scholarly journals ANALYSIS OF INTERMOLECULAR INTERACTIONS IN MIXED ADSORPTION LAYERS OF SURFACTANTS

2019 ◽  
Vol 85 (5) ◽  
pp. 69-74
Author(s):  
Olha Kochkodan ◽  
Nadiya Antraptseva ◽  
Roman Zhyla
Keyword(s):  
Adsorption Layer ◽  
Chemical Nature ◽  
Binary Solution ◽  
Molar Fraction ◽  
Graphitized Carbon Black ◽  
Ionic Surfactant ◽  
Surface Active ◽  
Triton X ◽  
Adsorption Layers ◽  
Mixed Systems

The adsorption of the surfactants mixtures of different chemical nature such as Triton X-100 and sodium hexadecyl sulfate at the surface of graphitized carbon black was studied. Using the model of phase separation (the Rubi–Rosen approach), the composition of the mixed adsorption layers and parameters of interaction between the surfactant molecules in the adsorption layers were calculated. It was found that mixed adsorption layers are enriched with molecules of the non-ionic surfactant Triton X-100. The purpose of the work was to study the adsorption of binary mixtures of surfactants of various chemical nature on the surface of non-porous hydrophobic carbon sorbent at different SAS ratio in mixtures. The results of calculations show that the composition of the adsorption layer on the surface of the GC is significantly different from the ratio of surfactants in the solution. The value of the parameter χ indicates that the mixed adsorption layer on the surface of the GC is enriched with non-ionic surfactant molecules, even with a small its content in the solution (αTХ-100 = 0,2). With an increase in the ТХ-100 molar fraction in the binary solution from 0,2 to 0,8 its share in the adsorption layer increases in approximately 1.5 times. Negative values of the interaction parameters βs indicate excessive attraction of the molecules and ions of the mixture components in the mixed adsorption layers. An increase in the absolute value of the parameter βs with an increase in αTХ-100 in the solution characterizes the enhancement of the interactions between the components in the adsorption layer. Thus, in the course of experiments carried out for mixed systems of SHDS-ТХ-100, the existence of a synergistic effect in relation to an increase in the adsorption of surfactants on the GC surface was established. It is found that mixed adsorption layers are enriched with molecules of the non-ionic surface  active  substance  of  the  triton  X-100.

scholarly journals Mixed adsorption of hexadecylpyridinium bromide and Triton X surfactants at graphitized carbon black

2020 ◽  
Vol 85 (6) ◽  
pp. 781-794
Author(s):  
Olga Kochkodan ◽  
Viktor Maksin
Keyword(s):  
Carbon Black ◽  
Adsorption Layer ◽  
Surfactant Molecule ◽  
Graphitized Carbon Black ◽  
Bulk Solution ◽  
Ionic Surfactant ◽  
Surfactant Mixtures ◽  
Graphitized Carbon ◽  
Experimental Values ◽  
Triton X

Adsorption of cationic 1-hexadecylpyridinium bromide (HDPB) and non-ionic p-(1,1,3,3-tetramethylbutyl)-phenoxypolyoxyethylene glycols surfactants of the Triton X series (Triton X-45, Triton X-100 and Triton X-305) from their single and mixed aqueous solutions at thermally graphitized carbon black (CB) was studied. It was shown that the adsorption of the non-ionic surfactant from its individual solution decreased when a number of ethylene oxide units in the surfactant molecule increased. Addition of the non-ionic surfactants increased the amount of HDPB adsorbed from HDPB/Triton X mixtures. At low solution concentrations it was found that in HDPB/Triton X mixtures, the experimental values of total surfactants adsorption are higher than the adsorption values calculated for the ideal surfactant mixtures. The composition of the mixed HDPB/Triton X adsorption layer and the parameters of the intermolecular interaction (?s), between the components in this layer, were calculated using the Rubingh-Rosen approach. It was shown that ?s parameters have negative values, which indicate notable interactions between Triton X molecules and HDPB ions in the mixed adsorption layer. It was found that the composition of the mixed adsorption layer at CB surface is notably different from the surfactants composition in the bulk solution. The mixed HDPB/Triton X adsorption layer is enriched with Triton X surfactant and the mole fraction of Triton X increases with decreasing of ethoxylation degree of its molecules.

Flotation Deinking of Xerographic and Laser-Printed Paper: Influence of Surface-Active Substances

2011 ◽  
Vol 287-290 ◽  
pp. 3028-3031
Author(s):  
Panitnad Chandranupap ◽  
Pravitra Chandranupap ◽  
Pantharee Kongsat
Keyword(s):  
Sodium Dodecyl ◽  
Ionic Surfactant ◽  
Paper Recycling ◽  
Recycled Paper ◽  
Burst Strength ◽  
Surface Active ◽  
Virgin Pulp ◽  
Triton X ◽  
Active Substances

In present time, recycled paper from xerographic and laser-printed wastepaper plays an important role as alternatives to paper from virgin pulp because of their good pulp quality and high amount of wastepaper each year. This type of paper is classified as Mixed Office Wastepaper (MOW). The xerographic and laser-printed inks are usually called “toner” which its formulation is different from conventional ink. This work aimed to investigate paper recycling by flotation deinking process. The flotation experiments were conducted using SDS (sodium dodecyl sulfate) and Triton X-100 (C14H22O(C2H4O)n). The experimental results demonstrated that ink removal was more efficient with the use of non-ionic surfactant (Triton X-100) than anionic surfactant (SDS). The efficiency of ink removal was determined by ERIC and the pulp’s brightness. In addition, the quality of de-inked pulps was evaluated by pulp physical properties such as burst strength, tear strength and tensile strength.

scholarly journals Ion-Specific Effects on Equilibrium Adsorption Layers of Ionic Surfactants

2018 ◽  
Vol 2 (2) ◽  
Author(s):  
Stoyan I. Karakashev
Keyword(s):  
Experimental Validation ◽  
Adsorption Layer ◽  
Liquid Films ◽  
Thin Liquid Films ◽  
Ionic Surfactant ◽  
Surfactant Adsorption ◽  
Specific Effects ◽  
Counter Ions ◽  
The Stability ◽  
Adsorption Layers

This review article reports on the effect of the counter-ions on the ionic surfactant adsorption layer and its relation to the stability of foams and emulsions. The adsorption theory of Davies about the ionic surfactant monolayer was revisited and it is shown how to account for the type of the counter-ions. The experimental validation of this theory on thin liquid films was shown as well, thus explaining the effect of Hofmeister. However their effect on foams and emulsions is more complex. Furthermore, it is shown how the counter-ions affect in complex way the stability of foams and emulsions via the surfactant adsorption layer in the light of the newest theory. To elucidate the nature of this effect further investigation is called for. 

scholarly journals Synergism of non-ionic and anionic surfactants in a binary solution.

2020 ◽  
Vol 11 (3-2020) ◽  
pp. 62-68
Author(s):  
A. S. Genevskaya ◽  
◽  
G. V. Mitrofanova ◽  
◽  
Keyword(s):  
Adsorption Layer ◽  
Mixed Micelles ◽  
Anionic Surfactants ◽  
Binary Solution ◽  
Micelle Formation ◽  
Ionic Component ◽  
Solution Composition ◽  
Binary Solutions ◽  
Air Interface ◽  
Adsorption Layers

Adsorption at the gas —air interface and micelle formation in binary solutions of ethoxylated alkyl phenol (Neonol AF 9-10) and sodium oleate have been studied. The Rubin and Rosen equations were used to determine the interaction parameters and the composition of mixed micelles and adsorption layers depending on the initial solution composition. The authors have found out that the micelles and the adsorption layer at the interface are enriched in a non-ionic component. The maximum synergistic effect during micelle formation was found for solutions containing 20–30 % molar of reagent Neonol AF 9-10, and during adsorption —20 and 50 %.

scholarly journals Adsorption of Sodium Hexadecyl Sulfate and Triton X from Binary Aqueous Solutions at Thermally Graphitized Carbon Black

2020 ◽  
Vol 65 (1) ◽  
pp. 72-79
Author(s):  
Olga Kochkodan ◽  
Victor Maksin ◽  
Tetyana Semenenko
Keyword(s):  
Carbon Black ◽  
Aqueous Solutions ◽  
Nonionic Surfactant ◽  
Adsorption Layer ◽  
Nonionic Surfactants ◽  
Graphitized Carbon Black ◽  
Bulk Solution ◽  
Graphitized Carbon ◽  
Individual Solution ◽  
Triton X

Adsorption of anionic sodium hexadecyl sulfate (SHS) and nonionic Triton X surfactants with different ethoxylation degree: TX-45, TX-100 and TX-300 from their individual and mixed aqueous solutions at the surface of thermally graphitized carbon black (CB) was studied. It was found that at low solution concentrations addition of the nonionic surfactant increases the amount of SHS adsorbed from SHS/Triton X mixtures compared to SHS amount adsorbed from its individual solution. These findings might be explained by decreasing in electrostatic repulsion between SHS ions due to inclusion of the molecules of the nonionic surfactant in the mixed adsorption layer. At higher solution concentrations, adsorption of SHS decrease as a result of displacement of SHS ions from the mixed adsorption layer by Triton X molecules. It was established that the composition of the mixed adsorption layer at CB surface notably differ from the composition of the surfactant mixture in the bulk solution. The mixed adsorption layer is enriched with the molecules of the nonionic surfactants and this conclusion is confirmed by the results of measuring zeta potential of CB particles with the adsorbed surfactants.

scholarly journals Ion-specific effects on equilibrium adsorption layers of ionic surfactants

2020 ◽  
Vol 3 (2) ◽  
pp. 53
Author(s):  
Stoyan I. Karakashev
Keyword(s):  
Experimental Validation ◽  
Adsorption Layer ◽  
Liquid Films ◽  
Thin Liquid Films ◽  
Ionic Surfactant ◽  
Surfactant Adsorption ◽  
Specific Effects ◽  
Counter Ions ◽  
The Stability ◽  
Adsorption Layers

This review article reports the effect of the counter-ions on the ionic surfactant adsorption layer and its relation to the stability of foams and emulsions. The adsorption theory of Davies about the ionic surfactant monolayer was revisited and it is shown how to account for the type of the counter-ions. The experimental validation of this theory on thin liquid films was shown as well, thus explaining the effect of Hofmeister. However, their effect on foams and emulsions is more complex. Furthermore, it is shown how the counter-ions affect in complex way the stability of foams and emulsions via the surfactant adsorption layer in the light of the newest theory. To elucidate the nature of this effect, further investigation is called for.

Studies of a Mixed Adsorption Layer of Butan-1-ol and o-Toluidine on Mercury Electrode

2002 ◽  
Vol 67 (11) ◽  
pp. 1579-1588 ◽  
Author(s):  
Dorota Sieńko ◽  
Dorota Gugała ◽  
Jolanta Nieszporek ◽  
Joanna Jankowska ◽  
Jadwiga Saba
Keyword(s):  
Thermodynamic Analysis ◽  
Adsorption Layer ◽  
Supporting Electrolyte ◽  
Mercury Electrode ◽  
Interaction Constant ◽  
Repulsive Interaction ◽  
Surface Excess ◽  
Adsorption Parameters ◽  
Frumkin Isotherm ◽  
Adsorption Layers

The results of thermodynamic analysis of o-toluidine adsorption on a mercury electrode in the presence of various butan-1-ol amounts complete our previous studies on properties of mixed adsorption layers of toluidine isomers-butan-1-ol. The values of the relative surface excess Γ'°T obtained for o-toluidine show that adsorption of this compound decreases with increasing of butan-1-ol concentration. Analysis of adsorption parameters derived from the Frumkin isotherm indicates that in the presence of 0.33 M BuOH in 1 M NaClO4 with adjusted pH 3 as supporting electrolyte, ∆G0 values for o-toluidine are the highest and, at the same time, the strongest repulsive interaction occurs. In the presence of 0.11 M butan-1-ol, smaller values of ∆G0 for o-toluidine correspond to weaker repulsive interaction. Therefore the change of the Γ'°T value for o-toluidine as a function of butan-1-ol concentration is the result of mutual changes of ∆G0 and interaction constant A between adsorbate molecules.

Drug Solubilization by Surfactants: Experimental Methods and Theoretical Perspectives

2021 ◽  
Vol 21 ◽  
Author(s):  
Nisar Ahmad Malik
Keyword(s):  
Theoretical Models ◽  
Experimental Methods ◽  
Poorly Soluble Drugs ◽  
Drug Solubilization ◽  
Theoretical Perspectives ◽  
Surface Active Agents ◽  
Poorly Soluble ◽  
Surface Active ◽  
Mixed Systems ◽  
Insight Into

: This mini review will give an insight into the need and usefulness of investigating the solubilization of poorly soluble drugs. Commonly used experimental and theoretical models are outlined to study the efficacy of the carrier or excipient for the poorly soluble drugs. Furthermore, the use of surface active agents for drug solubilization is discussed in correlation with the mathematical models suggested from time to time. A few experimental techniques are also discussed which would be very helpful in elucidating the interactions prevailing in the mixed systems of poorly soluble drugs and surface active agents.

336. Surface activity and proteins of milk

1946 ◽  
Vol 14 (3) ◽  
pp. 316-329 ◽  
Author(s):  
R. Aschaffenburg
Keyword(s):  
Milk Fat ◽  
Chemical Nature ◽  
Active Material ◽  
Milk Proteins ◽  
Residual Fraction ◽  
Total Milk ◽  
Surface Active ◽  
Surface Active Material ◽  
Dilution Curves

As moderate dilution causes little change in the surface tension of milk, it is shown to be advantageous to use σ-dilution curves in place of the σ-values of the undiluted fluid as a characteristic of the surface properties of milk. The complications arising from the presence of the milk fat are described, and it is suggested that the influence of the fat is of a physical rather than of a chemical nature. A study of the role of the various milk proteins shows the casein to be of great importance, whilst the heat-coagulable proteins have little influence. The serum obtained after removal of the casein and heat-coagulable proteins contains a residual fraction of protein-like material which is markedly surface active though constituting only about 3% of the total milk proteins. The surface-active material (σ-proteose) has been concentrated and isolated, and its properties are described in some detail.

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