scholarly journals Magnesium Oxychloride Cement Composites Lightened with Granulated Scrap Tires and Expanded Glass

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4828 ◽  
Author(s):  
Milena Pavlíková ◽  
Adam Pivák ◽  
Martina Záleská ◽  
Ondřej Jankovský ◽  
Pavel Reiterman ◽  
...  

In this paper, light burned magnesia dispersed in the magnesium chloride solution was used for the manufacturing of magnesium oxychloride cement-based composites which were lightened by granulated scrap tires and expanded glass. In a reference composite, silica sand was used only as filler. In the lightened materials, granulated shredded tires were used as 100%, 90%, 80%, and 70% silica sand volumetric replacement. The rest was compensated by the addition of expanded glass granules. The filling materials were characterized by particle size distribution, specific density, dry powder density, and thermal properties that were analyzed for both loose and compacted aggregates. For the hardened air-cured samples, macrostructural parameters, mechanical properties, and hygric and thermal parameters were investigated. Specific attention was paid to the penetration of water and water-damage, which were considered as crucial durability parameters. Therefore, the compressive strength of samples retained after immersion for 24 h in water was tested and the water resistance coefficient was assessed. The use of processed waste rubber and expanded glass granulate enabled the development of lightweight materials with sufficient mechanical strength and stiffness, low permeability for water, enhanced thermal insulation properties, and durability in contact with water. These properties make the produced composites an interesting alternative to Portland cement-based materials. Moreover, the use of low-carbon binder and waste tires can be considered as an eco-efficient added value of these products which could improve the environmental impact of the construction industry.

2012 ◽  
Vol 188 ◽  
pp. 183-188 ◽  
Author(s):  
Zhan Hong Qiu ◽  
Jin Rong Feng ◽  
Lei Xiao ◽  
Zhi Yong Zeng

Based on the results of compression and bending tests of fifty eight magnesium oxychloride cement test cubes, the influences of two factors on compression and bending strength have been analyzed which includes the mole ratio of magnesium oxide and magnesium chloride and Baum degree of magnesium chloride solution. Softening coefficient of magnesium oxychloride cement and its influence factor have been studied by immersion test of twelve test cubes. The results show when the mole ratio of magnesium oxide and magnesium chloride is 7.0, the strength and water resistance performance of magnesium oxychloride cement is best. This work is very important to the application and dissemination of magnesium oxychloride cement bearing structural member in southern wetter areas of china.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3899
Author(s):  
Pan Liu ◽  
Jinmei Dong ◽  
Chenggong Chang ◽  
Weixin Zheng ◽  
Xiuquan Liu ◽  
...  

Magnesium oxychloride cement (abbreviated as MOC) was prepared using magnesium residue obtained from Li2CO3 extraction from salt lakes as raw material instead of light magnesium oxide. The properties of magnesium residue calcined at different temperatures were researched by XRD, SEM, LSPA, and SNAA. The preparation of MOC specimens with magnesium residue at different calcination temperatures (from 500 °C to 800 °C) and magnesium chloride solutions with different Baume degrees (24 Baume and 28 Baume) were studied. Compression strength tests were conducted at different curing ages from 3 d to 28 d. The hydration products, microstructure, and porosity of the specimens were analyzed by XRD, SEM, and MIP, respectively. The experimental results showed that magnesium residue’s properties, the BET surface gradually decreased and the crystal size increased with increasing calcination temperature, resulting in a longer setting time of MOC cement. Additionally, the experiment also indicated that magnesium chloride solution with a high Baume makes the MOC cement have higher strength. The MOC specimens prepared by magnesium residue at 800 °C and magnesium chloride solution Baume 28 exhibited a compressive of 123.3 MPa at 28 d, which met the mechanical property requirement of MOC materials. At the same time, magnesium oxychloride cement can be an effective alternative to Portland cement-based materials. In addition, it can reduce environmental pollution and improve the environmental impact of the construction industry, which is of great significance for sustainable development.


Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5708
Author(s):  
Anna-Marie Lauermannová ◽  
Filip Antončík ◽  
Michal Lojka ◽  
Ondřej Jankovský ◽  
Milena Pavlíková ◽  
...  

A high-performance magnesium oxychloride cement (MOC) composite composed of silica sand, diatomite powder, and doped with graphene nanoplatelets was prepared and characterized. Diatomite was used as a 10 vol.% replacement for silica sand. The dosage of graphene was 0.5 wt.% of the sum of the MgO and MgCl2·6H2O masses. The broad product characterization included high-resolution transmission electron microscopy, X-ray diffraction, X-ray fluorescence, scanning electron microscopy and energy dispersive spectroscopy analyses. The macrostructural parameters, pore size distribution, mechanical resistance, stiffness, hygric and thermal parameters of the composites matured for 28-days were also the subject of investigation. The combination of diatomite and graphene nanoplatelets greatly reduced the porosity and average pore size in comparison with the reference material composed of MOC and silica sand. In the developed composites, well stable and mechanically resistant phase 5 was the only precipitated compound. Therefore, the developed composite shows high compactness, strength, and low water imbibition which ensure high application potential of this novel type of material in the construction industry.


2021 ◽  
Vol 13 (5) ◽  
pp. 2429
Author(s):  
Weixin Zheng ◽  
Xueying Xiao ◽  
Jing Wen ◽  
Chenggong Chang ◽  
Shengxia An ◽  
...  

Magnesium oxychloride cement (MOC) foam concrete (MOCFC) is an air-hardening cementing material formed by mixing magnesium chloride solution (MgCl2) and light-burned magnesia (i.e., active MgO). In application, adding caustic dolomite powder into light-burned magnesite powder can reduce the MOCFC production cost. The brine content of MOC changes with the incorporation of caustic dolomite powder. This study investigated the relationship between the mass percent concentration and the Baumé degree of a magnesium chloride solution after bischofite (MgCl2·6H2O) from a salt lake was dissolved in water. The proportional relationship between the amount of water in brine and bischofite, and the functional formula for the water-to-cement ratio (W/C) of MOC mixed with caustic dolomite powder were deduced. The functional relationship was verified as feasible for preparing MOC through the experiment.


Materials ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2537 ◽  
Author(s):  
Adam Pivák ◽  
Milena Pavlíková ◽  
Martina Záleská ◽  
Michal Lojka ◽  
Ondřej Jankovský ◽  
...  

Worldwide, Portland cement-based materials are the most commonly used construction materials. As the Portland cement industry negatively affects the environment due to the excessive emission of carbon dioxide and depletion of natural resources, new alternative materials are being searched. Therefore, the goal of the paper was to design and develop eco-friendly, low-cost, and sustainable magnesium oxychloride cement (MOC)-based building material with a low carbon footprint, which is characterized by reduced porosity, high mechanical resistance, and durability in terms of water damage. To make new material eco-efficient and functional, silica sand which was used in the composition of the control composite mixture was partially replaced with coal fly ash (FA), a byproduct of coal combustion. The chemical and mineralogical composition, morphology, and particle morphology of FA were characterized. For silica sand, FA, and MgO, specific density, loose bulk density, and particle size distribution were measured. Additionally, Blaine specific surface was for FA and MgO powder assessed. The workability of fresh mixtures was characterized by spread diameter. For the hardened MOC composites, basic structural, mechanical, hygric, and thermal properties were measured. Moreover, the phase composition of precipitated MOC phases and their thermal stability were investigated for MOC-FA pastes. The use of FA led to the great decrease in porosity and pore size compared to the control material with silica sand as only filler which was in agreement with the workability of fresh composite mixtures. The compressive strength increased with the replacement of silica sand with FA. On the contrary, the flexural strength slightly decreased with silica sand substitution ratio. It clearly proved the assumption of the filler function of FA, whereas its assumed reactivity with MOC cement components was not proven. The water transport and storage were significantly reduced by the use of FA in composites, which greatly improved their resistance against moisture damage. The heat transport and storage parameters were only slightly affected by FA incorporation in composite mixtures.


Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 484
Author(s):  
Michal Lojka ◽  
Anna-Marie Lauermannová ◽  
David Sedmidubský ◽  
Milena Pavlíková ◽  
Martina Záleská ◽  
...  

In this contribution, composite materials based on magnesium oxychloride cement (MOC) with multi-walled carbon nanotubes (MWCNTs) used as an additive were prepared and characterized. The prepared composites contained 0.5 and 1 wt.% of MWCNTs, and these samples were compared with the pure MOC Phase 5 reference. The composites were characterized using a broad spectrum of analytical methods to determine the phase and chemical composition, morphology, and thermal behavior. In addition, the basic structural parameters, pore size distribution, mechanical strength, stiffness, and hygrothermal performance of the composites, aged 14 days, were also the subject of investigation. The MWCNT-doped composites showed high compactness, increased mechanical resistance, stiffness, and water resistance, which is crucial for their application in the construction industry and their future use in the design and development of alternative building products.


2019 ◽  
Vol 8 (1) ◽  
pp. 94-104 ◽  
Author(s):  
Wei Gong ◽  
Hongfa Yu ◽  
Haiyan Ma ◽  
Hongxia Qiao ◽  
Guangfeng Chen

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