scholarly journals Mannich Base as Corrosion Inhibitors for N80 Steel in a CO2 Saturated Solution Containing 3 wt % NaCl

Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 449 ◽  
Author(s):  
Mingjin Tang ◽  
Jianbo Li ◽  
Zhida Li ◽  
Luoping Fu ◽  
Bo Zeng ◽  
...  
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Steel Sheet ◽  
Mannich Base ◽  
Saturated Solution ◽  
Control Group ◽  
Protective Film ◽  
Blank Control Group ◽  
Inhibition Effect ◽  
N80 Steel

In this paper, a corrosion inhibitor containing nitrogen atoms and a conjugated π bond was synthesised, and its final product synthesised by the optimal conditions of the orthogonal test results is named multi-mannich base (MBT). The corrosion inhibition effect on the N80 steel sheet of the corrosion inhibitor was evaluated in a CO2 saturated solution containing 3 wt % NaCl; the corrosion rate was 0.0446 mm/a and the corrosion inhibition rate was 90.4%. Through electrochemical and adsorption theory study, MBT is a mixed corrosion inhibitor that mainly shows cathode suppression capacity. The adsorption of MBT on the surface of the steel sheet follows the Langmuir adsorption isotherm; it can be spontaneously adsorbed on the surface of the N80 steel sheet, which has a good corrosion inhibition effect. The surface of the N80 steel sheet was microscopically characterised by atomic force microscope (AFM). It can be seen from the results that the N80 steel sheet with MBT added is significantly different from the blank control group; the surface of the steel sheet is relatively smooth, indicating that MBT forms an effective protective film on the surface of N80 steel, which inhibits the steel sheet.

A Mannich base 1-phenyl-3-(1-pyrrolidinyl)-1-propanone: synthesis and performance study on corrosion inhibition for N80 steel in 15% hydrochloric acid

2016 ◽  
Vol 63 (2) ◽  
pp. 153-159 ◽  
Author(s):  
Yuan Pan ◽  
Fengtao Zhan ◽  
Zhifeng Lu ◽  
Yan Lin ◽  
Zhen Yang ◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Mannich Base ◽  
Oil Well ◽  
Performance Study ◽  
Content Type ◽  
N80 Steel ◽  
Study Results ◽  
Inhibition Performance

Purpose – The purpose of this paper is to set out a study of a Mannich base, which was synthesized and used as an acidizing corrosion inhibitor first, and to the corrosion inhibitor mechanism. Design/methodology/approach – A Mannich base, 1-phenyl-3-(1-pyrrolidinyl)-propanone (PHPP), was synthesized with acetophenone, pyrrolidine and formaldehyde at pH = approximately 2-3. The structure of PHPP was characterized by elemental analysis and Fourier transform infrared spectroscopy (FTIR). The corrosion inhibition of PHPP on N80 steel in 15 per cent hydrochloric acid (HCl) was studied by weight loss method, scanning electron microscope (SEM) and energy dispersive X-ray analysis (EDAX), and the adsorption behavior of PHPP on the surface of N80 steel was discussed. Findings – The results showed that the inhibition efficiency reached to 99.8 per cent and corrosion rate was 2.65 g·m-2·h-1 at 0.6 per cent of PHPP concentration in 15 per cent HCl, which indicated that PHPP presented excellent corrosion inhibition performance. The results of SEM and EDAX analysis showed that PHPP could be absorbed on the surface of N80 steel. The adsorption process of PHPP on the surface of N80 steel was chemisorption. This process was spontaneous and obeyed Langmuir adsorption isotherm. Originality/value – It was found that PHPP presented excellent corrosion inhibition performance, and it is practicable to enhance oil production in oilfield development as a oil-well acidizing inhibitor. The study results can provide theoretical guidelines for the development of the inhibitor.

Corrosion and inhibition of N80 steel in 5% HCl solution by SA1-3

2017 ◽  
Vol 64 (6) ◽  
pp. 634-643 ◽  
Author(s):  
Liqiang Zhao ◽  
Yanhua Zhu ◽  
Pingli Liu ◽  
Jian Zhang ◽  
Yigang Liu
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Behavior ◽  
Theoretical Basis ◽  
Inhibition Mechanism ◽  
Corrosion Mechanism ◽  
Protective Film ◽  
Content Type ◽  
N80 Steel ◽  
Weight Loss Method ◽  
Hcl Solution

Purpose This paper aims to describe the corrosion behavior and possibility of inhibition by corrosion inhibitor SA1-3 in acidizing solution (5 per cent hydrochloric acid [HCl] solution). The study aims to explain the mechanism of corrosion and inhibition of N80 steel in 5 per cent HCl solution to provide theoretical basis for expanding the range of application of N80 steel in acidification process. Design/methodology/approach This paper opted for a laboratory study using simulation of acidizing solution to do the experiments. The results of experiments including weight-loss method, electrochemical method and surface analysis were used to explain the mechanism of corrosion and inhibition so as to predict the dissolution progress of N80 steel in 5 per cent HCl solution with and without inhibitor SA1-3. Findings This paper provides theoretical insights about how to inhibit the corrosion behavior of N80 steel in 5 per cent HCl solution. It suggests that the corrosion inhibitor which can form a protective film on the steel surface should be used to expand the application of N80 steel in acidizing solution. The inhibitor SA1-3 is a kind of cathodic corrosion-controlling inhibitor which mainly inhibits cathode corrosion; it cannot change the corrosion mechanism of N80 steel. Originality/value This paper provides a theoretical basis for the corrosion behavior and inhibition mechanism of N80 steel in acidizing solution.

Corrosion inhibitor system for blocking polymer well by potassium persulfate injection

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Qingchao Cheng ◽  
Guangsheng Cao ◽  
Congyu Sang ◽  
Yujie Bai ◽  
Dan Li ◽  
...  
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Ph Value ◽  
Sodium Molybdate ◽  
Potassium Persulfate ◽  
Inhibition Mechanism ◽  
Content Type ◽  
Inhibition Effect ◽  
Synergistic Mechanism ◽  
System Temperature

Purpose This paper aims to clarify the corrosion inhibition effect of different corrosion inhibitor systems on the corrosion of metal pipe string by potassium persulfate plugging agent, so as to improve the injection capacity of polymer plugging well and reduce the corrosion of steel by oxidant plugging agent. Design/methodology/approach The effect of different corrosion inhibitors on the corrosion inhibition of N80 carbon steel in 1% potassium persulfate solution was studied by electrochemical experiment and weight loss experiment. The corrosion inhibition mechanism of potassium persulfate inhibitor and the synergistic mechanism among different inhibitors were analyzed. Findings The results indicated that when the temperature was 50°C, the inhibition effect of 0.2% sodium molybdate with a single inhibitor was the best at pH 8.5, and the inhibition rate was 70.17%. The inhibition efficiency of 0.2% sodium molybdate + 0.3% sodium silicate in the composite inhibition system can reach 94.38%. In the temperature range of 20°C–60°C, with the increase of system temperature, the inhibition effect of corrosion inhibitor will gradually weaken. Originality/value The corrosion inhibition system of N80 steel in potassium persulfate oxidant was mainly studied, and it clarified the influence of temperature and pH value on the corrosion inhibition effect, which provided guidance and suggestions for the corrosion inhibition of tubular string in the oilfield.

scholarly journals Study of corrosion inhibition for mild steel in NaCl solution by propolis extract

2018 ◽  
Vol 37 (2) ◽  
Author(s):  
Veselinka Grudić ◽  
Ivana Bošković ◽  
Sanja Martinez ◽  
Bojana Knežević
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Electrode Surface ◽  
Chloride Solution ◽  
Electrochemical Impedance ◽  
Protective Layer ◽  
Protective Film ◽  
Propolis Extract ◽  
Electrochemical Testing ◽  
Working Solution

This paper studies the corrosion inhibition of X52 5L carbon steel in 0.51 mol dm-3 sodium chloride solution in the presence of propolis extract. The inhibition efficiency of propolis extract in a chloride solution was tested by its adding to the working solution and by making a solid propolis coating on the electrode surface. The possibility of corrosion inhibition in the presence of propolis in flow conditions as well as at different temperatures was investigated by electrochemical methods: potentiodynamic polarization method and electrochemical impedance spectroscopy. It was shown that propolis extract acts as a corrosion inhibitor of anodic type whose efficiency increases with increasing of temperature and with stirring of solution. The best protection is achieved by applying propolis coating in flow systems. The EIS method confirmed formation of a protective layer by adsorption of propolis extract on the electrode surface. The results of the FTIR, SEM and EDX surface tests are consistent with the results of electrochemical testing and suggest that propolis extract acts as a corrosion inhibitor of steel by forming a protective film on the electrode surface.

Carbohydrate compounds as green corrosion inhibitors: electrochemical, XPS, DFT and molecular dynamics simulation studies

RSC Advances ◽  
2016 ◽  
Vol 6 (111) ◽  
pp. 110053-110069 ◽  
Author(s):  
M. Yadav ◽  
T. K. Sarkar ◽  
I. B. Obot
Keyword(s):  
Molecular Dynamics ◽  
Molecular Dynamics Simulation ◽  
Corrosion Inhibition ◽  
Electrochemical Method ◽  
Corrosion Inhibitors ◽  
Dynamics Simulation ◽  
Simulation Studies ◽  
Inhibition Effect ◽  
N80 Steel ◽  
Green Corrosion Inhibitors

Corrosion inhibition effect of 5,6-bis(2-(1H-benzo[d]imidazol-2-yl)hydrazono)hexane-1,2,3,4-tetraol (BIHT) and 5,6-bis(2-(1-methyl-1H-imidazol-2-yl)hydrazono)hexane-1,2,3,4-tetraol (MIHT) on N80 steel in 15% HCl was measured by electrochemical method.

Adina Cordifolia as a corrosion inhibitor – a green approach against mild steel corrosion in 0.5M sulphuric acid medium

2020 ◽  
Vol 49 (1) ◽  
pp. 63-70
Author(s):  
Bhuvaneshwari Durvas Seshian ◽  
Bothi Raja Pandian ◽  
Umapathi Durai
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Corrosion Inhibitors ◽  
Corrosion Monitoring ◽  
Gravimetric Analysis ◽  
Protective Film ◽  
Transfer Resistance ◽  
Content Type ◽  
Green Corrosion Inhibitor

Purpose The purpose of this study is to develop green/natural corrosion inhibitors. Adina cordifolia leaves extract (ACLE) was screened for its corrosion inhibition potential for mild steel (MS) corrosion in 0.5 M H2SO4 medium. Design/methodology/approach Adina cordifolia (AC) leaves were subjected to cold ethanol extraction and concentrated after refluxed with double distilled water. The resultant concentrate was screened for corrosion inhibition studies using sequence of standard corrosion monitoring techniques, namely, gravimetric analysis, electrochemical studies and scanning electron microscopy (SEM). Findings Gravimetric analysis provided evidence that the prepared ACLE showed dose dependent corrosion inhibition; impedance study revealed that the ACLE increases the charge transfer resistance and decreases double layer capacitance while polarization curves indicated that ACLE acts as a mixed-type inhibitor. Further studies over MS surface/test solutions through SEM and Fourier-Transform Infrared spectroscopy evident the formation of ACLE protective film protects MS. Practical implications AC’s methanol extract developed in this work can be used as a green corrosion inhibitor over industrial applications. Originality/value For the first time, AC leaves were tested as corrosion inhibitors for MS corrosion in 0.5 M H2SO4 medium. The results evidenced that ACLE will be a promising corrosion inhibitor, which could be usable in industries as a green corrosion inhibitor.

scholarly journals Synthesis and Characterization of Nano-SiO2@octadecylbisimidazoline Quaternary Ammonium Salt Using as Acidizing Corrosion Inhibitor

2021 ◽  
Author(s):  
Yunfeng Liu ◽  
Xingde Zhang ◽  
Zhengsong Qiu ◽  
Lili Chen
Keyword(s):  
High Temperature ◽  
Corrosion Inhibition ◽  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Steel Sheet ◽  
Testing Machine ◽  
High Concentration ◽  
N80 Steel ◽  
Quantum Chemistry Calculations

Abstract Aiming at the current situation that the existing acidizing corrosion inhibitors are difficult to apply to high temperature, high concentration acid, and other complex conditions. This paper uses nano-SiO2 as the core and preferably functional monomers to synthesize nano-SiO2@octadecylbisimidazoline quaternary ammonium salt. Analytical methods such as nuclear magnetic resonance, infrared, SEM were used for characterization. The corrosion inhibition performance of the N80 steel sheet by nano-SiO2@octadecylbisimidazoline quaternary ammonium salt in 20% concentrated hydrochloric acid was studied using the high-temperature corrosion testing machine and adsorption isotherm model. Combined with quantum chemistry calculations to explore its mechanism of action. The results show that nano-SiO2@octadecylbisimidazoline quaternary ammonium salt has good high-temperature resistance. When the temperature is 180℃ and the dosage of nano-SiO2@octadecylbisimidazoline quaternary ammonium salt is 4%, the corrosion inhibition rate is 61.42g·m− 2·h− 1. Studies have shown that the adsorption of nano-SiO2@octadecylbisimidazoline quaternary ammonium salt on the surface of the N80 steel sheet follows the Langmuir isotherm adsorption model, which is spontaneous chemical adsorption.

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