scholarly journals Unusual Regularities of Propylene Carbonate Obtained by Propylene Oxide Carboxylation in the Presence of ZnBr2/Et4N+Br− System

2019 ◽  
Vol 3 (2) ◽  
pp. 46
Author(s):  
Alexander R. Elman ◽  
Sergei A. Zharkov ◽  
Liudmila V. Ovsyannikova
Keyword(s):  
Induction Period ◽  
Propylene Carbonate ◽  
Process Parameters ◽  
Propylene Oxide ◽  
Reaction Rate ◽  
Kinetic Method ◽  
Main Process ◽  
Turnover Frequency ◽  
Rapid Formation ◽  
Period Duration

The aim of the work was to study the unusual regularities of propylene carbonate prepared by carboxylation of propylene oxide in the presence of the catalytic system ZnBr2/Et4N+Br−. Using the kinetic method, a long induction period was detected, followed by the rapid formation of propylene carbonate in a quantitative yield, where the maximum turnover frequency (TOF) values reached 21,658 h−1. The regularities of the influence of the main process parameters on the induction period duration and the reaction rate were established. Based on the results obtained and considering the literature, assumptions about the mechanism of the process were proposed and ways for its further study were outlined.

scholarly journals Shoulder Related Temperature Thresholds in FSSW of Aluminium Alloys

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4375
Author(s):  
David G. Andrade ◽  
Sree Sabari ◽  
Carlos Leitão ◽  
Dulce M. Rodrigues
Keyword(s):  
Heat Generation ◽  
Process Parameters ◽  
Rotational Speed ◽  
Aluminium Alloys ◽  
Spot Welding ◽  
Base Material ◽  
Main Process ◽  
Welding Temperature ◽  
Friction Stir ◽  
Tool Diameter

Friction Stir Spot Welding (FSSW) is assumed as an environment-friendly technique, suitable for the spot welding of several materials. Nevertheless, it is consensual that the temperature control during the process is not feasible, since the exact heat generation mechanisms are still unknown. In current work, the heat generation in FSSW of aluminium alloys, was assessed by producing bead-on-plate spot welds using pinless tools. Coated and uncoated tools, with varied diameters and rotational speeds, were tested. Heat treatable (AA2017, AA6082 and AA7075) and non-heat treatable (AA5083) aluminium alloys were welded to assess any possible influence of the base material properties on heat generation. A parametric analysis enabled to establish a relationship between the process parameters and the heat generation. It was found that for rotational speeds higher than 600 rpm, the main process parameter governing the heat generation is the tool diameter. For each tool diameter, a threshold in the welding temperature was identified, which is independent of the rotational speed and of the aluminium alloy being welded. It is demonstrated that, for aluminium alloys, the temperature in FSSW may be controlled using a suitable combination of rotational speed and tool dimensions. The temperature evolution with process parameters was modelled and the model predictions were found to fit satisfactorily the experimental results.

Chiral salenCo(iii) complexes with bulky substituents as catalysts for stereoselective alternating copolymerization of racemic propylene oxide with carbon dioxide and succinic anhydride

2021 ◽  
Vol 12 (12) ◽  
pp. 1776-1786
Author(s):  
Zhou Wang ◽  
Ying Mu
Keyword(s):  
Carbon Dioxide ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
Succinic Anhydride ◽  
Poly Propylene ◽  
Alternating Copolymerization

Stereoregular poly(propylene carbonate)s and poly(propylene succinate-block-carbonate)s were synthesized with new chiral salenCo(iii) catalysts carrying bulky substituents.

Formability of Explosive Welded Mg/Al Bimetallic Bar

2016 ◽  
Vol 716 ◽  
pp. 114-120 ◽  
Author(s):  
Sebastian Mróz ◽  
Piotr Szota ◽  
Teresa Bajor ◽  
Andrzej Stefanik
Keyword(s):  
Plastic Deformation ◽  
Strain Rate ◽  
Process Parameters ◽  
Metal Forming ◽  
Explosive Welding ◽  
Physical Modelling ◽  
Main Process ◽  
Compression Tests ◽  
Welding Method

The paper presents the results of physical modelling of the plastic deformation of the Mg/Al bimetallic specimens using the Gleeble 3800 simulator. The plastic deformation of Mg/Al bimetal specimens characterized by the diameter to thickness ratio equal to 1 was tested in compression tests. The aim of this work was determination of the range of parameters as temperature and strain rate that mainly influence on the plastic deformation of Mg/Al bars during metal forming processes. The tests were carried out for temperature range from 300 to 400°C for different strain rate values. The stock was round 22.5 mm-diameter with an Al layer share of 28% Mg/Al bars that had been produced using the explosive welding method. Based on the analysis of the obtained testing results it has been found that one of the main process parameters influencing the plastic deformation the bimetal components is the initial stock temperature and strain rate values.

Quality Monitoring and Prospects of Wire Bonding

2012 ◽  
Vol 588-589 ◽  
pp. 1156-1160
Author(s):  
Ge Ge Mei ◽  
Bin Jin ◽  
Wei Gong
Keyword(s):  
Process Parameters ◽  
Wire Bonding ◽  
Quality Monitoring ◽  
Main Trend ◽  
Microelectronic Packaging ◽  
Main Process ◽  
Bonding Quality ◽  
Semiconductor Packaging

Wire bonding is rapidly developmental technology of microelectronic packaging nearly half a century and become the main trend of semiconductor packaging field currently. This article introduces the main process parameters influencing on bonding quality, the methods to improve the bonding reliability, and prospects of developmental tendency of wire bonding.

Research on Warpage of Polystyrene in Selective Laser Sintering

2010 ◽  
Vol 43 ◽  
pp. 578-582 ◽  
Author(s):  
C.Y. Wang ◽  
Q. Dong ◽  
X.X. Shen
Keyword(s):  
Layer Thickness ◽  
Process Parameters ◽  
Laser Power ◽  
Selective Laser Sintering ◽  
Scanning Speed ◽  
Laser Sintering ◽  
Main Process ◽  
Influence Of Process Parameters ◽  
Temperature Changes ◽  
Hatch Spacing

Warpage is a crucial factor to accuracy of sintering part in selective laser sintering (SLS) process. In this paper, The influence of process parameters on warpage when sintering polystyrene(PS) materials in SLS are investigated. The laser power, scanning speed, hatch spacing, layer thickness as well as temperature of powder are considered as the main process parameters. The results showed that warpage increases with the increase of hatch space. Contary to it, warpage decreases with the increase of laser power. Warpage decreases with the increase of layer thickness between 0.16~0.18mm and changes little with increase of the thickness. Warpage increases along with the increase of scanning speed but decreases when the speed is over about 2000mm/s. When the temperature changes between 82°C-86°C, warpage decreases little with the increase of temperature. But further increase of temperature leads to warpage decreasing sharply when the temperature changes between 86°C-90°C.

Rates of Reaction of Dissolved Oxygen With Scavengers in Sweet and Sour Brines

CORROSION ◽  
1969 ◽  
Vol 25 (10) ◽  
pp. 397-404 ◽  
Author(s):  
E. S. SNAVELY ◽  
F. E. BLOUNT
Keyword(s):  
Transition Metal ◽  
Dissolved Oxygen ◽  
Metal Ions ◽  
Induction Period ◽  
Natural Waters ◽  
Reaction Rate ◽  
Transition Metal Ions ◽  
Zero Order ◽  
Laboratory Apparatus ◽  
High Ph

Abstract Rates of reaction of dissolved oxygen with H2S were measured in a laboratory apparatus using a polarographic type instrument for the measurement of oxygen concentrations. Results show that oxidation occurs only at high pH in the absence of catalytic species. The reaction is catalyzed by transition metal ions in the order Ni++>Co ++>Mn++>Cu++>Fe++. In all cases, the reaction rate increases with pH and is at first complex but becomes zero-order with respect to oxygen after a brief induction period. Some natural waters contain sufficient catalysts that additional amounts are not required for scavenging O2 with SO2 or Na2SO3. Sour waters cannot be scavenged with SO2 or Na2SO3 because of ineffectiveness of catalysts.

Large-Diameter Line Pipe Expanding Process

2012 ◽  
Vol 192 ◽  
pp. 180-184 ◽  
Author(s):  
Ai Xia He ◽  
Rong Chang Li
Keyword(s):  
Process Parameters ◽  
Large Diameter ◽  
Dimensional Accuracy ◽  
Optimization Method ◽  
Main Process ◽  
Shape Accuracy ◽  
Line Pipe ◽  
Factors Affecting ◽  
Array Optimization

Mechanical expanding process for large diameter line pipe, a detailed analysis of factors affecting the quality of the final products of the mechanical expansion and proposed optimization using orthogonal array optimization method, as an indicator of dimensional accuracy and shape accuracy of the products, combination of a variety of specifications of mechanical expanding products, the main process parameters to be optimized. Analysis and discussion of results, revealing the degree of influence of various factors on the quality of the final product, and gives the optimum combination of the results. Experiments show that the combination of optimized process parameters, and more help to improve the accuracy of the size and shape of products.

Tetracarboxyl-Functionalized Ionic Liquid: Synthesis and Catalytic Properties

2015 ◽  
Vol 68 (10) ◽  
pp. 1513 ◽  
Author(s):  
Miaona Feng ◽  
Guoying Zhao ◽  
Hongling Gao ◽  
Suojiang Zhang
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Propionic Acid ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
High Stability ◽  
Ammonium Acetate ◽  
Catalytic Properties ◽  
Potential Applications

Novel tetracarboxyl-functionalized 2,2′-biimidazolium-based ionic liquids (ILs) with different anions were synthesized in two steps from readily available and sustainable starting materials including ammonium acetate, glyoxal, and halogenated propionic acid. The functionalized IL exhibited higher catalytic activity towards the cycloaddition of CO2 to terminal epoxides. With propylene oxide as a substrate, the optimum yield of propylene carbonate reached 82.7 % at an initial CO2 pressure of 2.0 MPa for 4 h at 140°C. Moreover, the functionalized IL catalyst displayed a high stability and can be reused for at least five cycles without obvious loss of catalytic activity. The results provide a simple and economical way to synthesize multi-functionalized imidazolium-based ILs with versatile potential applications.

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