Effect of Process Parameters on the Adsorption of Chromium VI on a Packed Bed Column (PBC) using Vetiver (Vetiveria zizanioides)

2021 ◽  
Vol 25 (12) ◽  
pp. 53-59
Author(s):  
Pejavara Narayana Gururaj ◽  
Kulathooran Ramalakshmi ◽  
Sureshkumar Sujithra ◽  
Ravichandran Shalini

The objective of this study is to evaluate the different process parameters on adsorption of chromium VI on a packed bed column using Vetiver (Vetiveria zizanioides) and to examine the effect of pH, Chemical Oxygen Demand (COD) and Biological Oxygen Demand (BOD) at a constant contact time of 10 minutes at a temperature of 40 ºC under two experimental conditions namely, tannery effluent with and without microwave treatment. The results revealed that microwave heating process had a higher impact on chromium (VI) adsorption than normal heating process. The pH values of microwave treated sample were found to be 6.65±0.65 when compared to normal heated sample where the pH was 4.62±0.72 when compared to the initial pH of effluent found to be 3.47±0.58. Further, a threefold reduction in BOD and COD values was observed in microwave treated vetiver sample which was around 86.73±1.43 and 107.90±2.82 mg/l respectively when compared to normal heated sample (250±1.45 and 200±2.65 mg/l respectively) and untreated effluent (780±2.53 and 920±3.86 mg/l respectively) which indicated the reduction of chromium VI present in the effluent water. It was also observed that the metal adsorption capacity of the vetiver powder and the adsorption characteristics were positively correlated with the FTIR and SEM analysis which confirmed the presence of chromium (VI) on the surface of vetiver.

2008 ◽  
Vol 99 (8) ◽  
pp. 3094-3099 ◽  
Author(s):  
M.G.A. Vieira ◽  
R.M. Oisiovici ◽  
M.L. Gimenes ◽  
M.G.C. Silva

2020 ◽  
Vol 8 (3) ◽  
pp. 8-13
Author(s):  
K. Thirugnanasambandham

Global warming due to greenhouse gases has become a serious global issue. Extensive efforts are being made to fighting this phenomenon through carbon capture as carbon dioxide (CO2) is its major contributor. This study focused on CO2 capture in packed bed column reactor using Poly-(D) glucosamine under the various process parameters such as temperature, feed flow rate and mass of the adsorbent. Statistical design of experiments was carried out in order to analysis the effect process parameters on the capacity of CO2 capture in packed bed column. The obtained results show that feed flow rate has the significant affect compared to others. The maximum of 956 mg of CO2 is captured under the following operating conditions; temperature of 40oC, feed flow rate of 30 ml/min and 0.25 g of the Poly-(D) glucosamine. The ability of Poly-(D) glucosamine to capture the CO2 in packed bed column is confirmed.


Author(s):  
Candelaria Nahir Tejada-Tovar ◽  
Angel Villabona-Ortíz ◽  
Rodrigo Ortega Toro

The present work aimed to evaluate the effect of temperature, particle size and bed height of the chromium (VI) adsorption process using plantain peels in a continuous system. The experiment was carried out on a packed bed column, adjusting the feed temperature of the solution with a REX-C100 controller coupled to a type K thermocouple. The initial concentration of Cr (VI) was set at 100 ppm, the pH at 2 and the feed rate of 0.75 mL/s. The analyses were performed by UV-Vis spectroscopy using the colourimetric method of 1.5-diphenylcarbazide. The material was characterized by infrared spectrometry by Fourier Transforms (FTIR), from this analysis, it was determined that the OH and NH2 functional groups are the main responsible for the formation of complexes with the cations in solution. Also, it was established that only the particle size is statistically significant. According to the response surface analysis, the optimum conditions of the process were 353.15 K, a particle size of 0.819 mm and a bed height of 67.768 mm. From the thermodynamic study of the process, it is established that it is endothermic and the chemical adsorption prevails in it. The results obtained in the process modelling suggest that Dose-Response can be used reliably to scale the process.


2015 ◽  
Vol 5 (4) ◽  
pp. 505-515 ◽  
Author(s):  
Kannan Radhakrishnan ◽  
Prabhakar Sivaraman ◽  
Wilson Richard Thilagaraj

The present study was investigated to find the efficiency of a hybrid process of an ecofriendly dehydrated Moringa oleifera biosorbent beads (DMB) and ultrafiltration (UF) membrane to remove organic pollutants from actual textile effluents. Experiments were conducted with a packed bed column (PBC) for the removal of dyes using various parameters such as flow rate, material mass and size of the biosorbent. The optimized biosorption process was then combined with a dead-end UF process for the removal of chemical oxygen demand/biochemical oxygen demand (COD/BOD) and turbidity. Three strategies were adopted by varying the sequences of UF and PBC. PBC followed by the UF process appears to be more effective for the removal of color (>99%), COD (90–93%) and turbidity (>95%), when compared to UF followed by the PBC process and the UF membrane alone. The results suggested that the treated effluent could be reused in industries for various purposes such as floor cleaning, gardening, etc.


2020 ◽  
Vol 8 (3) ◽  
pp. 1-7
Author(s):  
Aya Ayad Hussein ◽  
Rajaaaldeen Abd Khalid

Global warming due to greenhouse gases has become a serious global issue. Extensive efforts are being made to fighting this phenomenon through carbon capture as carbon dioxide (CO2) is its major contributor. This study focused on CO2 capture in packed bed column reactor using Poly-(D) glucosamine under the various process parameters such as temperature, feed flow rate and mass of the adsorbent. Statistical design of experiments was carried out in order to analysis the effect process parameters on the capacity of CO2 capture in packed bed column. The obtained results show that feed flow rate has the significant affect compared to others. The maximum of 956 mg of CO2 is captured under the following operating conditions; temperature of 40oC, feed flow rate of 30 ml/min and 0.25 g of the Poly-(D) glucosamine. The ability of Poly-(D) glucosamine to capture the CO2 in packed bed column is confirmed.


1986 ◽  
Vol 51 (6) ◽  
pp. 1222-1239 ◽  
Author(s):  
Pavel Moravec ◽  
Vladimír Staněk

Expression have been derived in the paper for all four possible transfer functions between the inlet and the outlet gas and liquid steams under the counter-current absorption of a poorly soluble gas in a packed bed column. The transfer functions have been derived for the axially dispersed model with stagnant zone in the liquid phase and the axially dispersed model for the gas phase with interfacial transport of a gaseous component (PDE - AD). calculations with practical values of parameters suggest that only two of these transfer functions are applicable for experimental data evaluation.


1982 ◽  
Vol 47 (10) ◽  
pp. 2639-2653 ◽  
Author(s):  
Pavel Moravec ◽  
Vladimír Staněk

Expressions have been derived for four possible transfer functions of a model of physical absorption of a poorly soluble gas in a packed bed column. The model has been based on axially dispersed flow of gas, plug flow of liquid through stagnant and dynamic regions and interfacial transport of the absorbed component. The obtained transfer functions have been transformed into the frequency domain and their amplitude ratios and phase lags have been evaluated using the complex arithmetic feature of the EC-1033 computer. Two of the derived transfer functions have been found directly applicable for processing of experimental data. Of the remaining two one is useable with the limitations to absorption on a shallow layer of packing, the other is entirely worthless for the case of poorly soluble gases.


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