scholarly journals Mitigation of Gaseous Emissions from Swine Manure with the Surficial Application of Biochars

2020 ◽  
Author(s):  
Zhanibek Meiirkhanuly ◽  
Jacek A. Koziel ◽  
Baitong Chen ◽  
Andrzej Białowiec ◽  
Myeongseong Lee ◽  
...  
Keyword(s):  
Low Cost ◽  
Swine Manure ◽  
Animal Manure ◽  
Isobutyric Acid ◽  
Lessons Learned ◽  
Regulatory Agencies ◽  
Gaseous Emissions ◽  
Percent Reduction ◽  
Volatile Organic ◽  
The Impact

Environmental impact associated with odor and gaseous emissions from animal manure is one of the challenges for communities, farmers, and regulatory agencies. Microbe-based manure additives treatments are marketed and used by farmers for mitigation of emissions. However, their performance is difficult to assess objectively. Thus, comprehensive, practical, and low-cost treatments are still in demand. We have been advancing such treatments based on physicochemical principles. The objective of this research was to test the effect of the surficial application of a thin layer (¼"; 6.3 mm) of biochar on the mitigation of gaseous emissions (as the percent reduction, % R) from swine manure. Two types of biochar were tested: highly alkaline and porous (HAP) biochar made from corn stover and red oak (RO), both with different pH and morphology. Three 30-day trials were conducted with a layer of HAP and RO (2.0 & 1.65 kg∙m-2, respectively) applied on manure surface, and emissions of ammonia (NH3), hydrogen sulfide (H2S), greenhouse gases (GHG), and odorous volatile organic compounds (VOCs) were measured. The manure and biochar type and properties had an impact on the mitigation effect and its duration. RO significantly reduced NH3 (19-39%) and p-cresol (66-78%). H2S was mitigated (16~23%), but not significantly for all trials. Significant (66~78%) reductions for p-cresol were observed for all trials. The phenolic VOCs had relatively high % R in most trials but not significantly for all trials. HAP reduced NH3 (4~21%) and H2S (2~22%), but not significantly for all trials. Significant % R for p-cresol (91~97%) and skatole (74~95%) were observed for all trials. The % R for phenol and indole ranged from (60~99%) & (29~94%) but was not significant for all trials. The impact on GHGs, isobutyric acid, and the odor was mixed with some mitigation and generation effects. However, larger-scale experiments are needed to understand how biochar properties and the dose and frequency of application can be optimized to mitigate odor and gaseous emissions from swine manure. The lessons learned can also be applicable to surficial biochar treatment of gaseous emissions from other waste and area sources.

scholarly journals Mitigation of Gaseous Emissions from Swine Manure with the Surficial Application of Biochars

Atmosphere ◽  
2020 ◽  
Vol 11 (11) ◽  
pp. 1179 ◽  
Author(s):  
Zhanibek Meiirkhanuly ◽  
Jacek A. Koziel ◽  
Baitong Chen ◽  
Andrzej Białowiec ◽  
Myeongseong Lee ◽  
...  
Keyword(s):  
Low Cost ◽  
Swine Manure ◽  
Animal Manure ◽  
Isobutyric Acid ◽  
Lessons Learned ◽  
Regulatory Agencies ◽  
Gaseous Emissions ◽  
Percent Reduction ◽  
Volatile Organic ◽  
The Impact

Environmental impact associated with odor and gaseous emissions from animal manure is one of the challenges for communities, farmers, and regulatory agencies. Microbe-based manure additives treatments are marketed and used by farmers for mitigation of emissions. However, their performance is difficult to assess objectively. Thus, comprehensive, practical, and low-cost treatments are still in demand. We have been advancing such treatments based on physicochemical principles. The objective of this research was to test the effect of the surficial application of a thin layer (¼ inches; 6.3 mm) of biochar on the mitigation of gaseous emissions (as the percent reduction, % R) from swine manure. Two types of biochar were tested: highly alkaline and porous (HAP) biochar made from corn stover and red oak (RO), both with different pH and morphology. Three 30-day trials were conducted with a layer of HAP and RO (2.0 & 1.65 kg∙m−2, respectively) applied on manure surface, and emissions of ammonia (NH3), hydrogen sulfide (H2S), greenhouse gases (GHG), and odorous volatile organic compounds (VOCs) were measured. The manure and biochar type and properties had an impact on the mitigation effect and its duration. RO significantly reduced NH3 (19–39%) and p-cresol (66–78%). H2S was mitigated (16~23%), but not significantly for all trials. The phenolic VOCs had relatively high % R in most trials but not significantly for all trials. HAP reduced NH3 (4~21%) and H2S (2~22%), but not significantly for all trials. Significant % R for p-cresol (91~97%) and skatole (74~95%) were observed for all trials. The % R for phenol and indole ranged from (60~99%) and (29~94%) but was not significant for all trials. The impact on GHGs, isobutyric acid, and the odor was mixed with some mitigation and generation effects. However, larger-scale experiments are needed to understand how biochar properties and the dose and frequency of application can be optimized to mitigate odor and gaseous emissions from swine manure. The lessons learned can also be applicable to surficial biochar treatment of gaseous emissions from other waste and area sources.

scholarly journals Mitigation of Gaseous Emissions from Swine Manure with the Surficial Application of Biochars

2020 ◽  
Author(s):  
Zhanibek Meiirkhanuly ◽  
Jacek A. Koziel ◽  
Baitong Chen ◽  
Andrzej Białowiec ◽  
Myeongseong Lee ◽  
...  
Keyword(s):  
Hydrogen Sulfide ◽  
Environmental Impact ◽  
Low Cost ◽  
Swine Manure ◽  
Animal Manure ◽  
Lessons Learned ◽  
Regulatory Agencies ◽  
Gaseous Emissions ◽  
Volatile Organic ◽  
Reduce Emissions

Environmental impact associated with odor and gaseous emissions from animal manure is one of the challenges for communities, farmers, and regulatory agencies. Microbe-based manure additives treatments are marketed and used by farmers for mitigation of emissions. However, their performance is difficult to assess objectively. Thus, a comprehensive, practical, and low-cost treatments are still in demand. We have been advancing such treatments based on physicochemical principles. The objective of this research was to test the effect of the surficial application of a thin layer (¼"; 6.3 mm) of biochar on the mitigation of gaseous emissions from swine manure. Two types of biochar were tested: highly alkaline and porous (HAP) biochar made from corn stover and red oak (RO), both with different pH and morphology. Three 30-day trials were conducted with a layer of HAP and RO (2.0 & 1.65 kg∙m-2, respectively) applied on manure surface, and emissions of ammonia (NH3), hydrogen sulfide (H2S), greenhouse gases (GHG), and odorous volatile organic compounds (VOCs) were measured. A significant reduction of NH3 and phenol emissions was observed. In the case of H2S, CH4, CO2, N2O, and other odorous VOCs, the biochar treatment reduced the emissions during the first 1~2 weeks, followed by either no effect or even (in some cases) increase of emissions. Based on this initial lab-scale testing, biochar is promising to be an effective, practical, and economical treatment to reduce emissions from stored swine manure. However, larger-scale experiments are needed to understand how biochar properties and the dose and frequency of application can be optimized to mitigate odor and gaseous emissions from swine manure. The lessons learned can also be applicable to consider using biochar for surficial applications to mitigate gaseous emissions from other types of waste and area sources.

scholarly journals The Impact of Surficial Biochar Treatment on Acute H2S Emissions during Swine Manure Agitation before Pump-Out: Proof-of-the-Concept

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 940 ◽  
Author(s):  
Baitong Chen ◽  
Jacek A. Koziel ◽  
Andrzej Białowiec ◽  
Myeongseong Lee ◽  
Hantian Ma ◽  
...  
Keyword(s):  
Inhalation Exposure ◽  
Swine Manure ◽  
Carbonaceous Material ◽  
Land Application ◽  
Gaseous Emissions ◽  
Total Emission ◽  
Initial State ◽  
H2s Emission ◽  
The Impact

Acute releases of hydrogen sulfide (H2S) are of serious concern in agriculture, especially when farmers agitate manure to empty storage pits before land application. Agitation can cause the release of dangerously high H2S concentrations, resulting in human and animal fatalities. To date, there is no proven technology to mitigate these short-term releases of toxic gas from manure. In our previous research, we have shown that biochar, a highly porous carbonaceous material, can float on manure and mitigate gaseous emissions over extended periods (days–weeks). In this research, we aim to test the hypothesis that biochar can mitigate H2S emissions over short periods (minutes–hours) during and shortly after manure agitation. The objective was to conduct proof-of-the-concept experiments simulating the treatment of agitated manure. Two biochars, highly alkaline and porous (HAP, pH 9.2) made from corn stover and red oak (RO, pH 7.5), were tested. Three scenarios (setups): Control (no biochar), 6 mm, and 12 mm thick layers of biochar were surficially-applied to the manure. Each setup experienced 3 min of manure agitation. Real-time concentrations of H2S were measured immediately before, during, and after agitation until the concentration returned to the initial state. The results were compared with those of the Control using the following three metrics: (1) the maximum (peak) flux, (2) total emission from the start of agitation until the concentration stabilized, and (3) the total emission during the 3 min of agitation. The Gompertz’s model for determination of the cumulative H2S emission kinetics was developed. Here, 12 mm HAP biochar treatment reduced the peak (1) by 42.5% (p = 0.125), reduced overall total emission (2) by 17.9% (p = 0.290), and significantly reduced the total emission during 3 min agitation (3) by 70.4%. Further, 6 mm HAP treatment reduced the peak (1) by 60.6%, and significantly reduced overall (2) and 3 min agitation’s (3) total emission by 64.4% and 66.6%, respectively. Moreover, 12 mm RO biochar treatment reduced the peak (1) by 23.6%, and significantly reduced overall (2) and 3 min total (3) emission by 39.3% and 62.4%, respectively. Finally, 6 mm RO treatment significantly reduced the peak (1) by 63%, overall total emission (2) by 84.7%, and total emission during 3 min agitation (3) by 67.4%. Biochar treatments have the potential to reduce the risk of inhalation exposure to H2S. Both 6 and 12 mm biochar treatments reduced the peak H2S concentrations below the General Industrial Peak Limit (OSHA PEL, 50 ppm). The 6 mm biochar treatments reduced the H2S concentrations below the General Industry Ceiling Limit (OSHA PEL, 20 ppm). Research scaling up to larger manure volumes and longer agitation is warranted.

scholarly journals AVIATOR - Assessing aViation emission Impact on local Air quality at airports: TOwards Regulation

2019 ◽  
Vol 304 ◽  
pp. 02023
Author(s):  
Víctor Archilla ◽  
Dévora Hormigo ◽  
María Sánchez-García ◽  
David Raper
Keyword(s):  
Air Quality ◽  
Low Cost ◽  
Aircraft Engine ◽  
Climatic Conditions ◽  
Test Cell ◽  
Gaseous Emissions ◽  
Aircraft Emissions ◽  
Gaseous Species ◽  
Assessment Approach ◽  
The Impact

Emissions from aircraft have adverse effects on the air quality in and around airports, contributing to public health concerns within neighbouring communities. AVIATOR will adopt a multi-level measurement, modelling and assessment approach to develop an improved description and quantification of the relevant aircraft engine emissions, and their impact on air quality under different climatic conditions. Particulate and gaseous emissions in a test cell and on-wing from an in-service aircraft will be measured to determine pollutant plume evolution from the engine and APU exhaust. This will provide an enhanced understanding of primary emitted pollutants, specifically the nvPM and vPM (down to 10nm), and the scalability between the regulatory test cell and real environments. AVIATOR will develop and deploy a proof-of-concept low cost sensor network for monitoring UFP, PM and gaseous species across multiple airports and surrounding communities. Campaigns will be complemented by high-fidelity modelling of aircraft exhaust dynamics, microphysical and chemical processes within the plume. CFD, box, and airport air quality models will be applied, providing validated parameterisations of the relevant processes, applicable to standard dispersion modelling on the local scale. Working with the regulatory community, AVIATOR will develop improved guidance on measuring and modelling the impact of aircraft emissions, and will provide airports and regulators with tools and guidance to improve the assessment of air quality in and around airports.

scholarly journals An Integrated System for Simultaneous Monitoring of Traffic and Pollution Concentration—Lessons Learned for Bielsko-Biała, Poland

Energies ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 8028
Author(s):  
Krzysztof Brzozowski ◽  
Artur Ryguła ◽  
Andrzej Maczyński
Keyword(s):  
Air Quality ◽  
Meteorological Data ◽  
Low Cost ◽  
Background Level ◽  
Lessons Learned ◽  
Integrated System ◽  
Network Information ◽  
Transit Times ◽  
Pm2.5 And Pm10 ◽  
The Impact

The challenge of maintaining the required level of mobility and air quality in cities can be met by deploying an appropriate management system in which the immediate vicinity of roads is monitored to identify potential pollution hotspots. This paper presents an integrated low-cost system which can be used to study the impact of traffic related emission on air quality at intersections. The system was used for three months in 2017 at five locations covering intersections in the centre of a mid-sized city. Depending on the location, pollution hotspots with high PM2.5 and PM10 concentrations occurred 5–10% of the time. It was shown that despite the close mutual proximity of the locations, traffic and the immediate surroundings lead to significant variation in air quality. At locations with adverse ventilation conditions a tendency towards more frequent occurrences of moderate and sufficient air quality was observed than at other locations (even those with more traffic). Based on the results, a practical extension of the system was also proposed by formulating a model for the prediction of PM2.5 concentration using a neural network. Information on transit times, meteorological data and the background level of PM10 concentration were used as model input parameters.

SEAR JIP: the value of sharing of lessons learned on subsea integrity and reliability

2019 ◽  
Vol 59 (2) ◽  
pp. 767
Author(s):  
Adriana Botto
Keyword(s):  
Value Chain ◽  
Oil And Gas ◽  
Low Cost ◽  
Cost Savings ◽  
Lessons Learned ◽  
Equipment Reliability ◽  
Award Winning ◽  
The Impact ◽  
Oil And Gas Sector ◽  
Geographical Locations

The award-winning Subsea Equipment Australian Reliability (SEAR) Joint Industry Project (JIP) is a partnership led by Wood and has participation of a group of OGAS Operators namely Chevron Australia, ConocoPhillips, Inpex, Quadrant, Shell Australia and Woodside. Now delivering Phase 6, the JIP is focused on collaboration and knowledge sharing, so as to improve the competitiveness of Australia’s oil and gas sector by addressing critical challenges associated with equipment that is failing prematurely subsea. The SEAR JIP was initiated in 2014 and has since developed a reliability database to collect failure information from SEAR members with Australian offshore operations. The SEAR database provides a low cost–high value method of capturing and sharing failures and lessons learnt for Australia. Over the years, the JIP has focused on different but common industry challenges, such as the impact of marine fouling affecting operability during interventions. To address this challenge, the JIP is deploying ‘living laboratories’ at different geographical locations and water depths across various Australian waters, in collaboration with suppliers and local universities to identify game-changing technology. The ability to better understand failures and intervention requirements has the potential to offer operators significant cost savings, by optimising equipment reliability and availability. This paper will provide an overview of SEAR JIP and outlines lessons learned and value created, and discusses how a similar collaborative approach can create value in other parts of the Australian LNG value chain.

scholarly journals Lessons Learned: Occupational Therapy in Nursing Homes during the First Wave of COVID-19 in Spain

Healthcare ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 117
Author(s):  
Sara Chimento-Díaz ◽  
Isabel Espino-Tato ◽  
Jose M. Garcia-Alonso ◽  
Pablo A. Cantero-Garlito
Keyword(s):  
Occupational Therapy ◽  
Low Cost ◽  
Elderly Care ◽  
Occupational Therapists ◽  
Comparison Method ◽  
Lessons Learned ◽  
Therapeutic Interventions ◽  
Structured Interviews ◽  
Care Facilities ◽  
The Impact

This research aims to explore the perception that occupational therapists working in elderly care facilities have about the measures implemented against the COVID-19 pandemic in their resources, and the impact that these measures have had on occupational therapy in these facilities. An interpretive paradigm was selected, using a qualitative approach and a phenomenological design. Sixteen occupational therapists working in elderly care facilities in two Spanish regions were included. Data were collected through semi-structured interviews. A discourse analysis of the narrative information was carried out using open, axial, and selective coding processes and the constant comparison method. Four themes were extracted from the analysis results: The initial chaos in senior centers; The blurring of occupational therapists’ roles; The emergence of technology; and organizational and therapeutic proposals for future pandemics. The pandemic had a significant impact on the care and therapeutic processes in elderly care facilities. Occupational therapists had to stop performing their functions to dedicate themselves to other support, auxiliary or communication tasks between the center and the families. Similarly, it is worth noting the emergence of low-cost technology to facilitate communication and to carry out some therapeutic interventions.

scholarly journals Configuration of the Volatile Aromatic Profile of Carob Powder Milled From Pods of Genetic Variants Harvested at Progressive Stages of Ripening From High and Low Altitudes

2021 ◽  
Vol 8 ◽  
Author(s):  
Chrystalla Antoniou ◽  
Angelos C. Kyratzis ◽  
Georgios A. Soteriou ◽  
Youssef Rouphael ◽  
Marios C. Kyriacou
Keyword(s):  
Sensory Quality ◽  
Isobutyric Acid ◽  
Influential Factor ◽  
Processed Foods ◽  
Lower Altitude ◽  
Fruit Maturity ◽  
Carob Powder ◽  
Volatile Organic ◽  
The Impact

Carob powder is increasingly valued as a substitute for cocoa and as a flavor-enhancing component of processed foods. However, little is known about the impact of preharvest factors such as fruit maturity, genotype and altitude on its volatile organic compounds (VOCs) composition. The current study examined the VOCs composition of powder milled from pods of two genotypes cultivated at 15 and 510 m altitude and harvested at six progressive stages of maturity, ranging from fully developed immature green (RS1) to late ripe (RS6). Fifty-six VOCs categorized into acids, esters, aldehydes, ketones, alcohols, furans, and alkanes were identified through HS-SPME GC-MS analysis. Maturity was the most influential factor, followed by altitude and least by genotype. Aldehydes and alcohols correlated positively (r = 0.789; p < 0.001), both accumulated in immature carobs and decreased with progressive ripening, resulting in the attenuation of green grassy aroma. Conversely, acids increased with ripening and dominated the carob volatilome at full maturity, correlating negatively with aldehydes and alcohols (r = −0.835 and r = −0.950, respectively; p < 0.001). The most abundant VOC throughout ripening (17.3-57.7%) was isobutyric acid, responsible for the characteristic cheesy-acidic-buttery aroma of carob powder. The pleasurable aroma detected at the immature stages (RS2 and RS3) was traced to isobutyrate and methyl isobutyrate esters, rendering unripe green carob powder a potential admixture component for improving the aroma of novel food products. Lower altitude favored the accumulation of acids linked to less pleasant aroma, whereas isobutyric acid was more abundant at higher altitude. This constitutes a significant indication that higher altitude enhances the characteristic carob-like aroma and sensory quality of carob powder.

Shock loading in biofilters: impact on biodegradation activity distribution and resilience capacity

2009 ◽  
Vol 59 (7) ◽  
pp. 1307-1314 ◽  
Author(s):  
L. Cabrol ◽  
L. Malhautier ◽  
F. Poly ◽  
A. S. Lepeuple ◽  
J. L. Fanlo
Keyword(s):  
High Efficiency ◽  
Complete Removal ◽  
Pilot Scale ◽  
Longitudinal Distribution ◽  
Gaseous Emissions ◽  
Contaminant Removal ◽  
Biomass Density ◽  
Volatile Organic ◽  
Gaseous Stream ◽  
The Impact

A synthetic contaminated gas was generated, representative of gaseous emissions from sludge composting. It was composed of six volatile organic compounds (aldehyde, ketones, esters, sulphur compound) in an ammoniacal matrix. The gaseous stream was purified by biofiltration, in pilot scale biofilters filled with pine bark woodchips as organic carrier for biomass colonization. After reaching a constant high efficiency, with complete removal, the system was disturbed by transient loading shocks. The impact of perturbations was assessed by both performance evaluation (i.e. contaminant removal) and microbial behaviour. The microbial community was analysed in terms of density. The resilience of functional component following a perturbation was evaluated. This work highlighted the longitudinal distribution of both biodegradation activities and biomass density.

Computer simulation study about the dependence of amorphous silicon photonic waveguides efficiency on the material quality

2020 ◽  
Vol 90 (3) ◽  
pp. 30502
Author(s):  
Alessandro Fantoni ◽  
João Costa ◽  
Paulo Lourenço ◽  
Manuela Vieira
Keyword(s):  
Amorphous Silicon ◽  
High Throughput Screening ◽  
Simulation Analysis ◽  
Low Cost ◽  
Deposition Process ◽  
Large Area ◽  
Sidewall Roughness ◽  
Sensing Applications ◽  
Fabrication Defects ◽  
The Impact

Amorphous silicon PECVD photonic integrated devices are promising candidates for low cost sensing applications. This manuscript reports a simulation analysis about the impact on the overall efficiency caused by the lithography imperfections in the deposition process. The tolerance to the fabrication defects of a photonic sensor based on surface plasmonic resonance is analysed. The simulations are performed with FDTD and BPM algorithms. The device is a plasmonic interferometer composed by an a-Si:H waveguide covered by a thin gold layer. The sensing analysis is performed by equally splitting the input light into two arms, allowing the sensor to be calibrated by its reference arm. Two different 1 × 2 power splitter configurations are presented: a directional coupler and a multimode interference splitter. The waveguide sidewall roughness is considered as the major negative effect caused by deposition imperfections. The simulation results show that plasmonic effects can be excited in the interferometric waveguide structure, allowing a sensing device with enough sensitivity to support the functioning of a bio sensor for high throughput screening. In addition, the good tolerance to the waveguide wall roughness, points out the PECVD deposition technique as reliable method for the overall sensor system to be produced in a low-cost system. The large area deposition of photonics structures, allowed by the PECVD method, can be explored to design a multiplexed system for analysis of multiple biomarkers to further increase the tolerance to fabrication defects.

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