scholarly journals Magnetically Recoverable and Reusable Titanium Dioxide Nanocomposite for Water Disinfection

2021 ◽  
Vol 9 (9) ◽  
pp. 943 ◽  
Author(s):  
Monica Keeley ◽  
Kim Kisslinger ◽  
Carman Adamson ◽  
Ping Y. Furlan

A bifunctional magnetic Fe3O4@SiO2@TiO2 or MS-TiO2 antimicrobial nanocomposite was prepared based on simple sol-gel methods with common equipment and chemicals. Reaction pH was found to influence the TiO2 upload in the nanocomposite. The alkaline condition produced the greatest TiO2 upload, while the acidic condition the least. Annealing at 300 °C turned the as-synthesized amorphous TiO2 into one with high content of anatase, the most photoactive form of TiO2. Irradiated by 365 nm UV light, a sample of 30 mg/mL of annealed nanocomposite containing 12.6 wt.% Ti was shown to be able to completely eradicate 104 CFU/mL of the laboratory-grown E. coli within 25 min, 25 min faster than the control when the 365 nm UV light was employed alone. The nanocomposite demonstrated consistent antimicrobial performance over repeated uses and was easily recoverable magnetically due to its high magnetization value (33 emu/g). Additionally, it was shown to reduce the bacterial count in a real surface water sample containing 500–5000 CFU/mL of different microbes by 62 ± 3% within 30 min. The irradiating 365 nm UV light alone was found to have generated little biocidal effect on this surface water sample. The nanocomposite is promising to serve as an effective, safe, and eco-friendly antimicrobial agent, especially for surface water disinfection.

2016 ◽  
Vol 4 (1) ◽  
Author(s):  
Mohamed F. Haroon ◽  
Luke R. Thompson ◽  
Ulrich Stingl

A draft genome of SAR324 bacterium lautmerah10 was assembled from a metagenome of a surface water sample from the Red Sea, Saudi Arabia. The genome is more complete and has a higher G+C content than that of previously sequenced SAR324 representatives. Its genomic information shows a versatile metabolism that confers an advantage to SAR324, which is reflected in its distribution throughout different depths of the marine water column.


Author(s):  
Aderonke A. Okoya ◽  
Oyeyemi S. Adegbaju ◽  
Oyindamola E. Akinola ◽  
Abimbola B. Akinyele ◽  
Omotayo S. Amuda

Nigeria is currently the largest rice producing country in Africa. High volumes of waste such as rice husk are inevitable with high production. Also pesticides used to rid of pests, diseases and improve crop yield find their ways into available surface water that serves domestic purpose. This study therefore determined the efficiency of conventional water treatment procedure for pesticide/pesticide residue removal and evaluated the performance of rice husk-based biochar as adsorbent to remove chlorpyrifos from domestic water supply with a view to manage  solid waste (rice husk) for treating pesticide polluted water. Batch adsorption studies were carried out to assess the adsorption efficiency of rice husk biochar (RHB) for chlorpyrifos pesticide removal from surface water. Adsorbent dosage, initial concentration, contact time and dosage were optimized during simulation experiment. RHB and commercial activated carbon (CAC) were used for the removal of chlorpyrifos from surface water sample using the optimum condition from the simulation experiment after which the concentrations were determined using Gas Chromatography with Mass Spectrometry detector. Both Langmuir and Freundlich adsorption isotherms were investigated. RHB gave percentage moisture (5.27±0.94), carbon yield (39.44±0.47), ash (41.96±0.96), fixed carbon (35.24±0.55), volatile matter (35.67±1.01 mg/g), Iodine number (85.57±0.81), surface area (97.20 m2/g), pH (7.90±0.14) and Electrical conductivity (298.8±1.14). Of the elements present in the char, Carbon has the highest percentage of 59.14%. Best adsorption conditions for RHB in this study were 2.8 mg/L initial concentration; 0.8 g of adsorbent dosage; pH of 5 and contact time of 30 min. The data fitted Freundlich than Langmuir model (R2 0.996 and 0.8315 respectively). Percentage removal of chlorpyrifos for CAC and RHB was 93.7±3.96 and 94.5±5.23 respectively for the surface water sample. Results concluded that RHB was efficient for removal of chlorpyrifos present in water and could be used as alternative for CAC in water treatments.


2011 ◽  
Vol 8 (1) ◽  
pp. 519-530 ◽  
Author(s):  
Baghdad Science Journal

Primary productivity and chlorophyll-a were used in this study to monitor the restoration process of southern Iraqi marshes (Al-Hewaizeh, central marshes, and Al-Hammar). The phytoplankton primary productivity was based on oxygen light/dark bottle method. Two different depths samples were taken monthly from six studied marshes stations (two stations for each marsh) during November 2005 to October 2006, while chlorophyll-a samples taken from surface water. The phytoplankton primary productivity values ranged 9.38 – 249.79 mg C/m3.hr for all marshes, its values for surface water sample ranged 11.71 – 256.24 mg C/m3.hr, while for 1m depth ranged 9.38 – 142.5 mg C/m3.hr. Chlorophyll-a values ranged between (1.1 – 21.26) µg/l indicating high values of productivity in the studied marshes comparing with other aquatic Iraqi ecosystems. Also, dissolved oxygen and oxygen saturation rate were measured in this study.


Water ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1622
Author(s):  
Xiao-Pin Guo ◽  
Peng Zang ◽  
Yong-Mei Li ◽  
Dong-Su Bi

2-methylisoborneol (2-MIB) is a common taste and odor compound caused by off-flavor secondary metabolites, which represents one of the greatest challenges for drinking water utilities worldwide. A TiO2-coated activated carbon (TiO2/PAC) has been synthesized using the sol-gel method. A new TiO2/PAC photocatalyst has been successfully employed in photodegradation of 2-MIB under UV light irradiation. In addition, the combined results of XRD, SEM-EDX, FTIR and UV-Vis suggested that the nano-TiO2 had been successfully loaded on the surface of PAC. Experimental results of 2-MIB removal indicated that the adsorption capacities of PAC for 2-MIB were higher than that of TiO2/PAC. However, in the natural organic matter (NOM) bearing water, the removal efficiency of 2-MIB by TiO2/PAC and PAC were 97.8% and 65.4%, respectively, under UV light irradiation. Moreover, it was shown that the presence of NOMs had a distinct effect on the removal of MIB by TiO2/PAC and PAC. In addition, a simplified equivalent background compound (SEBC) model could not only be used to describe the competitive adsorption of MIB and NOM, but also represent the photocatalytic process. In comparison to other related studies, there are a few novel composite photocatalysts that could efficiently and rapidly remove MIB by the combination of adsorption and photocatalysis.


Sign in / Sign up

Export Citation Format

Share Document