Теплофизические характеристики теплозащитного материала корпуса ракетного двигателя при температурах до 1000 оС

An experimental determination of the temperature dependences of the specific heat capacity and the thermal conductivity coefficient of the multifunctional coating MFP-92 at temperatures up to 1000 °C has been carried out. At temperatures up to 450 °C, an IT-c-400 device was used to determine the specific heat capacity. IT-l-400 device was used for the determination of thermal conductivity. At higher temperatures, the determination of the thermophysical characteristics (TPC) was carried out by solving the inverse problem of thermal conductivity (IPT) in a flat plate under conditions of one-sided heating in a muffle furnace. Composite material MFP-92 is a multilayer structure with upper layers based on silica fabric and chromophosphate binder and lower layers based on mullite-silica fabric and aluminosilicate binder. The TPC of the layers also differ from each other, and, accordingly, the properties of this material as a whole can be determined only in the form of their effective values, averaged in one way or another over the thickness of the coating. In addition, during heating, the material undergoes significant physicochemical transformations associated with the thermal destruction of its components, manifested in the form of abundant gas release, and a decrease in the density of the material, which significantly changes its TPC and determines its dependence on the heating rate. Therefore, studies of the thermophysical characteristics of the MFP-92 material were carried out with several (2-5) consecutive heating cycles. It was found that in four heating cycles of the MFP-92 material up to 450 °C for 75 minutes when measuring the specific heat on the IT-c-400 device, its temperature dependence significantly changes qualitatively and quantitatively. With furnace heating to 1000 °C, the temperature dependences of the TPC of the material, determined in the first and second heating cycles, have a different form, but change insignificantly in subsequent heating cycles. This makes it possible to ascribe to the MFP-92 material a set of two sets of TPC related to its initial (phase A) and annealed after heating to 1000 °C (phase B) states. Using the obtained TPС of phase A (including the magnitude of the thermal effect of irreversible endothermic phase transition at 100 °C) and phase B, good agreement was obtained between the calculated and experimental temperature fields in the samples under furnace heating conditions.