A parametric study on coal gasification for the production of syngas

2012 ◽  
Vol 66 (7) ◽  
Author(s):  
Afsin Gungor ◽  
Murat Ozbayoglu ◽  
Cosku Kasnakoglu ◽  
Atilla Biyikoglu ◽  
Bekir Uysal

AbstractIn this parametric study, the effects of coal and oxidiser type, air-to-fuel ratio, steam-to-fuel ratio, reactor temperature, and pressure on H2 and CO amounts at the gasifier output, H2/CO, and higher heating value of the syngas produced have been calculated using a coal gasification model. Model simulations have been performed to identify the optimum values which are assumed to be 100 % for both cold gas efficiency and carbon conversion efficiency in the gasification process. From this study, it may be observed that the moisture content of the coal type is of crucial importance for the air gasification process; the O2 content of similar coals (taking into consideration the moisture and H2 content) is of significant importance for the air gasification process. When compared with air gasification, air-steam gasification becomes a more effective coal gasification method. The optimum working condition for air-steam gasification is to carry out the process at one atmosphere. High gasifier temperatures are not needed for the air-steam gasification of coal.

Author(s):  
Rongbin Li ◽  
Mingzhuang Xie ◽  
Hui Jin ◽  
Liejin Guo ◽  
Fengqin Liu

AbstractThe three-dimensional (3-D) comprehensive mathematical model was developed to simulate the coal gasification process in an entrained flow gasifier with a swirl burner. The models employed or developed includes the coal devolatilization model, the char combustion and gasification model, the gas homogeneous reaction model, the random-trajectory model, gas turbulence model, and the P-1 radiation model. The solution of models was executed based on the computational fluid dynamics (CFD). By qualitatively comparing the results at different swirl number, the significant influences of swirl on characteristics of coal gasification such as flow distributions, gas temperature and product composition including hydrogen (H2), carbon monoxide (CO), etc., and on the performance of coal gasification such as averaged exit product composition, carbon conversion rate and cold gas efficiency, were in detail discussed. Especially, a proper swirl number (S ≤ 0.65) in favor of gasification was found for the investigated gasifier in this paper.


2012 ◽  
Vol 512-515 ◽  
pp. 575-578
Author(s):  
Hsien Chen ◽  
Chiou Liang Lin ◽  
Wun Yue Zeng ◽  
Zi Bin Xu

Catalysis was used to increase the H2 production, syngas heating value, enhanced carbon conversion efficiency and cold gas efficiency during gasification. Due to Cu and Zn were abundant in waste according to previous researches, this research discussed the effect of Cu and Zn on artificial waste gasification. The syngas composition and total lower heating value (LHV) were determined in this study. The results showed that the existence of Cu and Zn increased production of H2 and CO. However, the production of CH4 and CO2 decreased. At same time, total LHV was also increased. Additionally, the different Cu concentration affected gas composition and LHV, but the effect of Zn concentration was not significant.


Energies ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 102 ◽  
Author(s):  
Francesco Gallucci ◽  
Raffaele Liberatore ◽  
Luca Sapegno ◽  
Edoardo Volponi ◽  
Paolo Venturini ◽  
...  

This work aims to study the influence of an oxidant agent on syngas quality. A series of tests using air and steam as oxidant agents have been performed and the results compared with those of a pyrolysis test used as a reference. Tests were carried out at Sapienza University of Rome, using an updraft reactor. The reactor was fed with hazelnut shells, waste biomass commonly available in some parts of Italy. Temperature distribution, syngas composition and heating value, and producible energy were measured. Air and steam gasification tests produced about the same amount of syngas flow, but with a different quality. The energy flow in air gasification had the smallest measurement during the experiments. On the contrary, steam gasification produced a syngas flow with higher quality (13.1 MJ/Nm3), leading to the best values of energy flow (about 5.4 MJ/s vs. 3.3 MJ/s in the case of air gasification). From the cold gas efficiency point of view, steam gasification is still the best solution, even considering the effect of the enthalpy associated with the steam injected within the gasification reactor.


Author(s):  
Dandan Wang ◽  
Sheng Li ◽  
Lin Gao

In this paper, a novel coal gasification technology used for Integrated Gasification Combined Cycle (IGCC) power plants is proposed, in which a regenerative unit is applied to recover syngas sensible heat to generate steam and then the high temperature steam is used to gasify coke from pyrolyzer. Through such a thermochemical regenerative unit, the sensible heat with lower energy level is upgraded into syngas chemical energy with higher energy level, and therefore a higher cold gas efficiency (CGE) is expected. The Aspen Plus Software is selected to simulate the novel coal gasification system. Then the exergy and Energy-Utilization Diagram (EUD) analyses are applied to disclose the plant performance enhancement mechanism. It reveals that 83.2% of syngas sensible heat can be recovered into steam agent and so the CGE is upgraded to 90%. And with the enhancement of CGE, the efficiency of an IGCC plant based on the novel gasification system can be as high as 51.82%, showing a significant improvement compared to 45.2% in a Texaco coal gasification based plant. At the same time, the exergy destruction of gasification process is reduced from 132.5MW to 98.4MW through thermochemical reactions. Lift of accepted energy level (Aea), and decrease of released energy level (Aed) and heat absorption (ΔH) contribute to the exergy destruction reduction in the gasification process. Additionally, since oxygen agent is no longer used in the IGCC, 34.5MW exergy loss in the air separation unit is avoided. Thereby the novel coal gasification technology proposed in this paper has a good thermodynamic performance and may provide a quite promising way for high efficient and clean coal utilization.


Energies ◽  
2019 ◽  
Vol 12 (7) ◽  
pp. 1367 ◽  
Author(s):  
Xiao ◽  
Wang ◽  
Zheng ◽  
Qin ◽  
Zhou

A co-gasification process was proposed both for treating alkaline organic wastewater and to promote coal gasification by the alkaline substances in situ. A catalytic gasification model was developed by introducing a catalytic correction factor to describe the catalytic effects quantitatively. An integrated process simulation was carried out using Aspen Plus equipped with FORTRAN subroutines. The model was verified using the root mean square error between the simulation results and experimental data from the literature. Syngas composition, cold gas efficiency, and carbon conversion efficiency were analyzed with respect to different operating conditions (reaction temperature, steam/coal ratio, and equivalence ratio). The optimal conditions are summarized based on a self-sufficient system by using sensitivity analysis: Gasification temperature of 700 °C, steam/coal ratio = 1.0, and equivalence ratio = 0.4.


2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Ahmad F ◽  
◽  
Ahmad N ◽  
Asghar U ◽  
Ali A ◽  
...  

Converting rice husk into energy is a promising method of generating renewable energy and reducing greenhouse gas emissions. In this research rice hush is considered as biomass fuel. The characteristics of rice husk gasification were investigated at an Equivalence Ratio (ER) of 0.25–0.38 and a gasifier temperature of 750-870°C in 20 tons per day (TPD) using steam explosion process in fluidized bed gasifier system. Different operation conditions, temperatures and loads, are investigated for their effects on the compositions, calorific properties, gasification efficiencies of syngas. The effects of the critical parameters, namely, Steam-to-Biomass Ratio (S/B), Particle size variation and gasification temperature on the quality of the product gas as well as the gasifier cold gas efficiency were analyzed. This is the new finding in the research. The optimal conditions of the gasification operation were an ER of 0.20 and gasifier temperature of 800°C. The low heating value of the gas product and cold gas efficiency were 1390kcal/Nm³ and 75%, respectively. After passing the generated gas through the gas cleaning units, it was confirmed that the tar in the product gas was removed with an efficiency of 98%. The cleaned product gas was used for the operation of 420kW, gas engine. Pressure loss often occurred at the bottom of the gasifier during the gasification operation; we found that the agglomerates generated by the gasification process caused it. To prevent the pressure loss caused by the agglomerates, the stable control of temperature inside the gasifier is needed and an ash removal device remove agglomerates should be installed to maintain stable long-term operation. This paper leads towards the production of Syngas and further on the electricity from the rice husk, an eminent biomass, copiously available all around the world. Especially in Pakistan, the rice is used abundantly so the raw material is easily available. The gas is produced using the gasification process in dual fluidized gasifier. It is a wonderful alternative to the natural gas with high calorific value. The sulfur contents are quite less compared to natural gas. It also have a good correlation with environment as flue gases emission is negligible relative to other source like coal, wood, plastic, waste etc. Another benefit of this process is the waste management and pollution control. The results are developed by using the detailed analysis of the process values of plants which is generating electricity by rice husk gasification. We learned, all results revealed that the dual fluidized bed gasification is more economical and efficient method compared to all other methods for commercial scale production of syngas. Results are analyzed which imply that the biomass is more gigantic source which replace the fossil fuels and leads towards the green energy in a more economical way. This paper provides an overview of previous works on combustion and gasification of rice husk in atmospheric fluiuidized bed reactors and summarizes the state of the art knowledge. As the high ash content, low bulk density, p characteristics and low ash melting point makes the other types of reactors like grate furnaces and downdraft gasifers either inefficient or unsuitable for rice husk conversion to energy, the fluiuidized bed reactor seems to be the promising choice. The overview shows that the reported results are from only small bench or lab scale units. Although a combustion efficiency of about 80% can normally be attained; the reported values in the literature, which are more than 95%, seem to be in higher order. Combustion intensity of about 530kg/h/m² is reported. It is also technically feasible to gasify rice husk in a fluidized bed reactor to yield combustible producer gas, even with sufficient heating value for application in internal combustion engines.


2020 ◽  
Vol 209 ◽  
pp. 03011
Author(s):  
Igor Donskoy

In this work, we studied the efficiency of the coal gasification process under oxyfuel conditions. Using mathematical modelling one-dimensional stationary statement, the optimal parameters of coal processing were determined, air and oxyfuel conditions are compared. The calculated dependences of the characteristics of the gasification process on the stoichiometric ratio at different initial temperatures are constructed. The optimal values of oxygen stoichiometric ratio and the maximum values of cold gas efficiency in the selected range of parameters are determined. The contribution of the thermophysical and reactive properties of the gasification agent to the change in the cold gas efficiency is estimated.


Author(s):  
Nabila Aprianti ◽  
Muhammad Faizal ◽  
Muhammad Said ◽  
Subriyer Nasir

Oil palm empty fruit bunch (OPEFB is one of the enormous waste expected to become a renewable energy source. This study aimed to convert OPEFB into syngas through a gasification process using bentonite as a catalyst. The effects of temperature and product gas catalysts were investigated, and the efficiency of the gasification process was summarized. The process has used an updraft gasifier at 350-550 °C and air as the gasification medium (ER 0.2). The results indicate that syngas can be produced by updraft gasifier. When the temperature increase, the H2 and CO rising. The highest H2 and CO content of 27.74% and 20.43% are obtained at 550°C when bentonite applied. HHV and LHV range of 3.38~12.79 MJ/Nm3 and 3.03~11.58 MJ/Nm3, respectively. The maximum carbon conversion efficiency (CCE) and cold gas efficiency (CGE) reach 85.49% and 82.34%. Bentonite has been able to increase the concentration of the gas composition especially H2 and CO and the heating value of syngas.


Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1104
Author(s):  
Donatella Barisano ◽  
Giuseppe Canneto ◽  
Francesco Nanna ◽  
Antonio Villone ◽  
Emanuele Fanelli ◽  
...  

Biomass gasification for energy purposes has several advantages, such as the mitigation of global warming and national energy independency. In the present work, the data from an innovative and intensified steam/oxygen biomass gasification process, integrating a gas filtration step directly inside the reactor, are presented. The produced gas at the outlet of the 1 MWth gasification pilot plant was analysed in terms of its main gaseous products (hydrogen, carbon monoxide, carbon dioxide, and methane) and contaminants. Experimental test sets were carried out at 0.25–0.28 Equivalence Ratio (ER), 0.4–0.5 Steam/Biomass (S/B), and 780–850 °C gasification temperature. Almond shells were selected as biomass feedstock and supplied to the reactor at approximately 120 and 150 kgdry/h. Based on the collected data, the in-vessel filtration system showed a dust removal efficiency higher than 99%-wt. A gas yield of 1.2 Nm3dry/kgdaf and a producer gas with a dry composition of 27–33%v H2, 23–29%v CO, 31–36%v CO2, 9–11%v CH4, and light hydrocarbons lower than 1%v were also observed. Correspondingly, a Low Heating Value (LHV) of 10.3–10.9 MJ/Nm3dry and a cold gas efficiency (CGE) up to 75% were estimated. Overall, the collected data allowed for the assessment of the preliminary performances of the intensified gasification process and provided the data to validate a simulative model developed through Aspen Plus software.


Author(s):  
Armin Silaen ◽  
Ting Wang

Numerical simulations of the coal gasification process inside a generic 2-stage entrained-flow gasifier fed with Indonesian coal at approximately 2000 metric ton/day are carried out. The 3D Navier–Stokes equations and eight species transport equations are solved with three heterogeneous global reactions, three homogeneous reactions, and two-step thermal cracking equation of volatiles. The chemical percolation devolatilization (CPD) model is used for the devolatilization process. This study is conducted to investigate the effects of different operation parameters on the gasification process including coal mixture (dry versus slurry), oxidant (oxygen-blown versus air-blown), and different coal distribution between two stages. In the two-stage coal-slurry feed operation, the dominant reactions are intense char combustion in the first stage and enhanced gasification reactions in the second stage. The gas temperature in the first stage for the dry-fed case is about 800 K higher than the slurry-fed case. This calls for attention of additional refractory maintenance in the dry-fed case. One-stage operation yields higher H2, CO and CH4 combined than if a two-stage operation is used, but with a lower syngas heating value. The higher heating value (HHV) of syngas for the one-stage operation is 7.68 MJ/kg, compared with 8.24 MJ/kg for two-stage operation with 75%–25% fuel distribution and 9.03 MJ/kg for two-stage operation with 50%–50% fuel distribution. Carbon conversion efficiency of the air-blown case is 77.3%, which is much lower than that of the oxygen-blown case (99.4%). The syngas heating value for the air-blown case is 4.40 MJ/kg, which is almost half of the heating value of the oxygen-blown case (8.24 MJ/kg).


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