Laboratory studies of the oil-displacing capacity of multifunctional chemical composition based on surfactants

2021 ◽  
pp. 136-146
Author(s):  
V. V. Kozlov ◽  
L. K. Altunina ◽  
L. A. Stasyeva ◽  
U. V. Chernova ◽  
M. R. Sholidodov
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Strong Acid ◽  
High Viscosity ◽  
Buffer System ◽  
Chemical Compositions ◽  
Inorganic Acid ◽  
Aluminum Salts ◽  
Oil Displacement ◽  
Heterogeneous Formation

The development of deposits of hard-to-recover reserves, including heavy and high-viscosity oil, dictates the need to search for new and improve existing enhanced oil recovery methods. One of the well-known methods of increasing oil recovery is the use of reservoir treatments with chemical compositions containing surfactants. A new multifunctional chemical oil-displacing composition (MFC) capable of operating in a wide temperature range has been created at the Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences. The oil-displacing composition of MFC based on a surfactant, an adduct of inorganic acid, polyol, ammonium and aluminum salts, and urea is designed to increase the oil recovery of fields at both early and late stages of development.The article presents the results of laboratory tests of the developed MFC for enhanced oil recovery. Experiments were carried out on the setup to study the filtration characteristics of models of heterogeneous formation.As a result of experiments, it was found that the use of the MFC composition leads to a significant increase in the oil displacement coefficient at both low and high temperatures. The high oil-displacing capacity of MFC at low temperature is caused by the interaction of inorganic acid and polyol, which are part of the composition, with the formation of a strong acid that reacts with the carbonate rock of the reservoir. At high temperature, due to the processes of hydrolysis of urea and aluminum salt, MFC evolves into an alkaline composition with the formation of an alkaline buffer system (pH = 9), which is optimal for oil displacement purposes.

scholarly journals Enhanced oil recovery from high-viscosity oil deposits by acid systems based on surfactants, coordining solvents and complex compounds

Georesursy ◽  
2019 ◽  
Vol 21 (4) ◽  
pp. 103-113 ◽  
Author(s):  
Lyubov K. Altunina ◽  
Vladimir A. Kuvshinov ◽  
Lyubov A. Stasyeva ◽  
Ivan V. Kuvshinov
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
High Viscosity ◽  
Complex Compounds ◽  
Natural Mode ◽  
Inorganic Acid ◽  
Acid Oil ◽  
Oil Displacement ◽  
Oil Deposits ◽  
High Viscosity Oil

Physicochemical aspects of enhanced oil recovery (EOR) from heavy high-viscosity deposits, developed in natural mode and combined with thermal methods, using systems based on surface-active substances (surfactants), coordinating solvents and complex compounds are considered, which chemically evolve in situ to acquire colloidal-chemical properties that are optimal for oil displacement. Thermobaric reservoir conditions, interactions with reservoir rock and fluids are the factors causing the chemical evolution of the systems. To enhance oil recovery and intensify the development of high-viscosity deposits, acid oil-displacing systems of prolonged action based on surfactants, inorganic acid adduct and polyatomic alcohol have been created. As a result of experimental studies of acid-base equilibrium in the systems with donor-acceptor interactions – polybasic inorganic acid and polyol, the influence of electrolytes, non-electrolytes and surfactants, the optimal compositions of the systems were selected, as well as concentration ranges of the components in the acid systems. When the initially acid system interacts with the carbonate reservoir to release CO2, the oil viscosity decreases 1.2-2.7 times, the pH of the system rises and this system evolves chemically turning into an alkaline oil-displacing system. As a result it provides effective oil displacement and prolonged reservoir stimulation. The system is compatible with saline reservoir waters, has a low freezing point (minus 20 ÷ minus 60 oC), low interfacial tension at the oil boundary and is applicable in a wide temperature range, from 10 to 200 oC. In 2014-2018 field tests of EOR technologies were successfully carried out to intensify oil production in the test areas of the Permian-Carboniferous deposit of high-viscosity oil in the Usinsk oil field, developed in natural mode and combined with thermal-steam stimulation, using the acid oil-displacing system based on surfactants, coordinating solvents and complex compounds. The pilot tests proved high efficiency of EOR technologies, as far as the oil production rate significantly increased, water cut decreased to intensify the development. The EOR technologies are environmentally safe and technologically effective. Commercial use of the EOR is promising for high-viscosity oil deposits.

scholarly journals Impact of Integrated Technologies of Enhanced Oil Recovery on the Changes in the Composition of Heavy Oil

2020 ◽  
pp. 17-24
Author(s):  
Yury V. Savinykh ◽  
Darya I. Chuykina ◽  
Larisa D. Stakhina
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Component Composition ◽  
High Viscosity ◽  
Buffer System ◽  
Gas Liquid Chromatography ◽  
Oil Composition ◽  
Integrated Technology ◽  
The Impact

This paper deals with the impact of an integrated technology for enhanced oil recovery on the composition of high-viscosity heavy oil produced at the Usinskoye oilfield (Russia, Komi Republic). In order to increase the effectiveness of the thermal-steam stimulation, a surfactant-based composition generating carbon dioxide and an alkaline buffer system is injected into the formation. The analysis of the oil composition is performed via the methods of gradient-displacement liquid adsorption, gas-liquid chromatography, and IR spectroscopy. The results obtained show that two parallel processes are proceeding when pumping an oil-displacing composition. The first process is the additional extraction of residual oil. This process is controlled by an increase in the content of resin-asphaltene substances in oil. The second process is an increase in the coverage of reservoir and the involvement into the development of previously uncovered areas with oil compositionally similar to that at the beginning of development. Using the results of the analysis of the component composition, the individual composition of alkanes, and structural fragments of oil samples in order to control the development of the Usinskoye oilfield, the frontal oil-water boundary advance of the Northern area in the direction of the upper production facility is determined. The obtained patterns of changes in the oil composition after the application of an integrated technology using a surfactant-based composition can be characteristic of other deposits of heavy oil occurring in low-permeability reservoirs

scholarly journals Stability, rheological property and oil-displacement mechanism of a dispersed low-elastic microsphere system for enhanced oil recovery

RSC Advances ◽  
2017 ◽  
Vol 7 (14) ◽  
pp. 8118-8130 ◽  
Author(s):  
Hongbin Yang ◽  
Wanli Kang ◽  
Hairong Wu ◽  
Yang Yu ◽  
Zhou Zhu ◽  
...  
Keyword(s):  
Rheological Property ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Shear Thickening ◽  
Microstructure Change ◽  
Displacement Mechanism ◽  
Oil Displacement ◽  
Internal Forces ◽  
Thickening Behavior

The dispersed low-elastic microsphere system shows shear-thickening behavior because of the microstructure change and the interaction of internal forces.

Fluorescent visualization of oil displacement in a microfluidic device for enhanced oil recovery applications

The Analyst ◽  
2021 ◽  
Author(s):  
Khashayar R. Bajgiran ◽  
Hannah C. Hymel ◽  
Shayan Sombolestani ◽  
Nathalie Dante ◽  
Nora Safa ◽  
...  
Keyword(s):  
Surface Properties ◽  
Enhanced Oil Recovery ◽  
Microfluidic Device ◽  
Oil Recovery ◽  
Visualization Technique ◽  
Oil Displacement

The developed platform offers a simple fluorescent visualization technique to specifically identify the oil and water phases without altering their surface properties which improves on the achievable resolution in EOR applications.

scholarly journals Comparative study on microbial enhanced oil recovery using mannosylerithritol lipids and surfactin

2016 ◽  
Vol 4 (2) ◽  
pp. 69 ◽  
Author(s):  
Cristiano José de Andrade ◽  
Gláucia Maria Pastore
Keyword(s):  
Ionic Strength ◽  
Enhanced Oil Recovery ◽  
Surface Activity ◽  
Oil Recovery ◽  
Extreme Conditions ◽  
Microbial Enhanced Oil Recovery ◽  
Oil Displacement ◽  
Recovery Processes ◽  
Emulsification Index ◽  
Good Surface

Worldwide oil production has been declining. Microbial enhanced oil recovery is one of the most important tertiary recovery processes. The aim of this work was to evaluate the surface activity properties of surfactin and mannosylerithritol lipids-B. In our previous studies, surfactin and mannosylerithritol lipids were produced using cassava wastewater as substrate and then purified by ultrafiltration. Thus, this work extends our previous studies. Experiments of surface activity under extreme conditions (temperature, ionic strength and pH), oil displacement, removal of oil from sand and emulsification index were carried out. Central composite rotational design was performed under extreme conditions of temperature, pH and ionic strength. The results indicated that ionic strength significantly affected the surface activity of surfactin. On the other hand, ionic strength, but also temperature and pH significantly affected the tenso activity of mannosylerithritol lipids-B. Regarding oil displacement test, mannosylerithritol lipids-B showed higher clear zone than surfactin. Contrary, in the experiments of removal of crude oil from sand, minimal differences were observed between surfactin and mannosylerithritol lipids-B. Therefore, both surfactin and mannosylerithritol lipids-B showed good surface activity under extreme conditions. In addition, it seems that mannosylerithritol lipids-B is subtly better than surfactin for microbial enhanced oil recovery.

scholarly journals Enhanced Oil Recovery: Chemical Flooding

2021 ◽  
Author(s):  
Ahmed Ragab ◽  
Eman M. Mansour
Keyword(s):  
Interfacial Tension ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Recovery Phase ◽  
Mobility Ratio ◽  
Chemical Flooding ◽  
Sweep Efficiency ◽  
Oil Displacement ◽  
Remaining Oil ◽  
Oil Displacement Efficiency

The enhanced oil recovery phase of oil reservoirs production usually comes after the water/gas injection (secondary recovery) phase. The main objective of EOR application is to mobilize the remaining oil through enhancing the oil displacement and volumetric sweep efficiency. The oil displacement efficiency enhances by reducing the oil viscosity and/or by reducing the interfacial tension, while the volumetric sweep efficiency improves by developing a favorable mobility ratio between the displacing fluid and the remaining oil. It is important to identify remaining oil and the production mechanisms that are necessary to improve oil recovery prior to implementing an EOR phase. Chemical enhanced oil recovery is one of the major EOR methods that reduces the residual oil saturation by lowering water-oil interfacial tension (surfactant/alkaline) and increases the volumetric sweep efficiency by reducing the water-oil mobility ratio (polymer). In this chapter, the basic mechanisms of different chemical methods have been discussed including the interactions of different chemicals with the reservoir rocks and fluids. In addition, an up-to-date status of chemical flooding at the laboratory scale, pilot projects and field applications have been reported.

Self-gasified biosystems for enhanced oil recovery

2021 ◽  
pp. 2150274
Author(s):  
B. A. Suleimanov ◽  
S. J. Rzayeva ◽  
U. T. Akhmedova
Keyword(s):  
Carbon Dioxide ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Experimental Studies ◽  
Microbial Enhanced Oil Recovery ◽  
Heterogeneous Porous Medium ◽  
Oil Displacement ◽  
Subcritical Region ◽  
Reservoir Conditions

Microbial enhanced oil recovery is considered to be one of the most promising methods of stimulating formation, contributing to a higher level of oil production from long-term fields. The injection of bioreagents into a reservoir results in the creation of oil-displacing agents along with a significant amount of gases, mainly carbon dioxide. Earlier, the authors failed to study the preparation of self-gasified biosystems and the implementation of the subcritical region (SR) under reservoir conditions. Gasified systems in the subcritical phase have better oil-displacing properties than nongasified systems. In a heterogeneous porous medium, the filtration profile of gasified liquids in the SR should be more uniform than for a degassed liquid. Based on experimental studies, the superior efficiency of oil displacement by gasified biosystems compared with degassed ones has been demonstrated. The possibility of efficient use of gasified hybrid biopolymer systems has been shown.

Cyclical Gel-Polymer Flooding Technology is an Effective Method of Enhanced Oil Recovery in High-Viscosity Oil Fields

2020 ◽  
Author(s):  
Svetlana Yur’evna Lobanova ◽  
Berdibek Ulanovich Yelubaev ◽  
Nikolay Evgen’evich Talamanov ◽  
Zhijian Sun ◽  
Chunxi Wang ◽  
...  
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
High Viscosity ◽  
Polymer Flooding ◽  
Oil Fields ◽  
High Viscosity Oil

Optimization of Surfactant and Polymer for SP Flooding of Zahra Oil

2014 ◽  
Vol 535 ◽  
pp. 701-704 ◽  
Author(s):  
Peng Lv ◽  
Ming Yuan Li ◽  
Mei Qin Lin
Keyword(s):  
Interfacial Tension ◽  
Polymer Solution ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
High Viscosity ◽  
Oil Field ◽  
Interfacial Tensions

Producing ultra-low interfacial tensions and maintaining high viscosity is the most important mechanism relating to SP flooding for enhanced oil recovery. The interfacial tension between surfactant (PJZ-2 and BE)/polymer solution and Zahra oil was evaluated in the work. Based on the evaluatiojn of interfacial tension, the polymer FP6040s/surfactant BE system was selected as the SP flooding system for Zahra oil field.

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