scholarly journals Mitigation of Odor and Gaseous Emissions from Swine Barn with UV-A and UV-C Photocatalysis

Atmosphere ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 585
Author(s):  
Myeongseong Lee ◽  
Jacek A. Koziel ◽  
Wyatt Murphy ◽  
William S. Jenks ◽  
Baitong Chen ◽  
...  
Keyword(s):  
Air Pollutants ◽  
Scale Up ◽  
Dimethyl Disulfide ◽  
Isobutyric Acid ◽  
Gaseous Emissions ◽  
Swine Farm ◽  
Odor Character ◽  
Farm Scale ◽  
Economic Analyses ◽  
Uv C

UV-A (ca. 365 nm wavelength, a.k.a. ‘black light’) photocatalysis has been investigated to comprehensively mitigate odor and selected air pollutants in the livestock environment. This study was conducted to confirm the performance of UV-A photocatalysis on the swine farm. The objectives of this research were to (1) scale-up of the UV-A photocatalysis treatment, (2) evaluate the mitigation of odorous gases from swine slurry pit, (3) test different UV sources, (4) evaluate the effect of particulate matter (PM) and (5) conduct preliminary economic analyses. We tested UV-A photocatalysis at a mobile laboratory-scale capable of treating ~0.2–0.8 m3·s−1 of barn exhaust air. The targeted gaseous emissions of barn exhaust air were significantly mitigated (p < 0.05) up to 40% reduction of measured odor; 63%, 44%, 32%, 40%, 66% and 49% reduction of dimethyl disulfide, isobutyric acid, butanoic acid, p-cresol, indole and skatole, respectively; 40% reduction of H2S; 100% reduction of O3; and 13% reduction of N2O. The PM mitigation effect was not significant. Formaldehyde levels did not change, and a 21% generation of CO2 was observed. The percent reduction of targeted gases decreased as the airborne PM increased. Simultaneous chemical and sensory analysis confirmed that UV-A treatment changed the overall nuisance odor character of swine barn emissions into weaker manure odor with ‘toothpaste and ‘mint’ notes. The smell of benzoic acid generated in UV-A treatment was likely one of the compounds responsible for the less-offensive overall odor character of the UV-treated emissions. Results are needed to inform the design of a farm-scale trial, where the interior barn walls can be treated with the photocatalyst.

scholarly journals Mitigation of Odor and Gaseous Emissions from Swine Barn with UV-A and UV-C Photocatalysis

2021 ◽  
Author(s):  
Myeongseong Lee ◽  
Jacek A. Koziel ◽  
Wyatt Murphy ◽  
William S. Jenks ◽  
Baitong Chen ◽  
...  
Keyword(s):  
Scale Up ◽  
Dimethyl Disulfide ◽  
Isobutyric Acid ◽  
Gaseous Emissions ◽  
Swine Farm ◽  
Suspended Particulate ◽  
Odor Character ◽  
Farm Scale ◽  
Economic Analyses ◽  
Uv C

UV-A (ca. 365 nm wavelength, a.k.a. 'black light') photocatalysis has been investigated to comprehensively mitigate odor and selected air pollutants in the livestock environment. This study was conducted to confirm the performance of UV-A photocatalysis on the swine farm. The objectives of this research were to (1) scale-up of the UV-A photocatalysis treatment, (2) evaluate the mitigation of odorous gases from swine slurry pit, and (3) test different UV sources, (4) evaluate the effect of suspended particulate matter (PM), and (5) conduct preliminary economic analyses. We tested UV-A photocatalysis at a mobile laboratory-scale capable of treating ~0.2 - 0.8 m3&middot;s-1 of barn exhaust air. The targeted gaseous emissions of barn exhaust air were significantly mitigated (p &lt; 0.05) up to 40% reduction of measured odor; 63%, 44%, 32%, 40%, 66%, and 49% reduction of dimethyl disulfide, isobutyric acid, butanoic acid, p-cresol, indole, and skatole, respectively; 40% reduction of H2S; 100% reduction of O3; and 13% reduction of N2O. The PM mitigation effect was not significant. Formaldehyde levels did not change, and a 21% generation of CO2 was observed. The percent reduction of targeted gases decreased as the airborne PM increased. Simultaneous chemical and sensory analysis confirmed that UV-A treatment changed the overall nuisance odor character of swine barn emissions into weaker manure odor with 'toothpaste and 'mint' notes. The smell of benzoic acid generated in UV-A treatment was likely one of the compounds responsible for the less-offensive overall odor character of the UV-treated emissions. Results are needed to inform the design of a farm-scale trial, where the interior barn walls can be treated with the photocatalyst, and foul air will be passively treated as it moves through the barn.

scholarly journals Evaluation of TiO2 Based Photocatalytic Treatment of Odor and Gaseous Emissions From Swine Manure With UV-A and UV-C

2021 ◽  
Author(s):  
Myeongseong Lee ◽  
Jacek A. Koziel ◽  
Wyatt Murphy ◽  
William S. Jenks ◽  
Baitong Chen ◽  
...  
Keyword(s):  
Rural Communities ◽  
Treatment Effectiveness ◽  
Swine Manure ◽  
Pilot Scale ◽  
Gaseous Emissions ◽  
Uv Treatment ◽  
Uv Dose ◽  
Economic Analyses ◽  
Uv Technology ◽  
Uv C

It is essential to mitigate gaseous emissions that result from poultry and livestock production to increase industry sustainability. Odorous volatile organic compounds (VOCs), ammonia (NH3), hydrogen sulfide (H2S), and greenhouse gases (GHGs) have detrimental effects on the quality of life in rural communities, the environment, and climate. This study's objective was to evaluate the photocatalytic UV treatment of gaseous emissions of odor, odorous VOCs, NH3, and other gases (GHGs, O3 &ndash; sometimes considered as by-products of UV treatment) from stored swine manure on a pilot-scale. The manure emissions were treated in fast-moving air using a mobile lab equipped with UV-A and UV-C lights and TiO2-based photocatalyst. Treated gas airflow (0.25 to 0.76 m3/s) simulates output from a small ventilation fan in a barn. Through controlling the light intensity and airflow, UV dose was tested for techno-economic analyses. The treatment effectiveness depended on the UV dose and wavelength. Under UV-A (367 nm) photocatalysis, the percent reduction of targeted gases was up to i) 63% of odor, ii) 51%, 51%, 53%, 67%, and 32% of acetic acid, propanoic acid, butanoic acid, p-cresol, and indole, respectively, iii) 14% of nitrous oxide (N2O), iv) 100% of O3, and 26% generation of CO2. Under UV-C (185+254 nm) photocatalysis, the percent reductions of target gases were up to i) 54% and 47% for p-cresol and indole, respectively, ii) 25% of N2O, iii) 71% of CH4, and 46% &amp; 139% generation of CO2 &amp; O3, respectively. The results proved that the UV technology was sufficiently effective in treating odorous gases, and the mobile lab was ready for farm-scale trials. The UV technology can be considered for the scaled-up treatment of emissions and air quality improvement inside livestock barns.

scholarly journals Evaluation of TiO2 Based Photocatalytic Treatment of Odor and Gaseous Emissions from Swine Manure with UV-A and UV-C

Animals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1289
Author(s):  
Myeongseong Lee ◽  
Jacek A. Koziel ◽  
Wyatt Murphy ◽  
William S. Jenks ◽  
Baitong Chen ◽  
...  
Keyword(s):  
Rural Communities ◽  
Treatment Effectiveness ◽  
Swine Manure ◽  
Pilot Scale ◽  
Gaseous Emissions ◽  
Uv Treatment ◽  
Uv Dose ◽  
Economic Analyses ◽  
Uv Technology ◽  
Uv C

It is essential to mitigate gaseous emissions that result from poultry and livestock production to increase industry sustainability. Odorous volatile organic compounds (VOCs), ammonia (NH3), hydrogen sulfide (H2S), and greenhouse gases (GHGs) have detrimental effects on the quality of life in rural communities, the environment, and climate. This study’s objective was to evaluate the photocatalytic UV treatment of gaseous emissions of odor, odorous VOCs, NH3, and other gases (GHGs, O3—sometimes considered as by-products of UV treatment) from stored swine manure on a pilot-scale. The manure emissions were treated in fast-moving air using a mobile lab equipped with UV-A and UV-C lights and TiO2-based photocatalyst. Treated gas airflow (0.25–0.76 m3∙s−1) simulates output from a small ventilation fan in a barn. Through controlling the light intensity and airflow, UV dose was tested for techno-economic analyses. The treatment effectiveness depended on the UV dose and wavelength. Under UV-A (367 nm) photocatalysis, the percent reduction of targeted gases was up to (i) 63% of odor, (ii) 51%, 51%, 53%, 67%, and 32% of acetic acid, propanoic acid, butanoic acid, p-cresol, and indole, respectively, (iii) 14% of nitrous oxide (N2O), (iv) 100% of O3, and 26% generation of CO2. Under UV-C (185 + 254 nm) photocatalysis, the percent reductions of target gases were up to (i) 54% and 47% for p-cresol and indole, respectively, (ii) 25% of N2O, (iii) 71% of CH4, and 46% and 139% generation of CO2 and O3, respectively. The results proved that the UV technology was sufficiently effective in treating odorous gases, and the mobile lab was ready for farm-scale trials. The UV technology can be considered for the scaled-up treatment of emissions and air quality improvement inside livestock barns. Results from this study are needed to inform the experimental design for future on-farm research with UV-A and UV-C.

scholarly journals Mitigation of Gaseous Emissions from Swine Manure with the Surficial Application of Biochars

2020 ◽  
Author(s):  
Zhanibek Meiirkhanuly ◽  
Jacek A. Koziel ◽  
Baitong Chen ◽  
Andrzej Białowiec ◽  
Myeongseong Lee ◽  
...  
Keyword(s):  
Low Cost ◽  
Swine Manure ◽  
Animal Manure ◽  
Isobutyric Acid ◽  
Lessons Learned ◽  
Regulatory Agencies ◽  
Gaseous Emissions ◽  
Percent Reduction ◽  
Volatile Organic ◽  
The Impact

Environmental impact associated with odor and gaseous emissions from animal manure is one of the challenges for communities, farmers, and regulatory agencies. Microbe-based manure additives treatments are marketed and used by farmers for mitigation of emissions. However, their performance is difficult to assess objectively. Thus, comprehensive, practical, and low-cost treatments are still in demand. We have been advancing such treatments based on physicochemical principles. The objective of this research was to test the effect of the surficial application of a thin layer (&frac14;"; 6.3 mm) of biochar on the mitigation of gaseous emissions (as the percent reduction, % R) from swine manure. Two types of biochar were tested: highly alkaline and porous (HAP) biochar made from corn stover and red oak (RO), both with different pH and morphology. Three 30-day trials were conducted with a layer of HAP and RO (2.0 &amp; 1.65 kg∙m-2, respectively) applied on manure surface, and emissions of ammonia (NH3), hydrogen sulfide (H2S), greenhouse gases (GHG), and odorous volatile organic compounds (VOCs) were measured. The manure and biochar type and properties had an impact on the mitigation effect and its duration. RO significantly reduced NH3 (19-39%) and p-cresol (66-78%). H2S was mitigated (16~23%), but not significantly for all trials. Significant (66~78%) reductions for p-cresol were observed for all trials. The phenolic VOCs had relatively high % R in most trials but not significantly for all trials. HAP reduced NH3 (4~21%) and H2S (2~22%), but not significantly for all trials. Significant % R for p-cresol (91~97%) and skatole (74~95%) were observed for all trials. The % R for phenol and indole ranged from (60~99%) &amp; (29~94%) but was not significant for all trials. The impact on GHGs, isobutyric acid, and the odor was mixed with some mitigation and generation effects. However, larger-scale experiments are needed to understand how biochar properties and the dose and frequency of application can be optimized to mitigate odor and gaseous emissions from swine manure. The lessons learned can also be applicable to surficial biochar treatment of gaseous emissions from other waste and area sources.

scholarly journals Gaseous Emission from the Combustion of Dual Purpose Kerosene (DPK) from the Kaduna Refinery and Petroleum Company in Nigeria

2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Oluwaseun Adedayo O
Keyword(s):  
Crude Oil ◽  
Air Pollutants ◽  
Petroleum Products ◽  
Gaseous Emissions ◽  
Dual Purpose ◽  
Gaseous Emission ◽  
Acceptable Limit ◽  
Regulatory Bodies ◽  
Petroleum Company ◽  
Stationary Sources

Kaduna Refinery and Petroleum Company convert crude oil and other liquids into refined petroleum products. These petroleum products are used in our various homes as a source of energy but they can be a threat to human lives and the ecosystem. Gaseous emissions from the combustion of DPK of different volumes from Kaduna Refining were characterized for gaseous air pollutants using the E8500 combustion analyzer. The concentrations for the gaseous emission from the combustion of DPK were 34.92mg/m3 HC, 21.67mg/m3 CO, 89.00mg/m3 NOx for 10 ml. 41.47mg/m3 HC, 33.33mg/ m3 CO, 118.33mg/m3 NOx for 20 ml. 52.3 mg/m3 HC, 49.33mg/m3 CO, 183.33mg/m3 NOx for 30 ml. 50.20mg/m3 HC, 33.00mg/m3 CO, 189.33mg/m3 NOx for 40 ml. 61.12mg/m3 HC, 40.62mg/m3 CO, 199.00mg/m3 NOx , 2.6 mg/m3 SO2 for 50 ml. This study shows that CO and HC exceeded the acceptable limit for stationary sources while NOx and SO2 were below the acceptable limit. Hence, there is a need for rapid response and urgent attention from government and regulatory bodies to put in place policies that will help minimize the effect of these emissions.

scholarly journals VOC Removal from Manure Gaseous Emissions with UV Photolysis and UV-TiO2 Photocatalysis

Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 607 ◽  
Author(s):  
Xiuyan Yang ◽  
Jacek A. Koziel ◽  
Yael Laor ◽  
Wenda Zhu ◽  
J. (Hans) van Leeuwen ◽  
...  
Keyword(s):  
Treatment Effectiveness ◽  
Uv Light ◽  
Scale Up ◽  
Poultry Manure ◽  
Primary Treatment ◽  
Gaseous Emissions ◽  
Odor Removal ◽  
Odor Emissions ◽  
Livestock Odor ◽  
Uv Dose

Control of gaseous emissions from livestock operations is needed to ensure compliance with environmental regulations and sustainability of the industry. The focus of this research was to mitigate livestock odor emissions with UV light. Effects of the UV dose, wavelength, TiO2 catalyst, air temperature, and relative humidity were tested at lab scale on a synthetic mixture of nine odorous volatile organic compounds (VOCs) and real poultry manure offgas. Results show that it was feasible to control odorous VOCs with both photolysis and photocatalysis (synthetic VOCs mixture) and with photocatalysis (manure offgas). The treatment effectiveness R (defined as % conversion), was proportional to the light intensity for synthetic VOCs mixtures and followed an order of UV185+254 + TiO2 > UV254 + TiO2 > UV185+254; no catalyst > UV254; no catalyst. VOC conversion R > 80% was achieved when light energy was >~60 J L−1. The use of deep UV (UV185+254) improved the R, particularly when photolysis was the primary treatment. Odor removal up to ~80% was also observed for a synthetic VOCs mixture, and actual poultry manure offgas. Scale-up studies are warranted.

scholarly journals <i>Field-scale testing of mobile laboratory for mitigation of gaseous emissions from the swine farm with UV-A photocatalysis</i>

2021 ◽  
Author(s):  
Myeongseong Lee ◽  
Jacek A. Koziel ◽  
Wyatt Murphy ◽  
William Jenks ◽  
Baitong Chen ◽  
...  
Keyword(s):  
Gaseous Emissions ◽  
Mobile Laboratory ◽  
Field Scale ◽  
Swine Farm

scholarly journals Pyrolysis kinetic modelling of abundant plastic waste (PET) and in-situ emissions monitoring

2020 ◽  
Author(s):  
Ahmed I. Osman ◽  
Charlie Farrell ◽  
Ala'a H. Al-Muhtaseb ◽  
Ahmed S. Al-Fatesh ◽  
John Harrison ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Activation Energy ◽  
Kinetic Modelling ◽  
Degradation Mechanism ◽  
Scale Up ◽  
Plastic Waste ◽  
Gaseous Emissions ◽  
Low Carbon ◽  
Pyrolysis Process

Abstract Background: Recycling the ever-increasing plastic waste has become an urgent global concern. One of the most convenient methods for plastic recycling is pyrolysis, owing to its environmentally friendly nature and its intrinsic properties. Understanding the pyrolysis process and the degradation mechanism is crucial for scale-up and reactor design. Therefore, we studied kinetic modelling of the pyrolysis process for one of the most common plastics, polyethylene terephthalate (PET). The focus was to better understand and predict PET pyrolysis when transitioning to a low carbon economy and adhering to environmental and governmental legislation. This work aims at presenting for the first time, the kinetic triplet (activation energy, pre-exponential constant and reaction rate) for the PET pyrolysis using the differential iso-conversional method. This is coupled with the in-situ online tracking of the gaseous emissions using mass spectrometry.Results: The differential iso-conversional method showed activation energy (Ea) values of 165-195 kJ.mol-1, R2 = 0.99659. While the ASTM-E698 showed 165.6 kJ.mol-1 and integral methods such as Flynn-Wall and Ozawa (FWO) (166-180 kJ.mol-1). The in-situ Mass Spectrometry results showed the pyrolysis gaseous emissions which are C1-hydrocarbon and H-O-C=O along with C2 hydrocarbons, C5- C6 hydrocarbons, acetaldehyde, the fragment of O-CH=CH2, hydrogen and water. Conclusions: From the obtained results herein, thermal predictions (isothermal, non-isothermal and step-based heating) were determined based on the kinetic parameters and can be used at numerous scales with a high level of accuracy compared with the literature.

scholarly journals Is scaling-up COVID-19 testing cost-saving?

2020 ◽  
Author(s):  
Bernardo Sousa-Pinto ◽  
João Almeida Fonseca ◽  
Altamiro Costa-Pereira ◽  
Francisco Nuno Rocha-Gonçalves
Keyword(s):  
Cost Saving ◽  
Large Scale ◽  
Scale Up ◽  
Scaling Up ◽  
World Health ◽  
Hospitalization Costs ◽  
Testing Cost ◽  
Additional Costs ◽  
Economic Analyses ◽  
Health Organization

The World Health Organization currently recommends that governments scale up testing for COVID-19 infection. We performed health economic analyses projecting whether the additional costs from screening would be offset by the avoided costs with hospitalizations. We analysed Portuguese COVID-19 data up until the 22nd March 2020, and estimated the additional number of cases that would be detected if different testing rates and frequencies of positive results would have been observed. We projected that, in most scenarios, the costs with scaling up COVID-19 tests would be lower than savings with hospitalization costs, rendering large scale testing cost-saving.

scholarly journals Mitigation of Gaseous Emissions from Swine Manure with the Surficial Application of Biochars

Atmosphere ◽  
2020 ◽  
Vol 11 (11) ◽  
pp. 1179 ◽  
Author(s):  
Zhanibek Meiirkhanuly ◽  
Jacek A. Koziel ◽  
Baitong Chen ◽  
Andrzej Białowiec ◽  
Myeongseong Lee ◽  
...  
Keyword(s):  
Low Cost ◽  
Swine Manure ◽  
Animal Manure ◽  
Isobutyric Acid ◽  
Lessons Learned ◽  
Regulatory Agencies ◽  
Gaseous Emissions ◽  
Percent Reduction ◽  
Volatile Organic ◽  
The Impact

Environmental impact associated with odor and gaseous emissions from animal manure is one of the challenges for communities, farmers, and regulatory agencies. Microbe-based manure additives treatments are marketed and used by farmers for mitigation of emissions. However, their performance is difficult to assess objectively. Thus, comprehensive, practical, and low-cost treatments are still in demand. We have been advancing such treatments based on physicochemical principles. The objective of this research was to test the effect of the surficial application of a thin layer (¼ inches; 6.3 mm) of biochar on the mitigation of gaseous emissions (as the percent reduction, % R) from swine manure. Two types of biochar were tested: highly alkaline and porous (HAP) biochar made from corn stover and red oak (RO), both with different pH and morphology. Three 30-day trials were conducted with a layer of HAP and RO (2.0 & 1.65 kg∙m−2, respectively) applied on manure surface, and emissions of ammonia (NH3), hydrogen sulfide (H2S), greenhouse gases (GHG), and odorous volatile organic compounds (VOCs) were measured. The manure and biochar type and properties had an impact on the mitigation effect and its duration. RO significantly reduced NH3 (19–39%) and p-cresol (66–78%). H2S was mitigated (16~23%), but not significantly for all trials. The phenolic VOCs had relatively high % R in most trials but not significantly for all trials. HAP reduced NH3 (4~21%) and H2S (2~22%), but not significantly for all trials. Significant % R for p-cresol (91~97%) and skatole (74~95%) were observed for all trials. The % R for phenol and indole ranged from (60~99%) and (29~94%) but was not significant for all trials. The impact on GHGs, isobutyric acid, and the odor was mixed with some mitigation and generation effects. However, larger-scale experiments are needed to understand how biochar properties and the dose and frequency of application can be optimized to mitigate odor and gaseous emissions from swine manure. The lessons learned can also be applicable to surficial biochar treatment of gaseous emissions from other waste and area sources.

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