scholarly journals THE CONVERSION OF ETHANOL ON THE HZSM-5 ZEOLITE MODIFIED WITH LANTHANUM

2021 ◽  
pp. 55-60
Author(s):  
B.A. Babayeva ◽  
Keyword(s):  
Atmospheric Pressure ◽  
Octane Number ◽  
Ethanol Conversion ◽  
Substantial Impact ◽  
Temperature Range ◽  
Flow Type

The conversion of ethanol to hydrocarbons in the presence of lanthanum-modified ZSM-5 zeolite in the temperature range 3000 – 4500C at flow-type atmospheric pressure was studied and it was shown that the modification of ZSM-5 zeolite and imposed temperature affect the distribution of ethanol conversion products. Modification of HZSM-5 zeolite with lanthanum plays an important role in increasing the yield of isoparaffin hydrocarbons, as well as has a substantial impact on the quality and octane number of the catalyst. The catalyst obtained from the conversion of ethanol at 3000 – 3500C complies with the Euro-5 standard for the content of benzene (<1.0%), aromatic (<30%) and olefin (<2.0%) hydrocarbons

scholarly journals Experimental Study of Iraqi Light Naphtha Isomerization over Ni-Pt/H-Mordenite

2019 ◽  
Vol 20 (4) ◽  
pp. 61-66
Author(s):  
Halah M. Hussain ◽  
Abdulhaleem A.K. Mohammed
Keyword(s):  
Experimental Study ◽  
Reaction Temperature ◽  
Atmospheric Pressure ◽  
Octane Number ◽  
Space Velocity ◽  
Molar Ratio ◽  
Light Naphtha ◽  
Temperature Range ◽  
Liquid Hourly Space Velocity

Hydroisomerization of Iraqi light naphtha was studied on prepared Ni-Pt/H-mordenite catalyst at a temperature range of 220-300°C, hydrogen to hydrocarbon molar ratio of 3.7, liquid hourly space velocity (LHSV) 1 hr-1 and at atmospheric pressure. The result shows that the hydrisomerization of light naphtha increases with the increase in reaction temperature at constant LHSV. However, above 270 0C the isomers formation decreases and the reaction is shifted towards the hydrocracking reaction, a higher octane number of naphtha was formed at 270 °C.

Ethanol conversion over Ga2O3-ZrO2 solid solution: empirical evidences of the reaction pathway, the surface acid–base property, and role of isolated gallium ion

2021 ◽  
Author(s):  
Takashi Yamamoto ◽  
Akihito Kurimoto ◽  
Riona Sato ◽  
Shoki Katada ◽  
Hirotaka Mine ◽  
...  
Keyword(s):  
Solid Solution ◽  
Reaction Pathway ◽  
Ethanol Conversion ◽  
Acid Base ◽  
Base Property ◽  
Temperature Range ◽  
Acid Base Property

Ethanol conversion by Ga2O3-ZrO2 solid solution was examined in the temperature range 573–773 K, and acetone/isobutene formation was confirmed under cofeeding of H2O vapor. The reaction pathway was empirically investigated...

Transformation of 1-Butene over Synthetic Zeolites

1992 ◽  
Vol 57 (4) ◽  
pp. 869-881 ◽  
Author(s):  
Italo Ferino ◽  
Roberto Monaci ◽  
Vincenzo Solinas ◽  
Lucio Forni ◽  
Antonio Rivoldini ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Continuous Flow ◽  
Liquid Mixture ◽  
Isomerization Reaction ◽  
Reaction Conditions ◽  
Title Reaction ◽  
Y Zeolites ◽  
Temperature Range ◽  
Flow Microreactor ◽  
Synthetic Zeolites

The behaviour of several zeolites as catalysts for the title reaction has been investigated by means of a continuous flow microreactor. Runs performed at atmospheric pressure indicated that at 423 K the completely protonic forms of the zeolites catalyze just the isomerization reaction. In the case of Y zeolites, oligomerization occurs only over the partially decationated samples, in the temperature range between 373 and 423 K and W/F between 0.2 and 22 gcath/g1-but, to an extent which depends on the reaction conditions. Most of the catalysts were tested also under pressure (4.05 MPa) at 423 K. The protonic forms of Y and ZSM-5 zeolites seem promising catalysts in terms of both conversion and selectivity to oligomers. The 1-olefins account for 30% of the entire olefinic mixture. The octenes, which account for 70% of the liquid mixture, are mostly formed of dimethylhexenes. Trimers are also formed during the reaction and, in the very particular case of H[B]ZSM-5, tetramers are produced.

l-Asparagine-assisted synthesis of flower-like β-Bi2O3 and its photocatalytic performance for the degradation of 4-phenylphenol under visible-light irradiation

RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74977-74985 ◽  
Author(s):  
Xin Xiao ◽  
Shunheng Tu ◽  
Chunxia Zheng ◽  
Huan Zhong ◽  
Xiaoxi Zuo ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Photocatalytic Performance ◽  
Light Irradiation ◽  
Temperature Range

By introducing l-asparagine as a ligand, a flower-like precursor of Bi2O3 was prepared by a simple reflux process under atmospheric pressure. β-Bi2O3 was then conveniently obtained by decomposing the precursor and stabilized in a temperature range from room temperature to 420 °C due to the surface-coordination effects of CO32− derived from l-asparagine.

scholarly journals Photoluminescence and Cathodoluminescence of GaN doped with Pr

2000 ◽  
Vol 5 (S1) ◽  
pp. 817-823
Author(s):  
H. J. Lozykowski ◽  
W. M. Jadwisienczak ◽  
I. Brown
Keyword(s):  
Rare Earth ◽  
Thermal Annealing ◽  
Spectral Range ◽  
Atmospheric Pressure ◽  
Rare Earth Ions ◽  
Emission Lines ◽  
Decay Kinetics ◽  
Temperature Range ◽  
Characteristic Emission ◽  
Kinetics Measurement

In this paper we have reported the observation of visible photoluminescence (PL) and cathodoluminescence (CL) of Pr implanted in GaN. The implanted samples were given isochronal thermal annealing treatments at a temperature of 11000 C in NH3, N2, Ar2, and in forming gas N2 +H2, at atmospheric pressure to recover implantation damages and activate the rare earth ions. The sharp characteristic emission lines corresponding to Pr3+ intra-4fn-shell transitions are resolved in the spectral range from 350 nm to 1150 nm, and observed over the temperature range of 12 K-335 K. The PL and CL decay kinetics measurement was performed for 3P1, 3P0 and 1D2 levels.

H/D Isotope Effects in the Conductivity of Licl Aqueous Solutions in Sub and Supercritical State

2003 ◽  
Vol 2003 (1) ◽  
pp. 4-5
Author(s):  
Ibrahim M. Ismail ◽  
Massao Numora ◽  
Yoshio Masuko ◽  
Hiroshi Tomiyasu ◽  
Yasuhiko Fujii
Keyword(s):  
Aqueous Solutions ◽  
Isotope Effects ◽  
Electrical Conductance ◽  
Supercritical State ◽  
Temperature Range ◽  
Flow Type ◽  
Electrical Conductances

The electrical conductances of LiCl in H2O and D2O solutions were measured in the temperature range 373 - 673 K at pressures up to 37.27 MPa, using a flow type electrical conductance cell.

Heat Capacities of Some Alkyl Acetates at 295-323 K

1997 ◽  
Vol 62 (10) ◽  
pp. 1527-1532 ◽  
Author(s):  
Václav Svoboda ◽  
Kornelia Gottmanová ◽  
Vladimír Hynek ◽  
Bohumír Koutek
Keyword(s):  
Experimental Data ◽  
Linear Function ◽  
Atmospheric Pressure ◽  
Heat Capacities ◽  
Group Additivity ◽  
Temperature Range ◽  
Alkyl Acetates

Molar heat capacities Cp,m at constant atmospheric pressure have been determined with a typical uncertainty of about 0.3% for eight liquid alkyl acetates H(CH2)nOCOCH3 (n = 6-12, 14), over the temperature range 295-323 K. The Cp,m values were found to be a linear function of temperature. A comparison of experimental data with those predicted by the group additivity method demonstrated a rather limited capability of the additivity scheme to predict correctly the Cp,m values for higher (n > 10) homologues in the series.

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