scholarly journals A Mixed Numerical-Experimental Method to Characterize Metal-Polymer Interfaces for Crash Applications

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 818
Author(s):  
Jonas Richter ◽  
Moritz Kuhtz ◽  
Andreas Hornig ◽  
Mohamed Harhash ◽  
Heinz Palkowski ◽  
...  
Keyword(s):  
Experimental Parameter ◽  
Dissimilar Materials ◽  
Calibration Method ◽  
Parameter Determination ◽  
Failure Behavior ◽  
Cohesive Elements ◽  
Interface Failure ◽  
Wide Range ◽  
Polymer Metal ◽  
Metal Polymer

Metallic (M) and polymer (P) materials as layered hybrid metal-polymer-metal (MPM) sandwiches offer a wide range of applications by combining the advantages of both material classes. The interfaces between the materials have a considerable impact on the resulting mechanical properties of the composite and its structural performance. Besides the fact that the experimental methods to determine the properties of the single constituents are well established, the characterization of interface failure behavior between dissimilar materials is very challenging. In this study, a mixed numerical–experimental approach for the determination of the mode I energy release rate is investigated. Using the example of an interface between a steel (St) and a thermoplastic polyolefin (PP/PE), the process of specimen development, experimental parameter determination, and numerical calibration is presented. A modified design of the Double Cantilever Beam (DCB) is utilized to characterize the interlaminar properties and a tailored experimental setup is presented. For this, an inverse calibration method is used by employing numerical studies using cohesive elements and the explicit solver of LS-DYNA based on the force-displacement and crack propagation results.

FORMATION OF PHYSICAL INTERACTIONS IN POLYMER-STEEL FRICTION PAIRS

Tribologia ◽  
2016 ◽  
Vol 267 (3) ◽  
pp. 153-159
Author(s):  
Jacek PRZEPIÓRKA ◽  
Marian SZCZEREK
Keyword(s):  
Friction Pair ◽  
Wide Range ◽  
Metal Element ◽  
Polymer Metal ◽  
Physical Interactions ◽  
Short Time ◽  
Metal Polymer ◽  
Active Centres ◽  
Metal Friction ◽  
Oxidation Susceptibility

This article presents the results of tribological studies of metal-polymer pairs by taking into account a wide range of the externally applied parameters of friction pairs (pressure, rubbing speed), reaching the limits of polymer flow. Adhesion is the dominant mechanism of the wear of polymer-steel friction pairs; it triggers off the transfer of the polymer onto the metal as a result of local joining between the chains of hydrocarbons and the active centres located on the surface of the steel element. The main reason for this phenomenon is the high oxidation susceptibility of the metal element and, as a result, a tendency for oxide formation on its surface. This is a spontaneous phenomenon that is taking place in a short time, and the degree of over-reaction depends on the duration of exposure, humidity, temperature, the presence of impurities on the surface of the metal element, and many other factors. Therefore, limiting the formation of oxides on the surface of the metal element is a key issue related to enhancing the resistance of a polymer-metal friction pair resistance to adhesive wear.

scholarly journals Sonochemical Preparation of Polymer-Metal Nanocomposites with Catalytic and Plasmonic Properties

2021 ◽  
Author(s):  
Jing Wan ◽  
Bo Fan ◽  
San Thang
Keyword(s):  
Reducing Agents ◽  
Wide Range ◽  
Polymer Metal ◽  
Metal Nanocomposites

Polymer-metal nanocomposites are of increasing interest for a wide range of applications; however, the preparation of these nanocomposites often requires the addition of external initiation and reducing agents for the...

Fabrication of Ionic Polymer Metal Composite Actuator with Palladium Electrodes and Evaluation of its Bending Response

2009 ◽  
Vol 1190 ◽  
Author(s):  
Takuma Kobayashi ◽  
Takeshi Kuribayashi ◽  
Masaki Omiya
Keyword(s):  
Electric Field ◽  
Sample Length ◽  
Metal Composite ◽  
Ionic Polymer Metal Composite ◽  
Ionic Polymer ◽  
Palladium Electrode ◽  
Wide Range ◽  
Polymer Metal ◽  
Bending Response ◽  
Tip Displacement

AbstractWe built up the way of fabricating IPMC actuator with palladium electrodes and we found that it showed large bending response than Au-plated IPMC actuator. An ionic polymer-metal composite (IPMC) consisting of a thin perfuorinated ionomer membrane, electrodes plated on both faces, undergoes large bending motion when a small electric field is applied across its thickness in a hydrated state. The characteristics of IPMC are ease of miniaturization, low density, and mechanical flexibility. Therefore, it is considered to have a wide range of applications from MEMS sensor to artificial muscle. However, there are problems on IPMC. First, its mechanical and electric characteristics have not been clarified because of the complex mechanism of the deformation. Second, it is high-priced because most of IPMC actuators use gold or platinum as electrodes. In order for IPMC actuator to be widely put to practical use, we should solve these problems. Hence, this research focuses on fabrication of IPMC actuator with palladium electrode, which is cheaper than gold or platinum, and evaluation of its mechanical properties such as its tip displacement. We fabricated IPMC consisting of a thin Nafion® membrane, which is the film with fluorocarbon back-bones and mobile cations, sandwiched between two thin palladium plates. The surface resistivity was 2.88±0.18Ω/sq., so it could be said to be enough small. Then, we observed its cross section by using FE-SEM. As a result, palladium plates were evenly coated and its thickness was about 30μm. Also, we carried out an actuation test for two kinds of IPMCs: one was fabricated by using Nafion®117 (thickness 183μm), the other was by Nafion®115 (thickness 127μm). In this test, the relationship between voltage (0˜4V) across its thickness and tip displacement for the cantilevered strip of the IPMC was measured. Then we found that IPMCs showed large bending motion under a low electric field. When Nafion®117 sample was subjected to voltage of 1.5V, the ratio of the tip displacement to the sample length was 0.35, which was lager bending than Au-plated IPMC actuator, whose ratio of the tip displacement to the sample length was 0.12 [1]. When Nafion®115 sample was applied to 1.5V, the ratio of the tip displacement to the sample length was 0.22. Then, we found that Nafion®117 bended in a larger way than Nafion®115. Reference [1]Sia Nemat-Nesser and Yongxian Wu,”Comparative experimental study of ionic polymer-metal composites with different backbone ionomers and in various cation forms”, Journal of Applied Physics,93,5255 (2003)

INFLUENCE OF THE DYNAMICS OF FORCED MOTION ON THE STATIC FRICTION IN METAL-POLYMER SLIDING PAIRS

Tribologia ◽  
2021 ◽  
Vol 295 (1) ◽  
pp. 21-26
Author(s):  
Mariusz Opałka ◽  
Wojciech Wieleba ◽  
Angelika Radzińska
Keyword(s):  
Relative Motion ◽  
Friction Pair ◽  
Polymeric Materials ◽  
Static Friction ◽  
Metallic Materials ◽  
Test Results ◽  
Friction Resistance ◽  
Rate Of Increase ◽  
Polymer Metal ◽  
Metal Polymer

The resistance during the frictional interaction of polymeric materials with metallic materials is characterized by a significant dependence on the dynamics of the motion inputs. In a metal-polymer friction pair, the static friction resistance during standstill under load depends on the rate of growth of the force causing the relative motion. Tribological tests of selected (polymer-metal) sliding pairs were carried out. The selected polymers were polyurethane (TPU), polysulfone (PSU), and silicone rubber (SI). They interacted with a pin made of normalized C45 steel under unitary pressure p = 0.5 MPa in dry friction conditions at different gradients of the force driving the relative motion (dF/dt = 0.1-20 [N/s]). The static friction coefficient of the selected sliding pairs was determined on the basis of the recorded static friction force values. The test results show a significant influence of the rate of increase in the motion driving force on the values of static friction resistance. This is mainly due to the viscoelastic properties of polymers.

Effect of the Electrode Material on Electronic Switching in a Metal–Polymer–Metal Structure

2021 ◽  
Vol 15 (3) ◽  
pp. 601-606
Author(s):  
A. F. Galiev ◽  
A. A. Lachinov ◽  
D. D. Karamov ◽  
A. N. Lachinov ◽  
A. R. Yusupov ◽  
...  
Keyword(s):  
Electrode Material ◽  
Metal Structure ◽  
Electronic Switching ◽  
Polymer Metal ◽  
Metal Polymer

scholarly journals FAO-56 Penman-Monteith DailyETofrom Linear Regression Calibrated Hargreaves Equation with Wind Terms in Tropics with Limited Data

2014 ◽  
Vol 2014 ◽  
pp. 1-9 ◽  
Author(s):  
Eric Kra
Keyword(s):  
Linear Regression ◽  
Quadratic Function ◽  
Constant Term ◽  
Calibration Method ◽  
Temperature Data ◽  
Limited Data ◽  
Wide Range ◽  
Hargreaves Equation ◽  
Historical Temperature ◽  
Monteith Equation

Hargreaves equation (HG), which lacks a wind speed (u2) term, was modified, through a linear regression calibration method, into LHGu which hasu2terms. LHGu is effectively a simplified method for approximating FAO-56 Penman-Monteith equation (FPM) daily reference evapotranspiration (ETo) in tropics with only temperature data. In LHGu, the “0.0023” constant term in HG was calibrated as a shifted power function ofu2, and the calibration constant was parametrized as a quadratic function ofu2. LHGu was developed using simulated constantu2data and historical temperature data for four sites in West Africa: Abidjan, Accra, Daloa, and Lome. LHGu matched FPMETobetter than HG over a wide range ofu2: for Accra, foru2range 0.5–6.0 m/s, the modified coefficient of efficiency,E1, varied narrowly (0.83–0.98) for LHGu but widely (0.14–0.95) for HG optimized foru2=2.0 m/s; the corresponding MBE ranges were −0.05–0.01 mm/d for LHGu and 0.02–0.63 mm/d for HG which cannot respond to varying dailyu2. LHGu is useful for quickly computing practically accurate estimates of FPMETofor varying dailyu2where only temperature data are available.

Hybrid additive and subtractive manufacturing of multi-material objects

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Eric Weflen ◽  
Matthew Charles Frank
Keyword(s):  
Performance Metrics ◽  
Process Development ◽  
Dissimilar Materials ◽  
Material Objects ◽  
Functional Requirements ◽  
Polymer Additive ◽  
Content Type ◽  
Subtractive Manufacturing ◽  
Five Axis ◽  
Metal Polymer

Purpose This study presents a method for fabricating multi-material objects using a hybrid additive and subtractive approach. By hybridizing the material composition in addition to the fabrication process, functional requirements can be met more effectively than through homogenous material parts produced using a single manufacturing process. Development of multi-material objects consisting of dissimilar materials that have been hampered by a lack of a structural interface compatible with in-envelope hybrid additive and subtractive manufacturing. Design/methodology/approach This research presents a novel method for producing multi-material components through in-envelope hybrid additive and subtractive manufacturing. This study attempts to address the absence of a metal-polymer interface by integrating polymer additive manufacturing into a five-axis mill. The ability of the polymer additive system to reproduce overhang geometries is assessed with different levels of cooling. The relationship between structural performance, cooling and material flow rate is evaluated for the deposited carbon fiber reinforced acrylonitrile butadiene styrene. Findings A mechanically interlocking root structure is developed to form an interface between a machined aluminum region and a polymer region of an object. The tensile strength of the metal-polymer object is measured and found to be on the same order of magnitude as the bulk three-dimensional printed polymer. Originality/value By targeting the material properties to the local functional requirements within a part and taking advantage of both additive and subtractive manufacturing processes, this study will enable broader design options and optimization of performance metrics.

scholarly journals Validity and limitations of simple reaction kinetics to calculate concentrations of organic compounds from ion counts in PTR-MS

2019 ◽  
Vol 12 (11) ◽  
pp. 6193-6208 ◽  
Author(s):  
Rupert Holzinger ◽  
W. Joe F. Acton ◽  
William J. Bloss ◽  
Martin Breitenlechner ◽  
Leigh R. Crilley ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Reaction Kinetics ◽  
Transfer Reaction ◽  
Performance Status ◽  
Calibration Method ◽  
Proton Transfer Reaction ◽  
Rural Site ◽  
Water Molecules ◽  
Simple Reaction ◽  
Wide Range

Abstract. In September 2017, we conducted a proton-transfer-reaction mass-spectrometry (PTR-MS) intercomparison campaign at the CESAR observatory, a rural site in the central Netherlands near the village of Cabauw. Nine research groups deployed a total of 11 instruments covering a wide range of instrument types and performance. We applied a new calibration method based on fast injection of a gas standard through a sample loop. This approach allows calibrations on timescales of seconds, and within a few minutes an automated sequence can be run allowing one to retrieve diagnostic parameters that indicate the performance status. We developed a method to retrieve the mass-dependent transmission from the fast calibrations, which is an essential characteristic of PTR-MS instruments, limiting the potential to calculate concentrations based on counting statistics and simple reaction kinetics in the reactor/drift tube. Our measurements show that PTR-MS instruments follow the simple reaction kinetics if operated in the standard range for pressures and temperature of the reaction chamber (i.e. 1–4 mbar, 30–120∘, respectively), as well as a reduced field strength E∕N in the range of 100–160 Td. If artefacts can be ruled out, it becomes possible to quantify the signals of uncalibrated organics with accuracies better than ±30 %. The simple reaction kinetics approach produces less accurate results at E∕N levels below 100 Td, because significant fractions of primary ions form water hydronium clusters. Deprotonation through reactive collisions of protonated organics with water molecules needs to be considered when the collision energy is a substantial fraction of the exoergicity of the proton transfer reaction and/or if protonated organics undergo many collisions with water molecules.

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