scholarly journals Differences on Geochemical Characteristics and Their Implicating Significances of Nitrogen in Coal-Derived Gas and Oil-typed Gas in China

2021 ◽  
Vol 9 ◽  
Author(s):  
Wang Xiaobo ◽  
Li Jian ◽  
Yang Chunxia ◽  
Li Zhisheng ◽  
Chen Jianfa ◽  
...  
Keyword(s):  
Natural Gas ◽  
Nitrogen Isotope ◽  
Parent Material ◽  
Geochemical Characteristics ◽  
Source Rocks ◽  
Genetic Identification ◽  
Hydrocarbon Gases ◽  
Identification Methods ◽  
Main Frequency ◽  
Nitrogen Abundance

Natural gases in China are mainly coal-derived gas, with assistance from oil-typed gas. At present, many genetic identification methods, from hydrocarbon composition and isotope to light hydrocarbon and biomarker indexes, have been formed, but combined methods from non-hydrocarbon gases are lacking. Based on compositions and isotopes geochemical characteristics and the differences of non-hydrocarbon nitrogen gas in coal-derived gas and oil-typed gas, and combining the isotopic geochemical characteristics of non-hydrocarbon helium, the comprehensive identification methods of coal-derived gas and oil-typed gas for hydrocarbon gases according to the associated non-hydrocarbon gases of nitrogen and helium are established and the preliminary applications have been engaged. The main recognitions are as follows:1)Coal-derived gas generally has relatively lower nitrogen abundance, mainly distributed from 0 to 31.2% with main frequency from 0 to 2%. Oil-typed gas, on the other hand, usually has relatively higher nitrogen abundance, mainly distributed from 1.1 to 57.1% with main frequency from 2 to 16%. 2) Coal-derived gas generally has relatively heavier nitrogen isotope values, mainly distributed from -8 to 19.3‰ with main frequency from -8 to 8‰.Oil-typed gas usually has relatively lower nitrogen isotope values, mainly distributed from -10.6 to 4.6‰ with main frequency from -8 to 4‰.3)The geochemical characteristic differences of coal-derived gas and oil-typed gas are mainly due to the fact that the sapropel parent material is relatively rich in nitrogen element and rich in light δ14N, while the humic parent material is relatively poor in nitrogen element and rich in heavy δ15N. The differences on thermal maturity of source rocks, the redox conditions of source rock sedimentary environment, and the salinity of water body are also important effective factors.4)Differences on nitrogen abundances and isotopes in coal-derived gas and oil-typed gas have great significance in genetic identification. The genetic identification chart of R/Ra-δ15N for organic and inorganic nitrogen in natural gas and the comprehensive joint identification charts of R/Ra-δ15N-N2 of nitrogen and helium for coal-derived gas and oil-typed gas have been established, and are of great reference in investigating the origins and sources of natural gas and guiding natural gas exploration in China.

The Research of Origin of Deep Natural Gas of Qianbei Sub-Sag in the South of Songliao Basin

2014 ◽  
Vol 675-677 ◽  
pp. 1341-1346
Author(s):  
Wu Yi ◽  
Wei Chao Tian
Keyword(s):  
Natural Gas ◽  
Analytical Data ◽  
Parent Material ◽  
Source Rocks ◽  
Gas Content ◽  
Carbon Isotopic ◽  
Hydrocarbon Source Rocks ◽  
Study Results ◽  
Humus Type ◽  
Hydrocarbon Gas

This paper analyses the origins of deep natural gas in Qianbei Subsag using a variety of analytical data such as the natural gas components, the isotope and the light hydrocarbon analysis combining with the development characteristics of hydrocarbon source rocks. The study results show as the following: The abundance of organic matter from hydrocarbon source rocks in Qianbei Subsag is high and dominated by humus type. Part of good hydrocarbon source rocks of Type II1 and Type II2 are developed in Yingcheng Formation and these are the major gas source rocks that is in the stage of postmaturity in evolution degree. The natural gas component is dominated by methane and non-hydrocarbon gas content is low. The isotope values of ethane are lighter and methane and ethane have an obvious phenomenon of carbon isotopic reversal. Parent material types of methane and ethane are from different sources. The sources of methane are biased to humic parent material while the sources of ethane are biased to sapropelic parent material.

UNDERSTANDING SOURCE, DISTRIBUTION AND PRESERVATION OF AUSTRALIAN NATURAL GAS: A GEOCHEMICAL PERSPECTIVE

2001 ◽  
Vol 41 (1) ◽  
pp. 523 ◽  
Author(s):  
C.J. Boreham ◽  
J.M. Hope ◽  
B. Hartung-Kagi
Keyword(s):  
Organic Matter ◽  
Natural Gas ◽  
Isotopic Composition ◽  
Carbon Isotopic Composition ◽  
Source Rocks ◽  
Source Distribution ◽  
Hydrocarbon Gases ◽  
Carbon Isotopic ◽  
Wet Gas ◽  
Gaseous Hydrocarbons

Natural gases from all of Australia’s major gas provinces in the Adavale, Amadeus, Bass, Bonaparte, Bowen/ Surat, Browse, Canning, Carnarvon, Cooper/Eromanga, Duntroon, Gippsland, Otway and Perth basins have been examined using molecular and carbon isotopic compositions in order to define their source, maturity and secondary alteration processes.The molecular compositions of the gaseous hydrocarbons range from highly wet to extremely dry. On average, reservoired gases predominantly derived from land plants are slightly wetter than those derived from marine sources. The non-hydrocarbon gases CO2 and N2 were sourced from both inorganic and organic materials. A mantle and/or igneous origin is likely in the majority of gases with CO2 contents >5%. For gases with lower CO2 contents, an additional organic input, associated with hydrocarbon generation, is recognised where δ13C CO2 is A strong inter-dependency between source and maturity has been recognised from the carbon isotopic composition of individual gaseous hydrocarbons. This relationship has highlighted some shortcomings of common graphical tools for interpretation of carbon isotopic data. The combination of the carbon isotopic composition of gaseous hydrocarbons and the low molecular weight nalkanes in the accompanying oil allows our knowledge of oil-source correlations and oil families to be used to correlate gases with their sources. This approach has identified source rocks for gas ranging in age from the Ordovician in the Amadeus Basin to Late Cretaceous- Early Tertiary sources in the Bass and Gippsland basins. The carbon isotopic composition of organic matter, approximated using the δ13C of iso-butane, shows a progressive enrichment in 13C with decreasing source age, together with marine source rocks for gas being isotopically lighter than those from land plant sources. The Permian was a time when organic matter was enriched in 13C and isotopically uniform on a regional scale.Secondary, in-reservoir alteration has played a major role in the modification of Australian gas accumulations. Thus, biodegradation, prominent in the Bowen/Surat, Browse, Carnarvon and Gippsland basins, is found in both hydrocarbon and non-hydrocarbon gases. This is recognised by an increase in gas dryness, elevated isoalkane to n-alkane ratio, differential increase in δ13C of the individual wet gas components, a decrease in δ13C of methane and a reduction in CO2 content concomitant with enrichment in 13C. Evidence of water-washing has been identified in accumulations in the Bonaparte and Cooper/Eromanga basins, resulting in an increase in the wet gas content. Seal integrity is also a major risk for the preservation of natural gas accumulations, although its effect on gas composition is only evident in extreme cases, such as the Amadeus Basin, where preferential leakage of methane in the Palm Valley field has resulted in the residual methane becoming enriched in 13C.The greater mobility of gas within subsurface rocks can have a detrimental effect on oil composition whereby gas-stripping of light hydrocarbons is common amongst Australian oil accumulations. Alternatively, the availability of gas, derived from a source rock common to or different from oil, was likely to have been a prime factor controlling the regional distribution of oil, whereby mixing of both results in increased oil mobility and can lead to a greater access to the number and types of traps in the subsurface.

scholarly journals Comparison on Rare Gas Geochemical Characteristics and Gas Originations of Kuche and Southwestern Depressions in Tarim Basin, China

Geofluids ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-15
Author(s):  
Xiaobo Wang ◽  
Caineng Zou ◽  
Jian Li ◽  
Guoqi Wei ◽  
Jianfa Chen ◽  
...  
Keyword(s):  
Tarim Basin ◽  
Geochemical Characteristics ◽  
Source Rocks ◽  
Rare Gases ◽  
Hydrocarbon Gases ◽  
Gas Field ◽  
Resource Potential ◽  
Natural Gases ◽  
Kuche Depression ◽  
Gas Fields

The Kuche Depression is considered as the most important gas resource potential and gas exploring area with great gas resource potential and prospect in the Tarim Basin. Based on geochemical experimental analyses and comprehensive geological studies, the general geochemical characteristics of molecular and isotope compositions of rare gases as well as hydrocarbon gases and nonhydrocarbon gases are comparatively studied in the Kuche and Southwestern Depressions. Then, their genetic types are separately identified and gas originations are comprehensively discussed. The main results are as follows. (1) Gas fields in the Kuche Depression have a higher methane abundance, accompanied with low N2and CO2abundances, but the Akemomu gas field in the Southwestern Depression has a relatively lower average methane abundance, accompanied with high average N2and CO2abundances. The helium abundance of natural gases in gas fields from the Kuche Depression general has 1 order of magnitude higher than the air value. Comparatively, it has more than 2 orders of magnitude higher than the atmospheric value in the Akemomu gas field from the Southwestern Depression. The neon, argon, krypton, and xenon abundances in both Kuche and Southwestern Depressions are lower than the corresponding air values. (2) Natural gases from gas fields in the Kuche Depression and the Southwestern Depressions are generally typical coal-formed gases. The rare gases in the Kuche Depression have typical crustal genesis, mainly deriving from the radioactive decay of elements in the crust, while in the Akemomu gas field from the Southwestern Depression, the rare gases have main crustal genesis with a proportion of 92.5%, probably accompanied with a little mantled genetic contribution. (3) Natural gases in the Kuche Depression are generally derived from coal measure source rocks of Jurassic and Triassic, which principally originated from Jurassic in strata period and coals in source rock types. The Jurassic source rocks account for 55%-75% and the Triassic source rocks account for 25%-45% approximately, while coals occupy 68% and mudstones occupy 32% separately. Natural gases from the Akemomu gas field in the Southwestern Depression mainly originated from humic mudstones of marine and continental transitional source rocks of Carboniferous to Permian.

Generation and origin of natural gas in Lower Palaeozoic shales from southern Sweden

1969 ◽  
pp. 37-40
Author(s):  
Niels Hemmingsen Schovsbo ◽  
Arne Thorshøj Nielsen
Keyword(s):  
Source Rocks ◽  
Southern Sweden ◽  
Hydrocarbon Gases ◽  
Biogenic Gas ◽  
South Central ◽  
Alum Shale ◽  
Marine Source ◽  
Lower Palaeozoic ◽  
Background Gas ◽  
Origin Of Natural Gas

The Lower Palaeozoic succession in Scandinavia includes several excellent marine source rocks notably the Alum Shale, the Dicellograptus shale and the Rastrites Shale that have been targets for shale gas exploration since 2008. We here report on samples of these source rocks from cored shallow scientific wells in southern Sweden. The samples contain both free and sorbed hydrocarbon gases with concentrations significantly above the background gas level. The gases consist of a mixture of thermogenic and bacterially derived gas. The latter likely derives from both carbonate reduction and methyl fermentation processes. The presence of both thermogenic and biogenic gas in the Lower Palaeozoic shales is in agreement with results from past and present exploration activities; thermogenic gas is a target in deeply buried, gas-mature shales in southernmost Sweden, Denmark and northern Poland, whereas biogenic gas is a target in shallow, immature-marginally mature shales in south central Sweden. We here document that biogenic gas signatures are present also in gas-mature shallow buried shales in Skåne in southernmost Sweden.

Geochemical characteristics, origin of the Chang 8 oil and natural gas in the southwestern Ordos Basin, China

2021 ◽  
Vol 200 ◽  
pp. 108406
Author(s):  
Kaiming Su ◽  
Shijia Chen ◽  
Yuting Hou ◽  
Haifeng Zhang ◽  
Xiaolei Zhang ◽  
...  
Keyword(s):  
Natural Gas ◽  
Ordos Basin ◽  
Geochemical Characteristics ◽  
Oil And Natural Gas

scholarly journals Light hydrocarbon geochemical characteristics and their application in Upper Paleozoic, Shenmu gas field, Ordos Basin

2016 ◽  
Vol 35 (1) ◽  
pp. 103-121 ◽  
Author(s):  
Wenxue Han ◽  
Shizhen Tao ◽  
Guoyi Hu ◽  
Weijiao Ma ◽  
Dan Liu ◽  
...  
Keyword(s):  
Natural Gas ◽  
Ordos Basin ◽  
Light Hydrocarbon ◽  
Source Rocks ◽  
Higher Plant ◽  
Gas Field ◽  
Gas Source ◽  
Upper Paleozoic ◽  
Methyl Cyclohexane ◽  
Normal Stage

Light hydrocarbon has abundant geochemical information, but there are few studies on it in Shenmu gas field. Taking Upper Paleozoic in Shenmu gas field as an example, authors use gas chromatography technology to study light hydrocarbon systematically. The results show that (1) The Shenmu gas field is mainly coal-derived gas, which is mixed by partial oil-derived gas due to the experiment data. (2) Based on K1, K2 parameter and Halpern star chart, the Upper Paleozoic gas in Shenmu gas field belongs to the same petroleum system and the depositional environment of natural gas source rocks should be homologous. (3) The source rocks are mainly from terrestrial higher plant origins and belong to swamp facies humic due to methyl cyclohexane index and Mango parameter intersection chart, which excluded the possibility of the Upper Paleozoic limestone as source rocks. (4) The isoheptane ranges from 1.45 to 2.69 with an average of 2.32, and n-heptane ranges from 9.48 to 17.68% with an average of 11.71%, which is below 20%. The maturity of Upper Paleozoic gas in Shenmu gas field is low-normal stage, which is consistent with Ro data. (5) The Upper Paleozoic natural gas in the Shenmu gas field did not experience prolonged migration or secondary changes, thus can be analyzed by light hydrocarbon index precisely.

Organic geochemical characteristics and their roles on barium enrichment in the No. 2 Coal from Huanglong Jurassic Coalfield, China

2015 ◽  
Vol 12 (5) ◽  
pp. 453-462 ◽  
Author(s):  
Shu Yi ◽  
Lin Xiao ◽  
Yong Zhang ◽  
Dujuan Duan ◽  
Maksim G. Blokhin
Keyword(s):  
Organic Material ◽  
Higher Plants ◽  
Parent Material ◽  
Geochemical Characteristics ◽  
Average Content ◽  
Common World

This paper describes the organic geochemical characteristics and their roles on barium enrichment in the No. 2 Coal from Huanglong Jurassic Coalfield, China. A total of 18 bench samples were taken from Huangling Mine 2. The average content of barium (3701 mg/kg) was about 23 times higher than that of common world coals. Terrestrial higher plants were the main coal-forming parent material. Relying on the parameters of OEP, Pr/Ph and so on, there is little correlation between organic geochemical characteristics and barium enrichment. Therefore, organic material has little influence on the process of coal-forming and the enrichment of barium.

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