scholarly journals Heterogeneous Catalytic Conversion of Citronellal into Isopulegol and Menthol: Literature Review

2021 ◽  
Vol 6 (3) ◽  
pp. 166-180
Author(s):  
Amri Yahya ◽  
Dwiarso Rubiyanto ◽  
Is Fatimah
Keyword(s):  
Literature Review ◽  
Heterogeneous Catalyst ◽  
Active Site ◽  
Adsorption Mechanism ◽  
Low Cost ◽  
Cyclization Reactions ◽  
One Pot ◽  
Heterogeneous Catalytic ◽  
Active Metal ◽  
The One

The conversion of citronellal into isopulegol is a key route in the production of a number of important chemicals. In the perspective of green conversion, the use of a heterogeneous catalyst is superior due to its ease in separation and reusability, so it facilitates a highly economical conversion. In this review, we examine the use of some transition metals in cyclization reactions, which are suitable for citronellal conversion into isopulegol, and consider the potential progress in clay-based catalysts. The structure of clay which potentially provides the porosity by modification and supporting active metal is proposed to be the low-cost catalyst for the conversion. As other mechanism by porous materials-supported metal, the porosity of clay support contributes to conduct thesurface adsorption mechanism and the Broensted acid supply, meanwhile the metal acts as active site for cyclization, and in the one-pot conversion into menthol, as both cyclization and hydrogenation.

Rapid and Green One-Pot Synthesis of Novel 2-(4-Hydroxy-2-oxo-2H-chromen-3-yl)-2-(arylamino)-1H-indene-1,3(2H)-diones

2021 ◽  
Vol 18 ◽  
Author(s):  
Abolfazl Olyaei ◽  
Zahra Ghahremany ◽  
Madieh Sadeghpour
Keyword(s):  
Aromatic Amines ◽  
Low Cost ◽  
Guanidine Hydrochloride ◽  
Reaction Times ◽  
Solvent Free ◽  
One Pot ◽  
Solvent Free Conditions ◽  
The One ◽  
High Yields ◽  
Work Up

: A green and efficient protocol was developed for the one-pot three-component synthesis of novel 2-(4-hydroxy-2-oxo-2H-chromen-3-yl)-2-(arylamino)-1H-indene-1,3(2H)-dione derivatives by the reaction of 4-hydroxycoumarin, ninhydrin and aromatic amines in the presence of guanidine hydrochloride as an organocatalyst under solvent-free conditions. The present approach offers several advantages such as low cost, simple work-up, short reaction times, chromatography-free purification, high yields and greener conditions.

Sulfated Tin Oxide: A Convenient Heterogeneous Catalyst for the Synthesis of 4-Arylmethylidene-3-substituted-isoxazol-5(4H)-ones

2021 ◽  
Vol 18 ◽  
Author(s):  
Nitishkumar S. Kaminwar ◽  
Sunil U. Tekale ◽  
Srinivas L. Nakkalwar ◽  
Rajendra P. Pawar
Keyword(s):  
Heterogeneous Catalyst ◽  
Tin Oxide ◽  
Heterocyclic Compounds ◽  
Biological Activities ◽  
Hydroxylamine Hydrochloride ◽  
One Pot ◽  
Easy Method ◽  
Three Component Reaction ◽  
Wide Range ◽  
The One

: Synthesis of isoxazole structural heterocyclic compounds is important due to their wide range of biological activities. In the present article, we report a convenient and easy method for the synthesis of 4-arylmethylidene-3-substituted-isoxazol-5(4H)-ones by the one-pot three-component reaction of aldehydes, β-keto ester, and hydroxylamine hydrochloride cat-alyzed by sulfated tin oxide as a heterogeneous catalyst.

scholarly journals New fast “One-pot” Technique for the Production of Glycyrrhetinic Acid from the Roots of licorice (Glycyrrhiza glabra)

2018 ◽  
Vol 13 (7) ◽  
pp. 1934578X1801300
Author(s):  
Anna V. Lekar ◽  
Sergey N. Borisenko ◽  
Elena V. Vetrova ◽  
Elena V. Maksimenko ◽  
Salima S. Khizrieva ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Subcritical Water ◽  
Low Cost ◽  
Glycyrrhetinic Acid ◽  
Glycyrrhiza Glabra ◽  
One Pot ◽  
Glycyrrhiza Glabra L ◽  
The One ◽  
Toxic Organic Solvents ◽  
Pot Technique

The aim of this work was to develop and study a fast “one-pot” procedure for the production of glycyrrhetinic acid (GLA) from the roots of licorice ( Glycyrrhiza glabra L.) using subcritical water (SBW). Technique requires no use expensive and toxic organic solvents. For the first time the new method was used for the production of glycyrrhetinic acid (aglycone of glycyrrhizic acid) by “one-pot” technique. HPLC was used to determine the quantitative compositions of the obtained products. It has been shown that variation of only one parameter of the process (temperature) allows alteration of composition of the products obtained by new “one-pot” technique. The “one-pot” procedure developed for the production of GLA in SBW is faster (12 folds) than conventional methods that use expensive and toxic organic solvents. The proposed procedure has the excellent potential for the future development of the fast and low cost technologies for the production of GLA and its derivatives in the pharmaceutical, food and cosmetic industries.

scholarly journals Efficient Cu-catalyzed base-free C–S coupling under conventional and microwave heating. A simple access to S-heterocycles and sulfides

2013 ◽  
Vol 9 ◽  
pp. 467-475 ◽  
Author(s):  
Silvia M Soria-Castro ◽  
Alicia B Peñéñory
Keyword(s):  
Microwave Irradiation ◽  
Microwave Heating ◽  
Catalytic System ◽  
Low Cost ◽  
One Pot ◽  
Alkyl Aryl ◽  
One Pot Synthesis ◽  
Aryl Iodides ◽  
The One ◽  
Aryl Sulfides

S-aryl thioacetates can be prepared by reaction of inexpensive potassium thioacetate with both electron-rich and electron-poor aryl iodides under a base-free copper/ligand catalytic system. CuI as copper source affords S-aryl thioacetates in good to excellent yields, by using 1,10-phenanthroline as a ligand in toluene at 100 °C after 24 h. Under microwave irradiation the time was drastically reduced to 2 h. Both procedures are simple and involve a low-cost catalytic system. This methodology was also applied to the “one-pot” synthesis of target heterocycles, such as 3H-benzo[c][1,2]dithiol-3-one and 2-methylbenzothiazole, alkyl aryl sulfides, diaryl disulfides and asymmetric diaryl sulfides in good yields.

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