scholarly journals Asymmetric Fiber Supercapacitors Based on a FeC2O4/FeOOH-CNT Hybrid Material

2021 ◽  
Vol 7 (3) ◽  
pp. 62
Author(s):  
Paa Kwasi Adusei ◽  
Kevin Johnson ◽  
Sathya N. Kanakaraj ◽  
Guangqi Zhang ◽  
Yanbo Fang ◽  
...  

The development of new flexible and lightweight electronics has increased the demand for compatible energy storage devices to power them. Carbon nanotube (CNT) fibers have long been known for their ability to be assembled into yarns, offering their integration into electronic devices. They are hindered, however, by their low intrinsic energy storage properties. Herein, we report a novel composite yarn, synthesized through solvothermal processes, that attained energy densities in the range between 0.17 µWh/cm2 and 3.06 µWh/cm2, and power densities between 0.26 mW/cm2 and 0.97 mW/cm2, when assembled in a supercapacitor with a PVDF-EMIMBF4 electrolyte. The created unique composition of iron oxalate + iron hydroxide + CNT as an anode worked well in synergy with the much-studied PANI + CNT cathode, resulting in a highly stable yarn energy storage device that maintained 96.76% of its energy density after 4000 cycles. This device showed no observable change in performance under stress/bend tests which makes it a viable candidate for powering wearable electronics.

2018 ◽  
Vol 5 (8) ◽  
pp. 1805-1815 ◽  
Author(s):  
Wenda Qiu ◽  
Hongbing Xiao ◽  
Wenting He ◽  
Yu Li ◽  
Yexiang Tong

With the rapid development of portable and wearable electronics, energy storage devices featuring high energy and power densities, long-cycle lifetime, environment friendliness, safe operation, lightweight, ultrathin thickness and flexibilityl have become increasingly important.


Nanoscale ◽  
2018 ◽  
Vol 10 (40) ◽  
pp. 19004-19013 ◽  
Author(s):  
Pengxiao Sun ◽  
Weidong He ◽  
Hongcen Yang ◽  
Ruya Cao ◽  
Jiangmei Yin ◽  
...  

High-security deformable energy-storage devices that are mechanically robust, with considerable energy and power densities are becoming desirable for smart wearable electronics.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4000
Author(s):  
Eunhwan Kim ◽  
Juyeon Han ◽  
Seokgyu Ryu ◽  
Youngkyu Choi ◽  
Jeeyoung Yoo

For decades, improvements in electrolytes and electrodes have driven the development of electrochemical energy storage devices. Generally, electrodes and electrolytes should not be developed separately due to the importance of the interaction at their interface. The energy storage ability and safety of energy storage devices are in fact determined by the arrangement of ions and electrons between the electrode and the electrolyte. In this paper, the physicochemical and electrochemical properties of lithium-ion batteries and supercapacitors using ionic liquids (ILs) as an electrolyte are reviewed. Additionally, the energy storage device ILs developed over the last decade are introduced.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jing Hu ◽  
Xiaomin Tang ◽  
Qing Dai ◽  
Zhiqiang Liu ◽  
Huamin Zhang ◽  
...  

AbstractMembranes with fast and selective ions transport are highly demanded for energy storage devices. Layered double hydroxides (LDHs), bearing uniform interlayer galleries and abundant hydroxyl groups covalently bonded within two-dimensional (2D) host layers, make them superb candidates for high-performance membranes. However, related research on LDHs for ions separation is quite rare, especially the deep-going study on ions transport behavior in LDHs. Here, we report a LDHs-based composite membrane with fast and selective ions transport for flow battery application. The hydroxide ions transport through LDHs via vehicular (standard diffusion) & Grotthuss (proton hopping) mechanisms is uncovered. The LDHs-based membrane enables an alkaline zinc-based flow battery to operate at 200 mA cm−2, along with an energy efficiency of 82.36% for 400 cycles. This study offers an in-depth understanding of ions transport in LDHs and further inspires their applications in other energy-related devices.


Author(s):  
Sergey I. Shkuratov ◽  
Jason Baird ◽  
Vladimir G. Antipov ◽  
Christopher S. Lynch ◽  
Shujun Zhang ◽  
...  

The search for ferroelectric materials capable of producing high electric charge and power densities is important for developing a new generation of ultrahigh-power-density ferroelectric energy storage devices and autonomous megawatt power supplies.


2020 ◽  
Author(s):  
Jing Hu ◽  
Xiaomin Tang ◽  
Qing Dai ◽  
Zhiqiang Liu ◽  
Huamin Zhang ◽  
...  

Abstract Membranes with fast and selective ions transport are highly demanded for energy storage devices. Layered double hydroxides (LDHs), bearing uniform interlayer galleries and abundant hydroxyl groups covalently bonded within two-dimensional (2D) host layers, make them superb candidates for high-performance membranes. However, related research on LDHs for ions separation is quite rare, especially the deep-going study on ions transport behavior in LDHs. Here, we report a LDHs-based composite membrane with fast and selective ions transport for flow battery application. The hydroxide ions transport through LDHs via vehicular (standard diffusion) & Grotthuss (proton hopping) mechanisms is uncovered. The LDHs-based membrane enables an alkaline zinc-based flow battery to operate at 200 mA cm− 2, along with an energy efficiency of 82.36% for 400 cycles, which is among the highest efficiencies for zinc-based flow batteries. This study offers an in-depth understanding of ions transport in LDHs and further inspires their applications in other energy-related devices.


2021 ◽  
Author(s):  
Muhammad Irfan ◽  
Xianhua Liu ◽  
Suraya Mushtaq ◽  
Jonnathan Cabrera ◽  
Pingping Zhang

Abstract Development of sustainable electrochemical energy storage devices faces great challenge in exploring highly efficient and low cost electrode materials. Biomass waste derived carbonaceous materials can be used as an alternative to expensive metals in supercapacitor. However, their application limited by low performance. In this study, the combination use of persimmon waste derived carbon and transition metal nitride demonstrated strong potential for supercapacitor application. Persimmon based carbonaceous gel decorated with bimetallic-nitride (N-NiCo/PC) was firstly synthesized through a green hydrothermal method. Electrochemical properties of N-NiCo/PC as electrode in 6 M KOH electrolyte solution were evaluated by using cyclic voltammetry (CV) and charge-discharge measurements. The N-NiCo/PC exhibited 895.5 F/g specific capacitance at 1 A/g current density and maintained 91.5% capacitance retention after 900 cycles. Hence, the bimetallic nitride-based-composite catalyst is a potentially suitable material for high-performance energy storage devices. In addition, this work demonstrated a promising pathway for transforming environmental waste into sustainable energy conversion materials.


2022 ◽  
Vol 9 ◽  
Author(s):  
Adriana M. Navarro-Suárez ◽  
Milo S. P. Shaffer

Structural energy storage devices (SESDs), designed to simultaneously store electrical energy and withstand mechanical loads, offer great potential to reduce the overall system weight in applications such as automotive, aircraft, spacecraft, marine and sports equipment. The greatest improvements will come from systems that implement true multifunctional materials as fully as possible. The realization of electrochemical SESDs therefore requires the identification and development of suitable multifunctional structural electrodes, separators, and electrolytes. Different strategies are available depending on the class of electrochemical energy storage device and the specific chemistries selected. Here, we review existing attempts to build SESDs around carbon fiber (CF) composite electrodes, including the use of both organic and inorganic compounds to increase electrochemical performance. We consider some of the key challenges and discuss the implications for the selection of device chemistries.


2021 ◽  
Vol 1 (3) ◽  
pp. 49-56
Author(s):  
S.M. Zuyev ◽  
◽  
R.A. Maleyev ◽  
YU.M. Shmatkov ◽  
M.YU. Khandzhalov ◽  
...  

This article provides a comparative analysis of various energy storage devices. A detailed review and analysis of molecular energy storage units is carried out, their main characteristics and parame-ters, as well as their application areas, are determined. The main types of molecular energy storage are determined: electric double layer capacitors, pseudo capacitors, hybrid capacitors. Comparison of the characteristics of various batteries is given. The parameters of various energy storage devices are presented. The analysis of molecular energy storage devices and accumulators is carried out. Ttheir advantages and disadvantages are revealed. It has been shown that molecular energy storage or double layer electrochemical capacitors are ideal energy storage systems due to their high specific energy, fast charging and long life compared to conventional capacitors. The article presents oscillograms of a lithium-ion battery with a voltage of 10.8 V at a pulsed load current of 2A of a laptop with and without a molecular energy storage device, as well as oscil-lograms of a laptop with DVD lithium-ion battery with a voltage of 10.8 V with a parallel shutdown of a molecular energy storage device with a capacity of 7 F and without it. The comparative analysis shows that when the molecular energy storage unit with a 7 F capacity is switched on and off, transient processes are significantly improved and there are no supply voltage dips. The dependenc-es of the operating time of a 3.6 V 600 mAh lithium-ion battery at a load of 2 A for powering mo-bile cellular devices with and without a molecular energy storage are given. It is shown that when the molecular energy storage device is switched on, the battery operation time increases by almost 20%.


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