scholarly journals Catalytic Coal Gasification Process Simulation with Alkaline Organic Wastewater in a Fluidized Bed Reactor Using Aspen Plus

Energies ◽  
2019 ◽  
Vol 12 (7) ◽  
pp. 1367 ◽  
Author(s):  
Xiao ◽  
Wang ◽  
Zheng ◽  
Qin ◽  
Zhou

A co-gasification process was proposed both for treating alkaline organic wastewater and to promote coal gasification by the alkaline substances in situ. A catalytic gasification model was developed by introducing a catalytic correction factor to describe the catalytic effects quantitatively. An integrated process simulation was carried out using Aspen Plus equipped with FORTRAN subroutines. The model was verified using the root mean square error between the simulation results and experimental data from the literature. Syngas composition, cold gas efficiency, and carbon conversion efficiency were analyzed with respect to different operating conditions (reaction temperature, steam/coal ratio, and equivalence ratio). The optimal conditions are summarized based on a self-sufficient system by using sensitivity analysis: Gasification temperature of 700 °C, steam/coal ratio = 1.0, and equivalence ratio = 0.4.

Author(s):  
Rongbin Li ◽  
Mingzhuang Xie ◽  
Hui Jin ◽  
Liejin Guo ◽  
Fengqin Liu

AbstractThe three-dimensional (3-D) comprehensive mathematical model was developed to simulate the coal gasification process in an entrained flow gasifier with a swirl burner. The models employed or developed includes the coal devolatilization model, the char combustion and gasification model, the gas homogeneous reaction model, the random-trajectory model, gas turbulence model, and the P-1 radiation model. The solution of models was executed based on the computational fluid dynamics (CFD). By qualitatively comparing the results at different swirl number, the significant influences of swirl on characteristics of coal gasification such as flow distributions, gas temperature and product composition including hydrogen (H2), carbon monoxide (CO), etc., and on the performance of coal gasification such as averaged exit product composition, carbon conversion rate and cold gas efficiency, were in detail discussed. Especially, a proper swirl number (S ≤ 0.65) in favor of gasification was found for the investigated gasifier in this paper.


Author(s):  
Dandan Wang ◽  
Sheng Li ◽  
Lin Gao

In this paper, a novel coal gasification technology used for Integrated Gasification Combined Cycle (IGCC) power plants is proposed, in which a regenerative unit is applied to recover syngas sensible heat to generate steam and then the high temperature steam is used to gasify coke from pyrolyzer. Through such a thermochemical regenerative unit, the sensible heat with lower energy level is upgraded into syngas chemical energy with higher energy level, and therefore a higher cold gas efficiency (CGE) is expected. The Aspen Plus Software is selected to simulate the novel coal gasification system. Then the exergy and Energy-Utilization Diagram (EUD) analyses are applied to disclose the plant performance enhancement mechanism. It reveals that 83.2% of syngas sensible heat can be recovered into steam agent and so the CGE is upgraded to 90%. And with the enhancement of CGE, the efficiency of an IGCC plant based on the novel gasification system can be as high as 51.82%, showing a significant improvement compared to 45.2% in a Texaco coal gasification based plant. At the same time, the exergy destruction of gasification process is reduced from 132.5MW to 98.4MW through thermochemical reactions. Lift of accepted energy level (Aea), and decrease of released energy level (Aed) and heat absorption (ΔH) contribute to the exergy destruction reduction in the gasification process. Additionally, since oxygen agent is no longer used in the IGCC, 34.5MW exergy loss in the air separation unit is avoided. Thereby the novel coal gasification technology proposed in this paper has a good thermodynamic performance and may provide a quite promising way for high efficient and clean coal utilization.


Energies ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 688 ◽  
Author(s):  
Mauro Villarini ◽  
Vera Marcantonio ◽  
Andrea Colantoni ◽  
Enrico Bocci

The present paper presents a study of biomass waste to energy conversion using gasification and internal combustion engine for power generation. The biomass waste analyzed is the most produced on Italian soil, chosen for suitable properties in the gasification process. Good quality syngas with up to 16.1% CO–4.3% CH4–23.1% H2 can be produced. The syngas lower heating value may vary from 1.86 MJ/ Nm3 to 4.5 MJ/Nm3 in the gasification with air and from 5.2 MJ/ Nm3 to 7.5 MJ/Nm3 in the gasification with steam. The cold gas efficiency may vary from 16% to 41% in the gasification with air and from 37% to 60% in the gasification with steam, depending on the different biomass waste utilized in the process and the different operating conditions. Based on the sensitivity studies carried out in the paper and paying attention to the cold gas efficiency and to the LHV, we have selected the best configuration process for the best syngas composition to feed the internal combustion engine. The influence of syngas fuel properties on the engine is studied through the electrical efficiency and the cogeneration efficiency.


2012 ◽  
Vol 66 (7) ◽  
Author(s):  
Afsin Gungor ◽  
Murat Ozbayoglu ◽  
Cosku Kasnakoglu ◽  
Atilla Biyikoglu ◽  
Bekir Uysal

AbstractIn this parametric study, the effects of coal and oxidiser type, air-to-fuel ratio, steam-to-fuel ratio, reactor temperature, and pressure on H2 and CO amounts at the gasifier output, H2/CO, and higher heating value of the syngas produced have been calculated using a coal gasification model. Model simulations have been performed to identify the optimum values which are assumed to be 100 % for both cold gas efficiency and carbon conversion efficiency in the gasification process. From this study, it may be observed that the moisture content of the coal type is of crucial importance for the air gasification process; the O2 content of similar coals (taking into consideration the moisture and H2 content) is of significant importance for the air gasification process. When compared with air gasification, air-steam gasification becomes a more effective coal gasification method. The optimum working condition for air-steam gasification is to carry out the process at one atmosphere. High gasifier temperatures are not needed for the air-steam gasification of coal.


2019 ◽  
Vol 142 (3) ◽  
Author(s):  
Peng Jiang ◽  
Dengting Guo ◽  
Xiang Luo ◽  
Mengxia Xu ◽  
Tao Wu

Abstract This research is focused on the gasification performance of coal and its corresponding macerals as well as on the interactions among macerals under typical gasification conditions by Aspen Plus modeling. The synergistic coefficient was employed to show the degree of interactions, while the performance indicators including specific oxygen consumption (SOC), specific coal consumption (SCC), cold gas efficiency (CGE), and effective syngas (CO + H2) content were used to evaluate the gasification process. Sensitivity analyses showed that the parent coal and its macerals exhibited different gasification behaviors at the same operating conditions, such as the SOC and SCC decreased in the order of inertinite > vitrinite > liptinite, whereas CGE changed in the order of liptinite > vitrinite > inertinite. The synergistic coefficients of SOC and SCC for the simulated coals were in the range of 0.94–0.97, whereas the synergistic coefficient of CGE was 1.05–1.13. Moreover, it was found that synergistic coefficients of gasification indicators correlated well with maceral contents. In addition, the increase in temperature was found to promote the synergistic coefficients slightly, whilst at an oxygen to coal mass ratio of 0.8 and a steam to coal mass ratio of 0.8, the highest synergistic coefficient was obtained.


2020 ◽  
Vol 209 ◽  
pp. 03011
Author(s):  
Igor Donskoy

In this work, we studied the efficiency of the coal gasification process under oxyfuel conditions. Using mathematical modelling one-dimensional stationary statement, the optimal parameters of coal processing were determined, air and oxyfuel conditions are compared. The calculated dependences of the characteristics of the gasification process on the stoichiometric ratio at different initial temperatures are constructed. The optimal values of oxygen stoichiometric ratio and the maximum values of cold gas efficiency in the selected range of parameters are determined. The contribution of the thermophysical and reactive properties of the gasification agent to the change in the cold gas efficiency is estimated.


Author(s):  
Nabila Aprianti ◽  
Muhammad Faizal ◽  
Muhammad Said ◽  
Subriyer Nasir

Oil palm empty fruit bunch (OPEFB is one of the enormous waste expected to become a renewable energy source. This study aimed to convert OPEFB into syngas through a gasification process using bentonite as a catalyst. The effects of temperature and product gas catalysts were investigated, and the efficiency of the gasification process was summarized. The process has used an updraft gasifier at 350-550 °C and air as the gasification medium (ER 0.2). The results indicate that syngas can be produced by updraft gasifier. When the temperature increase, the H2 and CO rising. The highest H2 and CO content of 27.74% and 20.43% are obtained at 550°C when bentonite applied. HHV and LHV range of 3.38~12.79 MJ/Nm3 and 3.03~11.58 MJ/Nm3, respectively. The maximum carbon conversion efficiency (CCE) and cold gas efficiency (CGE) reach 85.49% and 82.34%. Bentonite has been able to increase the concentration of the gas composition especially H2 and CO and the heating value of syngas.


Author(s):  
Mawa Mutaz ◽  
Ibrahim H.Elamin ◽  
Hamid M. Mustafa

Bagasse has traditionally inefficiently burned in boilers for steam and electricity generation which still suffers from significant inefficiencies creating; therefore there is a need for alternative processes to be analyzed. Among the biomass utilization technologies, biomass gasification is an attractive solution for utilizing biomass effectively. In this study Aspen Plus simulation package V8 was used to develop a model for the gasification of Sudanese sugar cane bagasse in a fluidized bed reactor for syngas production. The developed model is based on Gibbs free energy minimization applying the non-stoichiometric equilibrium method for optimization of the gasifier performance. The objective is to study the effect of important operating parameters including gasification temperature, steam to biomass ratio (SBR) and air to biomass ratio (ABR), on syngas composition, low heating value (LHV) of syngas and cold gas efficiency (CGE). The optimal values of syngas composition, LHV and CGE were located at gasification temperature range from 750C to 950C, steam to biomass ratio around 0.5 to 0.8 and air to biomass ratio values equal to or below 0.4.


Author(s):  
Armin Silaen ◽  
Ting Wang

Numerical simulations of the coal gasification process inside a generic 2-stage entrained-flow gasifier fed with Indonesian coal at approximately 2000 metric ton/day are carried out. The 3D Navier–Stokes equations and eight species transport equations are solved with three heterogeneous global reactions, three homogeneous reactions, and two-step thermal cracking equation of volatiles. The chemical percolation devolatilization (CPD) model is used for the devolatilization process. This study is conducted to investigate the effects of different operation parameters on the gasification process including coal mixture (dry versus slurry), oxidant (oxygen-blown versus air-blown), and different coal distribution between two stages. In the two-stage coal-slurry feed operation, the dominant reactions are intense char combustion in the first stage and enhanced gasification reactions in the second stage. The gas temperature in the first stage for the dry-fed case is about 800 K higher than the slurry-fed case. This calls for attention of additional refractory maintenance in the dry-fed case. One-stage operation yields higher H2, CO and CH4 combined than if a two-stage operation is used, but with a lower syngas heating value. The higher heating value (HHV) of syngas for the one-stage operation is 7.68 MJ/kg, compared with 8.24 MJ/kg for two-stage operation with 75%–25% fuel distribution and 9.03 MJ/kg for two-stage operation with 50%–50% fuel distribution. Carbon conversion efficiency of the air-blown case is 77.3%, which is much lower than that of the oxygen-blown case (99.4%). The syngas heating value for the air-blown case is 4.40 MJ/kg, which is almost half of the heating value of the oxygen-blown case (8.24 MJ/kg).


2020 ◽  
Vol 7 (3) ◽  
pp. 516-535
Author(s):  
Tamer M. Ismail ◽  
Mingliang Shi ◽  
Jianliang Xu ◽  
Xueli Chen ◽  
Fuchen Wang ◽  
...  

Abstract With the help of Aspen Plus, a two-dimensional unsteady CFD model is developed to simulate the coal gasification process in a fixed bed gasifier. A developed and validated two dimensional CFD model for coal gasification has been used to predict and assess the viability of the syngas generation from coal gasification employing the updraft fixed bed gasifier. The process rate model and the sub-model of gas generation are determined. The particle size variation and char burning during gasification are also taken into account. In order to verify the model and increase the understanding of gasification characteristics, a set of experiments and numerical comparisons have been carried out. The simulated results in the bed are used to predict the composition of syngas and the conversion of carbon. The model proposed in this paper is a promising tool for simulating the coal gasification process in a fixed bed gasifier.


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