scholarly journals Asymmetric Magnetoelectrochemistry: An Efficient Method to Grow Enantiopure Self-Assemble Monolayer

2020 ◽  
Vol 6 (3) ◽  
pp. 37
Author(s):  
Suryakant Mishra ◽  
Debkumar Bhowmick

In this work, we are presenting magnetic field dependent electrochemical method to grow enantiopure monolayer. Thiol gold monolayer formation by redox reaction is studied on gold coated ferromagnetic surface. Infrared and photoemission spectroscopies are used to probe the quality of the monolayers, grown using different direction of magnetization of surface. Commercially available chiral molecules, L-cysteine along with dsDNA are used as control molecules for the measurements. Since it is established by aligning the electron spin within the surface, it helps to adsorb specific enantiomer of molecules, we have shown how direction of the magnet helps to grow good quality monolayer. Potential application of this work is in improving quality of monolayer and chiral separation.

Author(s):  
А.И. Вейнгер ◽  
И.В. Кочман ◽  
Д.А. Фролов ◽  
В.И. Окулов ◽  
Т.Е. Говоркова ◽  
...  

AbstractFeatures of magnetic-field-dependent microwave absorption in HgSe samples doped with Co and Ni impurities in different concentrations are investigated. The electron-spin resonance spectra of weakly coupled Co atoms and peculiarities of the magnetic-absorption variation in a magnetic field passing through the zero value are established. The main parameters of the electron-spin resonance spectra and temperature and angular dependences of microwave absorption in weak fields are determined.


1981 ◽  
Vol 42 (C6) ◽  
pp. C6-499-C6-501 ◽  
Author(s):  
H. Gerlinger ◽  
G. Schaack

1981 ◽  
Vol 42 (C5) ◽  
pp. C5-689-C5-693
Author(s):  
J. D.N. Cheeke ◽  
G. Madore ◽  
A. Hikata

2020 ◽  
Vol 72 (1) ◽  
Author(s):  
Sabrina Sanchez ◽  
Johannes Wicht ◽  
Julien Bärenzung

Abstract The IGRF offers an important incentive for testing algorithms predicting the Earth’s magnetic field changes, known as secular variation (SV), in a 5-year range. Here, we present a SV candidate model for the 13th IGRF that stems from a sequential ensemble data assimilation approach (EnKF). The ensemble consists of a number of parallel-running 3D-dynamo simulations. The assimilated data are geomagnetic field snapshots covering the years 1840 to 2000 from the COV-OBS.x1 model and for 2001 to 2020 from the Kalmag model. A spectral covariance localization method, considering the couplings between spherical harmonics of the same equatorial symmetry and same azimuthal wave number, allows decreasing the ensemble size to about a 100 while maintaining the stability of the assimilation. The quality of 5-year predictions is tested for the past two decades. These tests show that the assimilation scheme is able to reconstruct the overall SV evolution. They also suggest that a better 5-year forecast is obtained keeping the SV constant compared to the dynamically evolving SV. However, the quality of the dynamical forecast steadily improves over the full assimilation window (180 years). We therefore propose the instantaneous SV estimate for 2020 from our assimilation as a candidate model for the IGRF-13. The ensemble approach provides uncertainty estimates, which closely match the residual differences with respect to the IGRF-13. Longer term predictions for the evolution of the main magnetic field features over a 50-year range are also presented. We observe the further decrease of the axial dipole at a mean rate of 8 nT/year as well as a deepening and broadening of the South Atlantic Anomaly. The magnetic dip poles are seen to approach an eccentric dipole configuration.


Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 1870
Author(s):  
Dmitry Borin ◽  
Robert Müller ◽  
Stefan Odenbach

This paper presents the results of an experimental study of the influence of an external magnetic field on the shear flow behaviour of a magnetic fluid based on barium hexaferrite nanoplates. With the use of rheometry, the magnetoviscosity and field-dependent yield-stress in the fluid are evaluated. The observed fluid behaviour is compared to that of ferrofluids with magnetic nanoparticles having high dipole interaction. The results obtained supplement the so-far poorly studied topic of the influence of magnetic nanoparticles’ shape on magnetoviscous effects. It is concluded that the parameter determining the observed magnetoviscous effects in the fluid under study is the ratio V2/l3, where V is the volume of the nanoparticle and l is the size of the nanoparticle in the direction corresponding to its orientation in the externally applied magnetic field.


Heliyon ◽  
2021 ◽  
pp. e07707
Author(s):  
Suci Amalia ◽  
Stevin Carolius Angga ◽  
Elvina Dhiaul Iftitah ◽  
Dias Septiana ◽  
Baiq Octaviana D. Anggraeny ◽  
...  

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