scholarly journals Software development for calculating concentration in a buffer to the preparation of background electrolyte in the analytical method of capillary electrophoresis

2021 ◽  
Vol 63 (11) ◽  
pp. 29-34
Author(s):  
Thanh Dam Nguyen ◽  
◽  
Thi Phuc Nguyen ◽  
Minh Tuan Vu ◽  
◽  
...  
Keyword(s):  
Capillary Electrophoresis ◽  
Ionic Strength ◽  
Software Development ◽  
Analytical Method ◽  
Approximate Calculation ◽  
Background Electrolyte ◽  
C Language ◽  
Ph Adjustment ◽  
Ph Values ◽  
Acids And Bases

pH buffers of weak organic acids and bases are essential in capillary electrophoresis (CE) analyses, primarily when contactless conductivity detectors (C4D) are used. However, the preparation of a buffer with a known concentration of one component for use as a background electrolyte (BGE) in CE-C4D usually requires a pH adjustment to the desired value and an approximate calculation to estimate the concentration of the second component. This study developed software that allowed determining the concentration of one component when knowing the concentration of another component and the pH of the solution, taking into account the influence of ionic strength. The software was built in C# language with Windows Form interface on Microsoft Visual Studio. With the concentrations calculated from the developed software, the differences (|ΔpH|) between pH values of the obtained BGEs in practice and the desired values were smaller than 0.07, corresponding to the errors of less than 2%.

Effects of pH and ionic strength on the cation exchange capacity of soils with variable charge

Soil Research ◽  
1981 ◽  
Vol 19 (1) ◽  
pp. 93 ◽  
Author(s):  
GP Gillman
Keyword(s):  
Ionic Strength ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Surface Soils ◽  
Ph Values ◽  
Variable Charge ◽  
Effects Of Ph ◽  
Variable Charge Soils

The cation exchange capacity of six surface soils from north Queensland and Hawaii has been measured over a range of pH values (4-6) and ionic strength values (0.003-0.05). The results show that for variable charge soils, modest changes in electrolyte ionic strength are as important in their effect on caton exchange capacity as are changes in pH values.

scholarly journals Comparative Analysis on Dielectric Gold and Aluminium Triangular Junctions: Impact of Ionic Strength and Background Electrolyte by pH Variations

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Iswary Letchumanan ◽  
M. K. Md Arshad ◽  
Subash C. B. Gopinath ◽  
R. D. A. A. Rajapaksha ◽  
S. R. Balakrishnan
Keyword(s):  
Comparative Analysis ◽  
Ionic Strength ◽  
Background Electrolyte ◽  
Ph Variations

scholarly journals Compositional and Temperature Effects on the Rheological Properties of Polyelectrolyte–Surfactant Hydrogels

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 927 ◽  
Author(s):  
Jiří Smilek ◽  
Sabína Jarábková ◽  
Tomáš Velcer ◽  
Miloslav Pekař
Keyword(s):  
Ionic Strength ◽  
Rheological Properties ◽  
Surfactant Concentration ◽  
Background Electrolyte ◽  
Effect Of Temperature ◽  
Physical Interactions ◽  
Chain Conformations ◽  
Oppositely Charged ◽  
Electrolyte Ph ◽  
Positively Charged

The rheological properties of hydrogels prepared by physical interactions between oppositely charged polyelectrolyte and surfactant in micellar form were studied. Specifically, hyaluronan was employed as a negatively charged polyelectrolyte and Septonex (carbethopendecinium bromide) as a cationic surfactant. Amino-modified dextran was used as a positively charged polyelectrolyte interacting with sodium dodecylsulphate as an anionic surfactant. The effects of the preparation method, surfactant concentration, ionic strength (the concentration of NaCl background electrolyte), pH (buffers), multivalent cations, and elevated temperature on the properties were investigated. The formation of gels required an optimum ionic strength (set by the NaCl solution), ranging from 0.15–0.3 M regardless of the type of hydrogel system and surfactant concentration. The other compositional effects and the effect of temperature were dependent on the polyelectrolyte type or its molecular weight. General differences between the behaviour of hyaluronan-based and cationized dextran-based materials were attributed to differences in the chain conformations of the two biopolymers and in the accessibility of their charged groups.

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