan mengembangkan kekuatan kertas. Penelitian yang telah dilakukan meliputi penentuan kondisi refining dengan PFI Mill dan penentuan kondisi perlakuan awal lakase yang selanjutnya akan diterapkan pada proses biorefining. Jumlah putaran 2500 dari PFI mill merupakan jumlah yang optimum untuk menghasilkan kekuatan pulp Acacia crassicarpa. Sedangkan hasil penelitian kondisi optimum lakase menunjukkan bahwa lakase memiliki laju reaksi yang paling tinggi (0,0018 mM/s) pada suhu 50°C. Pada proses refining, freeness awal pulp adalah sekitar 550 mL CSF, dan ketika dikenakan perlakuan lakase turun menjadi 515 (LMS1) dan 520 (LMS2). Refining pulp tanpa perlakuan enzim menghasilkan indeks tarik, retak dan sobek berturut-turut adalah 6,4.10-2 kNm/g, 5,18 kPa.m2/g, dan 5,96 mN.m2/g. Indeks sobek tidak mengalami perubahan signifikan pada semua perlakuan. Perlakuan LMS1 meningkatkan indeks tarik menjadi 6,83 kNm/g dan indeks sobek menjadi 7,53 mN.m2/g. Indeks tarik dan sobek pada LMS2 menurun dibandingkan LMS1, namun masih lebih tinggi dibandingkan tanpa perlakuan. Dengan demikian perlakuan lakase pada proses refining dapat meningkatkan indeks tarik dan indeks sobek lembaran.Laccase Application in Pulp Refining Process AbstractRefining is a process to modify fibers with the aim of increasing fiber bonds and developing paper strength. The research that has been done includes determining the refining conditions with PFI Mill and determining the conditions of pretreatment of laccase which will then be applied to the biorefining process. The PFI mill revolutions of 2500 is the optimum to produce the strength of the Acacia crassicarpa pulp. Whereas the results of the study showed that optimum laccase conditions showed that laccase had the highest reaction rate (0.0018 mM/s) at 50oC. In the refining process, the initial freeness of the pulp is around 550 mL CSF, and when subjected to laccase treatment it drops to 515 (LMS1) and 520 (LMS2). Refining the pulp without enzyme treatment produced tensile, bursting and tearing indexes of 6.4.10-2 kNm/g, 5.18 kPa.m2/g, and 5.96 mN.m2/g, respectively. The tear index did not change significantly in all treatments. The LMS1 treatment increased the tensile index to 6.83 kNm/g and the tear index to 7.53 mN.m2/g. The tensile and tear index in LMS2 decreased compared to LMS1, but it was still higher than without treatment. Thus, laccase treatment in the refining process can increase the tensile index and tear indexof the sheet.  

Optimization of chemical and enzymatic deinking of photocopier waste paper

BioResources ◽  
2010 ◽  
Vol 6 (1) ◽  
pp. 447-463 ◽  
Author(s):  
Puneet Pathak ◽  
Nishi K. Bhardwaj ◽  
Ajay K. Singh
Keyword(s):  
Physical Properties ◽  
Removal Efficiency ◽  
Strength Properties ◽  
Waste Paper ◽  
Cellulase Enzyme ◽  
Tensile Index ◽  
Drainage Time ◽  
Tear Index ◽  
The World ◽  
Better Than

The utilization of post-consumer papers in the production of new paper products is increasing all over the world in recent years. Recycling of photocopier paper is a major problem due to difficulty in removal of non-impact ink. Enzymes offer potential advantages in ecofriendly deinking of recovered paper. In this study the deinking of photocopier paper was examined using chemicals and a commercial cellulase enzyme. Parameters of deinking experiments were optimized for hydrapulping. The ink was removed by flotation and washing processes. Then these parameters were compared in terms of ink removal ability of the process, as well as optical and strength properties of the deinked paper. The application of enzymatic deinking improved ink removal efficiency by 24.6% and freeness by 21.6% with a reduction in drainage time of 11.5% in comparison to those obtained with chemical deinking. The physical properties, namely burst index and tensile index, were observed to improve by 15.3% and 2.7%, respectively and brightness and tear index decreased by 2.1% and 21.9%, respectively. Results of deinking efficiency of photocopier paper showed that the enzyme used in the present work performed better than the conventional chemicals used for deinking.

scholarly journals Potensi Penggunaan Dua Spesies Agave untuk Pembuatan Pulp dan Kertas

2018 ◽  
Vol 8 (01) ◽  
pp. 43
Author(s):  
Arini Hidayati Jamil ◽  
Heronimus Judi Tjahjono ◽  
Parnidi Parnidi ◽  
Marjani Marjani
Keyword(s):  
Physical Properties ◽  
Pulp And Paper ◽  
Raw Material ◽  
National Standard ◽  
Chemical Components ◽  
Pulp Yield ◽  
Fiber Morphology ◽  
Tensile Index ◽  
Tear Index ◽  
Agave Sisalana

Potential of Two Agave Species for Pulp and Paper MakingAbstractBoth of Agave sisalana and A. cantala are the most favorite agave species for fiber producer plant in Indonesia. Nevertheless, research study for using fiber of A. sisalana and A. cantala for pulp and paper purpose is hard to find. This study aims to observe the characteristics of A. sisalana and A. cantala fibers as a raw material of pulp including fiber morphology, chemical components, pulp characteristics, optical and physical properties of the handsheets. The observation of all characters was based on Indonesian National Standard (SNI). The pulping method used both of soda process with 18% active alkali and kraft process with 18% active alkali and 25% sulfidity. The result of the study for the handsheets from A. sisalana and A. cantala fibers shows that the brightness, dirt, and tear index were fulfilled to SNI standard for NBKP while the tensile index and burst index just fulfilled to SNI standard for LBKP. The handsheet of A. sisalana fiber has a higher tear index, tensile index, and burst index than the A. cantala ones. Soda pulping of both agave species resulting higher pulp yield, cellulose polymerization degrees and physical properties than kraft pulping.Keywords : Agave sisalana, A. cantala, characteristics of the fiber, pulp AbstrakAgave sisalana dan A. cantala merupakan dua spesies agave yang paling banyak dibudidayakan di Indonesia sebagai tanaman penghasil serat alam. Namun penelitian mengenai fungsi serat A. sisalana dan A. cantala sebagai bahan baku pulp dan kertas masih sulit ditemukan. Tujuan dari penelitian ini adalah mempelajari karakteristik serat A. sisalana dan A. cantala sebagai bahan baku pulp yang meliputi morfologi serat, komposisi komponen kimia, karakeristik pulp, sifat optik dan fisik lembaran pulp yang dihasilkan. Pengamatan seluruh karakter dilakukan berdasarkan Standar Nasional Indonesia. Pemasakan menggunakan metode soda dengan alkali aktif 18% dan kraft dengan alkali aktif 18% dan sulfiditas 25%. Hasil pengamatan pada lembaran pulp yang dihasilkan dari serat A. sisalana dan A. cantala menunjukkan bahwa derajat cerah, noda, dan kekuatan sobek memenuhi Standar Nasional Indonesia (SNI) Pulp Kraft Putih Kayujarum (NBKP) sementara kekuatan tarik dan kekuatan retak memenuhi SNI Pulp Krat Putih Kayudaun (LBKP). Lembaran pulp A. sisalana memiliki kekuatan sobek, tarik, dan retak lebih tinggi dibanding lembaran pulp A. cantala. Metode pemasakan soda pada serat kedua spesies agave tersebut menghasilkan rendemen pulp, derajat polimerisasi selulosa, dan kekuatan fisik lebih baik dibanding metode kraft.Kata kunci : Agave sisalana, A. cantala, karakteristik serat, pulp 

scholarly journals PENINGKATAN MUTU KERTAS DAUR ULANG MENGGUNAKAN XYLAN ( IMPROVEMENT QUALITY OF RECYCLED FIBER USING XYLAN )

2017 ◽  
Vol 7 (01) ◽  
pp. 33
Author(s):  
Sonny Kurnia Wirawan ◽  
Chandra Apriana Purwita ◽  
Nina Elyani
Keyword(s):  
Agricultural Waste ◽  
Strength Properties ◽  
Paper Strength ◽  
Tensile Index ◽  
Potential Source ◽  
Recycled Fiber ◽  
Corrugated Cardboard

ABSTRACTCorncob as agricultural waste is a potential source of xylan to be used as an additive to increase the paper strength sheets originating from old corrugated cardboard (OCC). The aim of this research is to know increasing of strength properties from recycled fiber after addition of corncob xylan, compared to the commercial xylan. The xylan extraction was carried out by acid and the addition of xylan to the fiber was carried out at 80 ºC for 30 minutes. The results showed that the use of corncob xylan 5% (w/w) can increase the tensile index by 13.08%, burst index by 9.24%, ring crush test (RCT) index by 39.13% and corrugated medium test (CMT) index by 17.44%.ABSTRAKTongkol jagung sebagai limbah pertanian merupakan sumber xylan yang potensial yang dapat digunakan sebagai aditif untuk meningkatkan kekuatan lembaran kertas daur ulang yang berasal dari Kertas Karton Gelombang (KKG) bekas. Tujuan penelitian ini adalah untuk mengetahui peningkatan kekuatan lembaran kertas daur ulang setelah penambahan xylan dari tongkol jagung, dibandingkan dengan xylan komersial. Ekstraksi xylan dilakukan dengan metode asam dan penambahan xylan terhadap serat dilakukan pada temperatur 80ºC selama 30 menit. Hasil penelitian menunjukkan bahwa penggunaan xylan tongkol jagung sebanyak 5% (berat xylan/berat kering pulp) dapat meningkatkan indeks tarik 13,08%, indeks retak 9,24%, indeks RCT 39,13% dan indeks CMT 17,44%.

Effect of nanofibrillated cellulose made from enzyme-pretreated bamboo pulp on paper strength

BioResources ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 964-978
Author(s):  
Hae Min Jo ◽  
Ji Young Lee ◽  
Su Ho Kim ◽  
Yeon Hui Lee
Keyword(s):  
Physical Properties ◽  
Kraft Pulp ◽  
Nanofibrillated Cellulose ◽  
Raw Material ◽  
Paper Strength ◽  
Strength Enhancement ◽  
Tensile Index ◽  
Similar Improvement ◽  
Bamboo Pulp ◽  
Enzyme Pretreatment

The applicability of bleached bamboo kraft pulp (Ba-BKP) was explored as a raw material for the manufacture of nanofibrillated cellulose (EN-NFC) made of enzyme-pretreated pulps and the effects of the EN-NFC on enhancing paper strength. The Ba-BKP was pretreated using an endo-glucanase enzyme at 50 °C and pH 6, after which the EN-NFC was made by micro-grinding. Bleached hardwood kraft pulp (Hw-BKP) was used as a control, and the non-enzymatic refining pretreatment of BKPs was compared with the enzyme pretreatment. The EN-NFC was incorporated into handsheets, and the sheet strengths were measured. The physical properties of the NFC made from the Ba-BKP were similar to those made from the Hw-BKP. The NFC prepared following enzyme pretreatment were smaller and more uniform than those pretreated with refining. The EN-NFC made from the Ba-BKP was effective at enhancing tensile index by 52.7%, and burst index by 210.2% when 2% of EN-NFC was added in the furnish, and those of handsheets containing the EN-NFC made from Hw-BKP showed the similar improvement. Therefore, Ba-BKP can be used as a raw material for the manufacture of EN-NFC that confers similar physical properties and strength enhancement to paper as those made from Hw-BKP.

Effect of Cellulase Pretreatment on Alkali-Oxygen Pulping of Bagasse

2012 ◽  
Vol 518-523 ◽  
pp. 332-336
Author(s):  
Bing Sun ◽  
Wen Zhuo Xin ◽  
Yu Xin Liu ◽  
Ke Li Chen
Keyword(s):  
Lignin Content ◽  
Uv Spectroscopy ◽  
Kappa Number ◽  
Tensile Index ◽  
Tear Index ◽  
Folding Endurance ◽  
Significant Change ◽  
Cooking Conditions

In this paper, the process of cellulase pretreatment before alkali-oxygen pulping of bagasse was studied. The effect of cellulase pretreatment on subsequent pulping was also researched. The results showed that some small-sized components and sugars dissolved into the effluent in the process of cellulase pretreatment. UV spectroscopy showed that there was no significant lignin content in the pretreatment effluent.It was also found that pulping properties were promoted when the cellulase dosage was 2 ECU/g pulp, in that under the same cooking conditions, pulp kappa number was decreased by 1.3 and pulp brightness was increased by 2.5 %ISO, while the viscosity of pulp also increased slightly. Moreover, the tensile index, tear index and folding endurance were increased by 8%, 7% and 30%, respectively, but burst index showed no significant change. The above results illustrated that cellulase pretreatment was only beneficial to the dissolution of sugars and fine components from bagasse and it was an effective method of promoting alkali-oxygen pulping of bagasse.

scholarly journals Preparation and Application of Cationic Modified Cellulose Fibrils as a Papermaking Additive

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Yanhong Gao ◽  
Qun Li ◽  
Yu Shi ◽  
Ruitao Cha
Keyword(s):  
Zeta Potential ◽  
Chemical Properties ◽  
Cationic Starch ◽  
Physical Strength ◽  
Tensile Index ◽  
Tear Index ◽  
Colloid Titration ◽  
Cellulose Fibrils ◽  
Physical And Chemical ◽  
Modified Cellulose

This paper deals with cationic modified cellulose fibrils obtained by reacting the cellulose fibrils with 2,3-epoxypropyltrimethylammonium chloride (EPTMAC). The physical and chemical properties of unmodified cellulose fibrils (UMCF) and cationic modified cellulose fibrils (CMCF) were characterized by SEM, FTIR, degree of substitution, colloid titration, zeta potential, and thermogravimetric analysis. The experimental results showed that, after cationization, surface charge density and zeta potential reversed, thermal stability decreased, and new functional groups appeared, while the surface morphology did not show much difference from the UMCF. With the addition of three kinds of additives (UMCF, CMCF, and cationic starch (CS)) to BCTMP, the addition of UMCF and CMCF had little effect on zeta potential, while the addition of CS changed zeta potential obviously. With the increasing of additive amount, the bulk of paper sheets added CMCF did not change obviously, while the bulk of paper sheets added UMCF and CS decreased rapidly. With regard to physical strength, all the three kinds of additives could improve the tensile index and tear index; the tensile index of paper sheets added CS was higher than that of added UMCF and CMCF, while the tear index of paper sheets added CMCF was the highest among the three additives.

scholarly journals MODIFIKASI PERMUKAAN SERAT LBKP DAN HASIL DEINKING DENGAN KARBOKSIMETIL SELULOSA

2016 ◽  
Vol 2 (02) ◽  
Author(s):  
Sonny Kurnia Wirawan ◽  
Nina Elyani ◽  
Jenni Rismijana
Keyword(s):  
Physical Properties ◽  
Carboxymethyl Cellulose ◽  
Kraft Pulp ◽  
Fiber Strength ◽  
Fiber Quality ◽  
Strength Properties ◽  
Sem Analysis ◽  
Tensile Index ◽  
Bleached Kraft Pulp ◽  
Tear Index

The strength properties of paper are strongly affected by fiber quality. The objective of this study was to assess the effect of modification fiber by carboxymethylation of leaf bleached kraft pulp (LBKP) and deinked pulp (DIP) by using carboxymethyl cellulose (CMC). Carboxymethylation was carried out by addition of various concentration of CMC and cationic agent of CaCl2. Handsheets with 70 gsm were made from the stock, and the physical properties were tested as the tensile index, stretch, tensile energy absorption (TEA), tearing index, and bursting index as well as SEM analysis. The results showed that the highest increase of fiber strength of LBKP and DIP was achieved by addition of 1% CMC and 9.19% CaCl2. For LBKP, the increasing of tensile index was 18.1%, stretch 27%, TEA 30.2%, tear index 7,8 % and burst index 16,7%. Whereas for DIP, the increasing of tensile index reached 29.9%, stretch 22.2%, TEA 61.2%, tear index 20.7% and burst index 63.1%. From the results of SEM analysis showed that the addition of CMC and CaCl2 increased fiber bonding.Keywords: CMC, LBKP, DIP ABSTRAK Sifat kekuatan kertas sangat dipengaruhi oleh kualitas serat. Tujuan penelitian ini adalah untuk mengetahui pengaruh modifikasi serat kraft putih kayu daun (LBKP) dan serat hasil deinking (DIP) dengan karboksimetilasi menggunakan karboksimetil selulosa (CMC). Modifikasi secara karboksimetilasi dilakukan dengan variasi penambahan CMC dan sebagai cationic agent CaCl2. Lembaran dibuat dari stok dengan gramatur 70 gsm, kemudian dilakukan pengujian fisik dengan parameter indeks tarik, regang, TEA, indeks sobek dan indeks retak. Selain itu lembaran juga diuji morfologi dan SEM. Hasil penelitian menunjukan peningkatan kekuatan lembaran tertinggi dicapai oleh LBKP maupun DIP, pada kondisi penambahan 1% CMC and 9.19% CaCl2. Untuk LBKP peningkatan indeks tarik adalah 18,1%, regang 27%, TEA 30,2%, indeks sobek 7,8 % dan indeks retak 16,7%. Sedangkan untuk DIP, peningkatan indeks tarik mencapai 29,9%, regang 22,2%, TEA 61,2%, indeks sobek 20,7% dan indeks retak 63,1%. Hasil analisa SEM menunjukan bahwa dengan penambahan CMC dan CaCl2, mengakibatkan terjadi peningkatan ikatan antar serat.Kata kunci: CMC, LBKP, DIP

scholarly journals PERBAIKAN FREENESS DAN MUTU KERTAS BEKAS MENGGUNAKAN CELLULOSE BINDING DOMAIN DARI ENDOGLUKANASE Egl-II

2014 ◽  
Vol 4 (02) ◽  
Author(s):  
Rina Masriani ◽  
Taufan Hidayat ◽  
Henggar Hardiani
Keyword(s):  
Cellulose Degradation ◽  
Binding Domain ◽  
Waste Paper ◽  
Cellulose Binding Domain ◽  
Total Enzyme Activity ◽  
Tensile Index ◽  
Tear Index ◽  
Paper Fibers ◽  
Cellulose Binding ◽  
Total Enzyme

The objective of this research is improving the freeness of waste paper stock and paper quality by using the Cellulose Binding Domain (CBD) of endoglucanase Egl-II. CBD has been separated from endoglucanase Egl-II by proteolysis method. CBD has a molecular weight of approximately 21 kD. The produced CBD contained 0.04 mg / mL protein and did not show the total enzyme activity. Waste paper disintegrated using Niagara beater with no load at the consistency of 1.5%. CBD was applied to the refined waste paper fibers with a freeness of 200 mL CSF (Canadian Standard Freeness). The dosages of CBD used for waste paper treatment were 0.2 and 0.3 mg CBD/g of oven-dried pulp. The result shows that this treatment increases the freeness of fibers by 140 mL CSF (70%). CBD also increases the amount of removed water from the fibers from 290 mL to 390 mL and 370 mL, respectively, using the dynamic drainage jar (DDJ) measurement. The cellobiose assay of the waste paper filtrate treated with CBD shows no sugar dissolution, which indicates no cellulose degradation. The tear index of paper produced by treatment with CBD shows insignificant change. The Concora Medium Test (CMT) of paper produced by treatment with CBD has higher tensile index, burst index, and ring crush.Keywords: cellulose-binding domain, endoglucanase Egl-II, freeness improvement, waste paperABSTRAKTujuan penelitian ini adalah untuk memperbaiki freeness dari stok kertas bekas dan mutu lembaran kertas yang  dihasilkan dengan menggunakan Cellulose Binding Domain (CBD) dari endoglukanase Egl-II. CBD yang  digunakan merupakan hasil pemisahan dari endoglukanase Egl-II dengan metode proteolisis. CBD ini memiliki  berat molekul sekitar 21 kD. CBD yang dihasilkan mengandung kadar protein sebesar 0,04 mg/mL dan tidak  terdeteksi adanya aktivitas total enzim. Kertas bekas diuraikan dengan menggunakan Niagara beater tanpa  beban pada konsistensi 1,5%. CBD diaplikasikan pada serat kertas bekas yang telah digiling dan memiliki freeness 200 mL CSF (Canadian Standard Freeness). Dosis CBD yang digunakan untuk perlakuan terhadap serat kertas  bekas adalah 0,2 dan 0,3 mg CBD/g pulp kering-oven. Hasil penelitian menunjukkan perlakuan dengan CBD  meningkatkan freeness bubur serat kertas bekas sebesar 140 mL CSF (70%). CBD juga meningkatkan volume air yang dihilangkan dari serat kertas bekas dari 290 mL menjadi 390 mL dan 370 mL menggunakan pengukuran dynamic drainage jar (DDJ). %FPR meningkat dari 98,80% menjadi 99,77%. Pengujian selobiosa terlarut pada filtrat serat kertas bekas yang telah mengalami perlakuan dengan CBD memperlihatkan tidak ada gula terlarut, artinya tidak ada degradasi selulosa menjadi gula terlarut. Indeks sobek dari kertas yang dihasilkan melalui perlakuan dengan CBD memperlihatkan tidak ada perubahan yang signifikan. Nilai tensile index, burst index, ring crush dan Concora Medium Test (CMT) dari kertas yang dihasilkan melalui perlakuan dengan CBD meningkat.Kata kunci: cellulose-binding domain, endoglukanase Egl-II, perbaikan freeness, kertas bekas

scholarly journals THE EFFECT OF ORGANOSOLV TREATMENT ON THE PHYSICOCHEMICAL PROPERTIES OF PULP AND PAPER FROM HORSE GRASS (ANDROPOGON TECTORUM).

2020 ◽  
Vol 45 (6) ◽  
Author(s):  
O. Otitoju ◽  
A.O. Ashogbon
Keyword(s):  
Fiber Length ◽  
Fiber Diameter ◽  
Good Alternative ◽  
Strength Properties ◽  
Cooking Time ◽  
Pulp And Paper ◽  
Paper Strength ◽  
Ethanoic Acid ◽  
Tear Index ◽  
Alternative Sources

The delignification of horse grass (HG) was carried out using methanol and water (organosolv pulping); varying the cooking conditions at 30min, 60min and 90min with ratios: 1:1, 1:2 and 1:3, Methanol-water, cooked in autoclave at 1050C. The pulp obtained were selected and macerated in equal volume of glacial acetic acid (ethanoic acid) and hydrogen peroxide (1:1) at a temperature 1000C, to investigate the fiber length; fiber diameter; lumen with their derived indices and paper strength properties was determined according to TAPPI standard methods, T 494 om-96. The best fiber length of 3.21mm, tear index 31.43 mN.m2/g, tensile index 97.79Nm/g and bulk index 5.15 kPa.m2/g was obtained at 1:3 methanol: H2O at 105°C with cooking time of 60 min. Therefore, it was established that high quality papers of different grades can be produced from horse grass with acceptable strength properties using low concentration of methanol/water pulping with moderate time at boiling temperature. The research concluded that methanol-water was excellently good for pulping of horse grass fibers. The above results showed that horse grass is a good alternative sources of fibers to produce pulp and paper.

Sign in / Sign up

Export Citation Format

Share Document