LIMBAH KAYU DAN KERTAS BEKAS UNTUK PULP KERTAS

His study aims to analyze the extent to which a mixture of wood waste and used newsprint can be used as raw material for making paper.This study used a completely randomized design with two replications. where the treatment given is a mixture composition between waste wood pulp and old newsprint pulp, each consisting of 0 : 100% (A), 30% 70% (B), 50% : 50% (C), 70% : 30% (D) and 100% : 0% (E) of oven-dry weight of pulp per sheet of paperThe physical properties of paper pulp tested in the form of tear index, tensile index, crack index and folding resistance significantly affect the composition of the mixture of wood waste and used newsprint.The value of tear index, tensile index and folding resistance tend to decrease with the increase in the percentage of used newsprint to the composition of the mixture, while the value of the crack index increases. Wood waste and used newsprint can be used as raw materials in pulp and paper manufacture, especially in the treatment of mixed composition C (50%:50%.)

The Influence of Pulping Process and Energy Consumption on Properties of Nanofibrillated Lignocellulose (NFLC) Films Isolated from Wheat Straw

The present research has primarily focused on the production of nanofibrillated lignocellulose (NFLC) instead of nanofibrillated cellulose (NFC), which could be produced with less energy and is expected to have similar uses as NFC, especially in the sectors where the transparency is not important. Furthermore, the effect of energy consumption needed for NFLC production and also the influence of pulping methods on the produced NFLC properties has been surveyed. Through mechanical refining and different passes in microfluidizer, the results showed the average diameter of NFLC declined from around 19000 nm to 36 nm. Soda-NFLC films had higher calliper and lower roughness, compared to those of MEA at given energy consumption in refiner and microfluidizer. For both kinds of pulps, the optimum level of energy consumption to reach the best tensile index of NFLC films was 258 kWh/t, with three passes through microfluidizer. More increase in the number of passes and pressure only resulted in increasing of energy consumption without any positive effect on improving the tensile index. The maximum tensile indices of NFLC films obtained from soda and MEA pulping processes were 113.5 and 119.86 N·m/g, respectively. The burst index of 8.5 kP·m2/g and the energy consumption of 458 kWh/t were obtained for five passes through microfluidizer. With the increase of the number of passes of soda and MEA samples through microfluidizer, the opacity decreased but transparency increased.

Eco-Friendly Rice Straw Paper Coated with Longan (Dimocarpus Longan) Peel Extract as Bio-Based and Antibacterial Packaging

This study aimed to develop active paper from rice straw fibers with its function as antibacterial activity obtained from longan (Dimocarpus longan) peels. The morphology and mechanical properties of fibers of rice straw were examined as quality parameters for paper production. Rice straw paper (RSP) with basis weight ca 106.42 g/m2, 0.34 mm thickness, 34.15% brightness, and 32.26 N·m/g tensile index was successfully prepared from fibers and pulps without chemical bleaching process. Bioactive compounds of longan peels were extracted using maceration technique with a mixture of ethanol-water, and subsequently coated onto RSP at concentration of 10%, 15% and 20% (w/v). Fourier transform infrared (FTIR) spectroscopic analysis demonstrated the functional groups of phytochemicals in the peel extract. The results of physical properties showed that the coated RSP had similar thickness and tensile index, but had lower brightness compared to control papers. Scanning electron microscopy (SEM) confirmed the significantly different of surface and cross-section structures between coated and uncoated RSP. The coated RSP had relatively greater barrier properties to prevent water absorption. In addition, the RSP coated with longan peel extracts showed significant antibacterial activity against foodborne bacteria, Staphylococcus aureus and Bacillus cereus. This study reveals the benefits of natural byproducts as potential materials for active packaging prepared by environmentally friendly processes.

Optimization of Technological Parameters of Straw Fiber-Based Plant Fiber Seedling Pot Raw Materials

Straw fiber seedling pots are a promising substitute for plastic seedling pots. The mixing mode of straw fiber affects the mechanical properties of the raw material membrane of the seedling pot. To explore the processing technology of making the raw material membrane of the seedling pot with two kinds of plant fibers in a layered manner, the optimal combination of the process parameters of the raw material membrane of the seedling pot without additives in the production process was studied experimentally. Response surface methodology (RSM) was used to analyze the parameters (beating degree of unbleached softwood kraft pulp fiber, beating degree of wheat straw fiber, wheat straw fiber quality percentage content, and film grammage) with regard to the dry tensile index and Z-direction tensile index of the seedling pot body. The optimal process parameter combination with a certain dry tensile index and Z-direction tensile index of seedling pot raw material was obtained by using four factors and five levels of a quadratic regression orthogonal rotation center combination design parameter optimization experiment. The optimal technical parameters were optimized as wheat straw fiber quality percentage content 70%, film grammage 70 g/m2, unbleached softwood kraft pulp fiber beating degree 47–48 °SR, and wheat straw fiber beating degree 65–75 °SR. With the optimal conditions, the dry tensile index of the seedling bowl raw material film was between 21 and 22 N·(m·g−1), and the Z-direction tensile index was greater than 2.1 N·(m·g−1). Using wheat straw fibers and unbleached sulfite wood pulp fibers as raw materials for seedling pots, the raw material membrane of the seedling pots was made in a layered manner. The experimental study proved this feasibility. With this mixing process of raw materials, the straw fiber-based plant fiber seedling pot would meet the demands of a crop nursery after adding chemical additives. The research results provide a theoretical basis and technical support for the manufacture of the raw material membrane of the seedling pot body.

EFFECT OF ADDITION OF DEINKED PULP TO BLEACHED KRAFT PULP ON TISSUE PAPER PROPERTIES

The influence of addition of deinked pulps with low and high brightness to bleached eucalyptus and pine kraft pulps on functional tissue paper properties was studied. Deinked pulps with low and high brightness had some different functional properties. Deinked pulp with high brightness has higher bulk, porosity, water absorption after immersion, initial water absorption, bulk softness as well as brightness. On the contrary, the difference in relative bonded area and porosity e between deinked pulps with low and high brightness was moderate. The mixed pulps laboratory pulp sheets from bleached eucalyptus kraft pulp or bleached pine kraft pulp with addition of 20, 40 and 80% of deinked pulp with low brightness or deinked pulp with high brightness were prepared. The addition of the deinked pulp with high or low brightness to bleached kraft pulp leads to increasing of bulk, bulk softness as well as high water absorption after immersion and initial water absorption. The tensile index rapidly decreased by the addition of deinked pulps with high brightness to bleached eucalyptus and pine kraft pulps. Similarly, the addition of deinked pulp with low brightness to bleached pine kraft pulp led to rapid decreasing of tensile index. On contrary, with the addition of deinked pulp with low brightness to eucalyptus kraft pulp, the decreasing of tensile index was less pronounced. Mixed pulp from bleached eucalyptus kraft pulp with a small content of deinked pulp with low brightness with functional properties suitable for production of tissue papers was found as optimal.

Biorefining: the role of endoglucanases in refining of cellulose fibers

With an annual production of more than 400 million tons, paper is the main product of the largest biorefinery process industrially implemented. Enzymes have been used for pulp refining to dramatically reduce energy consumption. However, exact mechanisms related to the individual enzymes are hardly understood. Yet, this knowledge would be important to predict enzyme performance in industrial processes. Three commercial refining enzyme formulations showed different endoglucanase (1.25 nkat mg−1–13.7 nkat mg−1), β-glucosidase (0.57 nkat mg−1–1.34 nkat mg−1) and xylanase activities (1.78 nkat ml−1–62.1 nkat mg−1) on model substrates. Additionally, distinct amounts of reducing sugars from hardwood sulfate pulp were released. Endoglucases were purified from each formulation by using hydrophobic interaction and anion exchange chromatography and showed molecular weights from 20 to 55 kDa and specific activities ranging between 3.11 and 26.3 nkat mg−1 according to endoglucanase specific derivatized cellopentaose (CellG5). Refining trials of hardwood sulfate pulp were conducted using a PFI laboratory mill and fiber properties such as degree of refining or fiber length and properties of formed sheets like tensile index were monitored. Thereby, enzymes were dosed based on identical endoglucanase activity on CellG5. Enzyme formulations and purified endoglucanases led to an increase of the degree of refining of up to 47.9 [°SR] at 6000 PFI revolutions while the tensile index was improved by up to 76.0 Nm g−1. In summary, refining effects can be primarily attributed to endoglucanases indicating activity on CellG5 being a suitable parameter for enzyme dosing.

Mapping variation of handsheet properties within loblolly pine trees

Within-tree variation of four handsheet properties (burst index, sheet density, STFI short-span compression strength (STFI) and tensile index) was mapped for loblolly pine trees aged 13 and 22 years using NIR predicted handsheet property data (representing an average of 18 trees for each age). All within-tree maps were similar demonstrating a radial decrease in handsheet properties at all heights, with sheet density and tensile index having the greatest within-tree variation. The corewood zone had the highest values for all properties, while the lowest values were observed in a region consistent with juvenile and transitional outerwood as defined by Burdon et al. (2004). The maps are also similar to, but the inverse of, maps reported in prior studies for density and tracheid coarseness and wall thickness. Relationships amongst the examined handsheet properties and wood and tracheid properties explains the overall similarities of the different maps. The maps provide a representation of within-tree variation of important paper properties at two different ages. An understanding of how these properties vary within loblolly pine trees can aid in better utilization of forest resources.

Dynamic-head space GC-MS analysis of volatile odorous compounds generated from unbleached and bleached pulps and effects on strength properties during ageing

Mixed hardwood unbleached (UB) and final bleached (FB) pulp along with the pulp of intermediate bleaching stages from an integrated paper mill have been undertaken for this study. Headspace GC-MS analysis of these pulps was made to identify the odorous compounds which are volatile organic compounds (VOCs), generated during ageing for 60 days. The result showed that a number of pre-generated VOCs such as aliphatic hydrocarbons and aldehydes are observed in the pulp sample which might be came from the process and it has been observed that upon ageing at ambient conditions, some acid functionalized VOC were generated in the pulp. The generation of these VOCs were established by ATR-FTIR analysis and the results showed that intensity of peak absorbance near 3340 cm − 1 {\text{cm}^{-1}} and 1641 cm − 1 {\text{cm}^{-1}} which represents the –OH stretching of acidic functional group and C=O stretch of aldehyde and acidic functional groups increased after ageing. Generation of acid functionalized volatile compounds were observed more in bleached pulp than in unbleached pulp. Degree of polymerization (DP) is pretty much related to the strength of paper. DP of both unbleached and bleached pulp gets reduced upon ageing while more reduction were observed in bleached pulp. Bleached pulps are more prone to degrade as compared to the unbleached pulp in terms of strength properties such as tensile index, breaking length, burst and double fold were observed. 12.3 % and 21.8 % reduction in tensile index was observed for UB and final bleached FB pulp respectively. Burst index of UB and FB pulp were found reduced to 23.8 % and 41.9 % respectively due to ageing. Reduction in the mechanical and optical properties was also observed in intermediate bleaching stages. There is much evidence for the contribution of VOCs to the degradation of paper. The results are strongly suggested that acid functionalized volatile compounds can have strong effects on degradation of cellulosic paper.

Optimization of wheat straw pretreatment process parameters for straw mulch mat

Straw mulch mat is a promising alternative to petroleum-based plastic mulching film. The straw pretreatment process parameters influence the mechanical properties of the mat. To explore the effect of pretreatment process parameters on physical properties of wheat straw mulch mat, a five-factor and five-level central composite design (CCD) methodology was studied. With response surface methodology (RSM) analysis, the effects of parameters (soaking water temperature, soaking time, processing speed, manufacturing temperature, and manufacturing pressure) on dry tensile index and wet tensile index of original film, and initial beating degree of the straw pulp were reported. The optimal technical parameters were optimized as soaking water temperature 90 °C, soaking time 1.5 h, manufacturing pressure 1.5 MPa, processing speed 83.5 to 87.8 r/min, and manufacturing temperature 95 to 100 °C. With the optimal condition, the dry tensile index, wet tensile index, and initial beating degree were higher than 8 N·m/g, 4 N·m/g, and 17 °SR, respectively. With this pretreatment of raw materials, the wheat straw mulch mat would meet the demands of mechanical properties for agriculture mulching after adding chemical additives.

Effect of nanofibrillated cellulose made from enzyme-pretreated bamboo pulp on paper strength

The applicability of bleached bamboo kraft pulp (Ba-BKP) was explored as a raw material for the manufacture of nanofibrillated cellulose (EN-NFC) made of enzyme-pretreated pulps and the effects of the EN-NFC on enhancing paper strength. The Ba-BKP was pretreated using an endo-glucanase enzyme at 50 °C and pH 6, after which the EN-NFC was made by micro-grinding. Bleached hardwood kraft pulp (Hw-BKP) was used as a control, and the non-enzymatic refining pretreatment of BKPs was compared with the enzyme pretreatment. The EN-NFC was incorporated into handsheets, and the sheet strengths were measured. The physical properties of the NFC made from the Ba-BKP were similar to those made from the Hw-BKP. The NFC prepared following enzyme pretreatment were smaller and more uniform than those pretreated with refining. The EN-NFC made from the Ba-BKP was effective at enhancing tensile index by 52.7%, and burst index by 210.2% when 2% of EN-NFC was added in the furnish, and those of handsheets containing the EN-NFC made from Hw-BKP showed the similar improvement. Therefore, Ba-BKP can be used as a raw material for the manufacture of EN-NFC that confers similar physical properties and strength enhancement to paper as those made from Hw-BKP.