scholarly journals In-Situ Ellipsometric Study of the Optical Properties of LTL-Doped Thin Film Sensors for Copper(II) Ion Detection

Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 423 ◽  
Author(s):  
Dervil Cody ◽  
Tsvetanka Babeva ◽  
Violeta Madjarova ◽  
Anastasia Kharchenko ◽  
Sabad-e-Gul ◽  
...  
Keyword(s):  
Optical Properties ◽  
Optical Sensors ◽  
Composite Films ◽  
High Temporal Resolution ◽  
Thin Film Sensors ◽  
Treatment Conditions ◽  
Ellipsometric Study ◽  
Short Time ◽  
Resolution Single

Optical sensors fabricated in zeolite nanoparticle composite films rely on changes in their optical properties (refractive index, n, and thickness, d) to produce a measurable response in the presence of a target analyte. Here, ellipsometry is used to characterize the changes in optical properties of Linde Type L (LTL) zeolite thin films in the presence of Cu2+ ions in solution, with a view to improving the design of optical sensors that involve the change of n and/or d due to the adsorption of Cu2+ ions. The suitability of two different ellipsometry techniques (single wavelength and spectroscopic) for the evaluation of changes in n and d of both undoped and zeolite-doped films during exposure to water and Cu2+-containing solutions was investigated. The influence of pre-immersion thermal treatment conditions on sensor response was also studied. Due to the high temporal resolution, single wavelength ellipsometry facilitated the identification of a Cu2+ concentration response immediately after Cu2+ introduction, indicating that the single wavelength technique is suitable for dynamic studies of sensor–analyte interactions over short time scales. In comparison, spectroscopic ellipsometry produced a robust analysis of absolute changes in film n and d, as well as yielding insight into the net influence of competing and simultaneous changes in n and d inside the zeolite-doped films arising due to water adsorption and the ion exchange of potassium (K+) cations by copper (Cu2+).

scholarly journals In situ polymerization of PEDOT:PSS films based on EMI-TFSI and the analysis of electrochromic performance

e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 722-733
Author(s):  
Haiyun Jiang ◽  
Wei Wu ◽  
Zigong Chang ◽  
Hailan Zeng ◽  
Ronglian Liang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Optical Properties ◽  
Diffusion Coefficient ◽  
Response Time ◽  
Color Change ◽  
In Situ Polymerization ◽  
Electrochemical Polymerization ◽  
Composite Films ◽  
Ion Diffusion

Abstract In this report, PEDOT composite films were prepared by in situ electrochemical polymerization. 1-Ethyl-3-methylimidazole bis(trifluoromethylsulfonyl)imide (EMI-TFSI) was used as an ionic liquid dopant for PEDOT:PSS films. Subsequently, these PEDOT:PSS/EMI-TFSI films were compared with PEDOT:PSS films based on their morphology, structure, electrochromic properties, and optical properties at different deposition voltages and deposition times. It was observed that the addition of EMI-TFSI enhanced all the aforementioned properties of the films. PEDOT:PSS/EMI-TFSI films were seen to have a larger ion diffusion coefficient (1.38 × 10−20 cm2·s−1), a wider color change range (43.48%), a shorter response time (coloring response time = 1.2 s; fade response time = 2 s), and a higher coloring efficiency (189.86 cm2·C−1) when compared with normal PEDOT:PSS films. The introduction of EMI-TFSI in the films ultimately resulted in superior electrochemical and optical properties along with higher stability.

In situ ellipsometric study of optical properties of ultrathin films

1992 ◽  
Vol 31 (10) ◽  
pp. 1612 ◽  
Author(s):  
Masaki Yamamoto ◽  
Takeshi Namioka
Keyword(s):  
Optical Properties ◽  
Ultrathin Films ◽  
Ellipsometric Study

Fluorescent Nanotechnology: An Evolution in Optical Sensors

2020 ◽  
Vol 17 ◽  
Author(s):  
Dilawar Hassan ◽  
Hadi Bakhsh ◽  
Asif M. Khurram ◽  
Shakeel A. Bhutto ◽  
Nida S. Jalbani ◽  
...  
Keyword(s):  
Optical Properties ◽  
Optical Sensors ◽  
Light Emission ◽  
Environmental Contaminants ◽  
Fluorescent Nanoparticles ◽  
Sensing Applications ◽  
Properties Of Materials ◽  
Optical Properties Of Materials ◽  
Fluorescent Nanomaterials

Background: The optical properties of nanomaterials have evolved enormously with the introduction of nanotechnology. The property of materials to absorb and/or emit specific wavelength has turned them into one of the most favourite candidates to be effectively utilized in different sensing applications e.g organic light emission diodes (OLEDs) sensors, gas sensors, biosensors and fluorescent sensors. These materials have been reported as a sensor in the field of tissue and cell imaging, cancer detection and detection of environmental contaminants etc. Fluorescent nanomaterials are heling in rapid and timely detection of various contaminants that greatly impact the quality of life and food, that is exposed to these contaminants. Later, all the contaminants have been investigated to be most perilous entities that momentously affect the life span of the animals and humans who use those foods which have been contaminated. Objective: In this review, we will discuss about various methods and approaches to synthesize the fluorescent nanoparticles and quantum dots (QDs) and their applications in various fields. The application will include the detection of various environmental contaminants and bio-medical applications. We will discuss the possible mode of action of the nanoparticles when used as sensor for the environmental contaminants as well as the surface modification of some fluorescent nanomaterials with anti-body and enzyme for specific detection in animal kingdom. We will also describe some RAMAN based sensors as well as some optical sensing-based nanosensors. Conclusion: Nanotechnology has enabled to play with the size, shape and morphology of materials in the nanoscale. The physical, chemical and optical properties of materials change dramatically when they are reduced to nanoscale. The optical properties can become choosy in terms of emission or absorption of wavelength in the size range and can result in production of very sensitive optical sensor. The results show that the use of fluorescent nanomaterials for the sensing purposes are helping a great deal in the sensing field.

Doping-induced modulation of optical properties of PFO/PMMA composite films

2020 ◽  
Author(s):  
Vinayak S. Bhat ◽  
S. B. Kapatkar ◽  
N. H. Ayachit ◽  
Ishwar Naik ◽  
M. S. Murari
Keyword(s):  
Optical Properties ◽  
Composite Films

scholarly journals Structural and optical properties of amorphous Si–Ge–Te thin films prepared by combinatorial sputtering

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
C. Mihai ◽  
F. Sava ◽  
I. D. Simandan ◽  
A. C. Galca ◽  
I. Burducea ◽  
...  
Keyword(s):  
Optical Properties ◽  
Data Storage ◽  
Optical Sensors ◽  
Material Selection ◽  
Functional Materials ◽  
Stability Study ◽  
Optical Data Storage ◽  
Optical Data ◽  
Structural And Optical Properties ◽  
Topological Constraint

AbstractThe lack of order in amorphous chalcogenides offers them novel properties but also adds increased challenges in the discovery and design of advanced functional materials. The amorphous compositions in the Si–Ge–Te system are of interest for many applications such as optical data storage, optical sensors and Ovonic threshold switches. But an extended exploration of this system is still missing. In this study, magnetron co-sputtering is used for the combinatorial synthesis of thin film libraries, outside the glass formation domain. Compositional, structural and optical properties are investigated and discussed in the framework of topological constraint theory. The materials in the library are classified as stressed-rigid amorphous networks. The bandgap is heavily influenced by the Te content while the near-IR refractive index dependence on Ge concentration shows a minimum, which could be exploited in applications. A transition from a disordered to a more ordered amorphous network at 60 at% Te, is observed. The thermal stability study shows that the formed crystalline phases are dictated by the concentration of Ge and Te. New amorphous compositions in the Si–Ge–Te system were found and their properties explored, thus enabling an informed and rapid material selection and design for applications.

scholarly journals Flexible Methyl Cellulose/Polyaniline/Silver Composite Films with Enhanced Linear and Nonlinear Optical Properties

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1225
Author(s):  
Ali Atta ◽  
Mostufa M. Abdelhamied ◽  
Ahmed M. Abdelreheem ◽  
Mohamed R. Berber
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Band Gap ◽  
Nonlinear Optical ◽  
Composite Films ◽  
Methyl Cellulose ◽  
Carbon Cluster ◽  
Nonlinear Susceptibility ◽  
Optical Parameters ◽  
Flexible Polymer

In order to potentiate implementations in optical energy applications, flexible polymer composite films comprising methyl cellulose (MC), polyaniline (PANI) and silver nanoparticles (AgNPs) were successfully fabricated through a cast preparation method. The composite structure of the fabricated film was confirmed by X-ray diffraction and infrared spectroscopy, indicating a successful incorporation of AgNPs into the MC/PANI blend. The scanning electron microscope (SEM) images have indicated a homogenous loading and dispersion of AgNPs into the MC/PANI blend. The optical parameters such as band gap (Eg), absorption edge (Ed), number of carbon cluster (N) and Urbach energy (Eu) of pure MC polymer, MC/PANI blend and MC/PANI/Ag films were determined using the UV optical absorbance. The effects of AgNPs and PANI on MC polymer linear optical (LO) and nonlinear optical (NLO) parameters including reflection extinction coefficient, refractive index, dielectric constant, nonlinear refractive index, and nonlinear susceptibility are studied. The results showed a decrease in the band gap of MC/PANI/AgNPs compared to the pure MC film. Meanwhile, the estimated carbon cluster number enhanced with the incorporation of the AgNPs. The inclusion of AgNPs and PANI has enhanced the optical properties of the MC polymer, providing a new composite suitable for energy conversion systems, solar cells, biosensors, and nonlinear optical applications.

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