scholarly journals Nitrogen, Phosphorus, and Potassium Adsorption and Desorption Improvement and Soil Buffering Capacity Using Clinoptilolite Zeolite

Agronomy ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 379
Author(s):  
Perumal Palanivell ◽  
Osumanu Haruna Ahmed ◽  
Latifah Omar ◽  
Nik Muhamad Abdul Majid

The physical and chemical properties of clinoptilolite zeolite can be used to enhance soil nutrient availability for optimum crop use. Amending nitrogen, phosphorus, and potassium fertilizers with clinoptilolite zeolite could create a pool of negative charges to retain and release nutrients timely for crop use. Thus, we used clinoptilolite zeolite to enhance Typic Paleudults sorption (adsorption and desorption) of nitrogen, phosphorus, potassium, and this soil’s pH buffering capacity. The treatments evaluated were: (i) 250 g soil alone, (ii) 20 g clinoptilolite zeolite alone, (iii) 250 g soil + 20 g clinoptilolite zeolite, (iv) 250 g soil + 40 g clinoptilolite zeolite, and (v) 250 g soil + 60 g clinoptilolite zeolite. Clinoptilolite zeolite increased soil nitrogen and potassium adsorption, nitrogen desorption, and soil pH. Moreover, ability of the soil to resist drastic change in pH (pH buffering capacity) was improved. Additionally, phosphorus adsorption and desorption of phosphorus and potassium were reduced. Higher potassium adsorption with lower potassium desorption suggests that the clinoptilolite zeolite sorbs potassium effectively. The clinoptilolite zeolite nitrogen, phosphorus, and potassium contributed to the reduction in the adsorption these nutrients. The clinoptilolite zeolite improved nitrogen, phosphorus, and potassium availability and soil buffering capacity to prevent these nutrients from being fixed or lost through for example, leaching. Therefore, clinoptilolite zeolite application could contribute to improved use of nitrogen, phosphorus, and potassium fertilizers to prevent soil, air, and water pollution. Additionally, our intervention could improve nitrogen, phosphorus, and potassium use efficiency.

2019 ◽  
Vol 10 (1) ◽  
pp. 295
Author(s):  
Perumal Palanivell ◽  
Osumanu Haruna Ahmed ◽  
Omar Latifah ◽  
Nik Muhamad Abdul Majid

Adsorption and desorption of nitrogen (N), phosphorus (P), and potassium (K) soils are controlled by pH, pH buffering capacity, organic matter, and cation exchange capacity (CEC). These factors optimized to improve timely availability of N, P, and K crop use using organic amendments such as chicken litter biochar (CLB). The objective of this study was to determine the effects of CLB on N, P, K sorption and pH buffering capacity of an acid soil. Different rates of CLB were mixed with an acid soil for N, P, and K sorption and pH buffering capacity determination. The CLB increased soil pH and pH buffering capacity, but unlike P and K adsorption, the different rates of CLB significantly increased N adsorption, suggesting that this soil amendment has high affinity for N than P and K. Also, because CLB reduced N, P, and K desorption, it suggests that N in particular will be slowly released with time. The reduced N desorption but higher N adsorption further indicates that N can be temporary fixed by CLB. This work has revealed CLB is more effective controlling soil N availability for timely crop use to avoid losses.


2018 ◽  
Vol 42 (6) ◽  
pp. 445-449 ◽  
Author(s):  
Sudharani A Pyati ◽  
R Naveen Kumar ◽  
Vinod Kumar ◽  
N H Praveen Kumar ◽  
K M Parveen Reddy

Objectives: To measure and compare the levels of salivary flow rate, pH, buffering capacity, total protein, malondialdehyde (MDA) and total antioxidant capacity (TAC) between caries active and caries free children and to study the correlation between the DMFS/dfs score and above salivary parameters in caries active children. Study design: 50 caries active (DMFS/dfs ≥ 5) and 50 caries free (DMFS/dfs = 0) children aged between 6 to 12 years were included in the study. From all the children, unstimulated, mid-morning saliva samples were collected and salivary flow rate was calculated. Salivary pH, buffering capacity, total protein, MDA and TAC were measured. Results: The mean levels of salivary flow rate, pH, buffering capacity were significantly decreased (p < 0.05) and total protein, MDA and TAC were significantly increased (p < 0.05) in caries active children when compared to caries free controls. There was a proportionate decrease (p < 0.05) in salivary flow rate, pH and buffering capacity and proportionate increase (p > 0.05) in salivary total protein, MDA and TAC as DMFS/dfs score increased in caries active children. Conclusions: Significant alteration in the levels of salivary flow rate, pH, total proteins, MDA and TAC and their correlation with DMFS/dfs score in caries active children suggest, the levels of these physico-chemical properties of saliva can act as strong indicators of caries status in children.


2016 ◽  
Vol 30 (4) ◽  
pp. 401-414 ◽  
Author(s):  
Ewa Błońska ◽  
Kazimierz Januszek ◽  
Stanisław Małek ◽  
Tomasz Wanic

AbstractThe experimental plots used in the study were located in the middle forest zone (elevation: 900-950 m a.s.l.) on two nappes of the flysch Carpathians in southern Poland. The aim of this study was to assess the effects of serpentinite in combination with nitrogen, phosphorus, and potassium fertilizers on selected chemical properties of the soil and activity of dehydrogenase and urease in the studied soils. All fertilizer treatments significantly enriched the tested soils in magnesium. The use of serpentinite as a fertilizer reduced the molar ratio of exchangeable calcium to magnesium, which facilitated the uptake of magnesium by tree roots due to competition between calcium and magnesium. After one year of fertilization on the Wisła experimental plot, the pH of the Ofh horizon increased, while the pH of the mineral horizons significantly decreased. Enrichment of serpentinite with nitrogen, phosphorus, and potassium fertilizers stimulated the dehydrogenase activity in the studied organic horizon. The lack of a negative effect of the serpentinite fertilizer on enzyme activity in the spruce stand soil showed that the concentrations of the heavy metals added to the soil were not high enough to be toxic and indicated the feasibility of using this fertilizer in forestry.


2004 ◽  
Vol 68 (2) ◽  
pp. 662-668 ◽  
Author(s):  
A. R. Weaver ◽  
D. E. Kissel ◽  
F. Chen ◽  
L. T. West ◽  
W. Adkins ◽  
...  

2018 ◽  
Vol 63 (01) ◽  
pp. 63-68
Author(s):  
Efka Zabokova Bilbilova ◽  
Ana Sotirovska Ivkovska ◽  
Olivera Sarakinova ◽  
Olga Kokoceva Ivanovska ◽  
Natasha Stavreva

The aim of this study was to determine salivary pH, buffering capacity and calcium levels in caries-free and caries-active children. We examined 80 children of both genders, 15 years of age. Subjects were divided into four groups as follows: caries-free females, caries-active females, caries-free males, caries-active males; each group consisted of 20 subjects. The unstimulated saliva sample was collected by the spitting method and then pH, buffering capacity and calcium in saliva was measured. The results showed that mean level of buffering capacity of saliva was decreased significantly in the caries-active group as compared to caries-free group. The obtained data showed that the mean levels of pH and calcium were decreased in the caries-active group as compared to the caries-free group, but the difference was not statistically significant. The saliva with its constituents plays an important role in maintaining oral and especially dental health. Salivary pH values were found to be higher in the caries-free group. In our study, there was no significant correlation of pH values and caries activity with gender. Buffer capacity values were significantly lower in the caries-active group than in the caries-free group. There were significant differences when the groups were compared in the caries-active group where buffer capacity values were higher in boys than in girls. Calcium content of saliva was higher in the caries-free group. The results obtained in this study related to the values of the pH, buffering capacity and calcium in saliva, may serve as parameters for determining the caries risk patients, and accordingly to plan and carry appropriate caries preventive measures. Keywords: saliva, dental caries, pH, buffer capacity, calcium


Author(s):  
Zawawi Ibrahim ◽  
Aisyah Humaira Alias ◽  
Ridzuan Ramli ◽  
Noorshamsiana Abdul Wahab ◽  
Mansur Ahmad ◽  
...  

Studies on the manufacture of medium density fiberboard (MDF) from oil palm frond (OPF) fibre were conducted to provide a sustainable and feasible source of lignocellulosic materials. The quality and properties of the fibre are very important as it dictates the final MDF properties. The properties of fibre like fibre pH, buffering capacity, and morphology can influence most of the MDF performances. Refining condition is one of the most important factors which determine the properties of the refined fibre. In this study, the effects of different refining pressures and temperatures on OPF fibre were evaluated. The refining of OPF fibre was observed at four levels of refining parameters; which were categorized as low (2 bar at 130 °C), medium (4 bar at 150 °C), high (6 bar at 170 °C), and severe (8 bar at 190 °C). The refining heating time of 5 minutes was employed. The pH, buffering capacity, morphology, and the surface of the fibres were evaluated. The refined fibres were used to manufacture fibreboard panels at a target density of 720 kg/m3 and 12% urea formaldehyde (UF) resin. The panel's physical (thickness swelling) and mechanical properties (bending and internal bonding strength) were then evaluated according to European Standard (EN 622-5, 2006). The results indicated that refining conditions affected the properties of the fibres and final boards. High steam pressure and temperature-induced pH changes in OPF fibres, leading to more acidic fibres and greater acid buffering capacity. The fibre separation was more adequate at this level and produced fibre with a smooth surface. Based on the test results for fibreboard properties, high steam pressure and temperature produced better dimensional stability of panels and bending and bonding strength. However, at the highest refining condition (severe level), the board performances began to deteriorate. The best performances of the samples were found for the panels made under refining conditions of 6 bar at 170 °C.


HortScience ◽  
2016 ◽  
Vol 51 (9) ◽  
pp. 1153-1158 ◽  
Author(s):  
Matthew D. Taylor ◽  
Rachel Kreis ◽  
Lidia Rejtö

The pH of peatmoss generally ranges from 3.0 to 4.0 and limestone is typically added to raise pH to a suitable range. Compost is also used as a substrate component and typically has a high pH of 6.0 to 8.0. When using compost, lime rates must be reduced or eliminated. The two objectives of this study were to determine the resulting pH of substrates created with varying amounts of limestone and compost and assess the impact of the various amounts of limestone and compost on pH buffering capacity. Compost was created from a 1:1:1 weight ratio of a mixture of green plant material and restaurant food waste:horse manure:wood chips. The first experiment was a factorial design with five compost rates (0%, 10%, 20%, 30%, and 40% by volume), four limestone rates (0, 1.2, 2.4, and 3.6 g·L−1 substrate) with five replications. The experiment was conducted three times, each with a different batch of compost. With 0 lime, initial substrate pH increased from 4.5 to 6.7 as compost rate increased. This trend occurred at all other lime rates, which had pH ranges of 5.2–6.9, 5.6–7.0, and 6.1–7.1 for rates of 1.2, 2.4, and 3.6 g·L−1 substrate, respectively. Substrate pH increased significantly as either compost or lime rates increased. The second experiment was a factorial design with four compost rates by volume (0%, 10%, 20%, and 30%), the same four limestone rates as Expt. 1, and five replications. Each substrate treatment was titrated through incubations with six sulfuric acid rates (0, 0.1, 0.2, 0.4, or 0.7 mol of H+ per gram of dry substrate). Substrates with a similar initial pH had very similar buffering capacities regardless of the compost or limestone rate. These results indicate compost can be used to establish growing substrate pH similar to limestone, and this change will have little to no effect on pH buffering capacity.


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