Ana C. Fernandes of the Instituto Superior Técnico, Lisboa, devised (Tetrahedron Lett. 2010, 51, 1048) an effective Re catalyst for the solvent-free hydrogenation of an alkene 1. Yasushi Imada and Takeshi Naota of Osaka University showed (Organic Lett. 2010, 12, 32) that a flavin could catalyze the hydrogenation of an alkene 3. Note that the thioether was stable under these conditions. Huanfeng Jian of the South China University of Technology developed (J. Org. Chem. 2010, 75, 2321) a Pd-based protocol for the oxidative cleavage of an alkene 5. The cleavage could be halted at the cis diol. K. C. Nicolaou of Scripps/La Jolla optimized (Organic Lett. 2010, 12, 1552) a complemetary cleavage of an alkene 7, again proceeding via the diol. J. R. Falck of UT Southwestern established (J. Org. Chem. 2010, 75, 1701) the Heck-type oxidative silylation of an alkene 9 to the Z -silane 10. Timothy F. Jamison of MIT effected (Chem. Commun. 2010, 46, 907) the borylation of an alkene 11. Kálmán Szabó of Stockholm University reported (Angew. Chem. Int. Ed. 2010, 49, 4051) a complementary approach for effecting the same transformation. Cathleen M. Crudden of Queen’s University, Kingston, observed (J. Am. Chem. Soc. 2010, 132, 131) that Rh-catalyzed hydroboration of 13 delivered the borane 14. Tehshik P. Yoon of the University of Wisconsin used (J. Am. Chem. Soc. 2010, 132, 4570) Fe to catalyze the addition of an oxaziridine 16 to an alkene 15. Yasuhiro Shiraishi of Osaka University improved (J. Org. Chem. 2010, 75, 1450) the photochemical addition of acetone to an alkene 18. Chul-Ho Jun of Yonsei University described (Tetrahedron Lett. 2010, 51, 160) a related procedure. Professor Jamison effected (J. Am. Chem. Soc. 2010, 132, 6880) the branching homologation of an alkene to give 21 . F. Dean Toste of the University of California, Berkeley, accomplished (J. Am. Chem. Soc. 2010, 132, 8885) the oxidative homologation of an alkene to the ester 22. Markus R. Heinrich of the Universität Erlangen-Nürnberg developed (Tetrahedron Lett. 2010, 51, 1758) the tandem addition of the hydroperoxide 23 and a diazonium salt 24, leading to 25.